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61.
Tahiana F. C. Hermenegildo Tiago F. A. Santos Edwar A. Torres Conrado R. M. Afonso Antonio J. Ramirez 《Metals and Materials International》2018,24(5):1120-1132
Evaluation was made of friction stir welded joints, identifying conditions that resulted in satisfactory welded joints free from defects and with microstructural characteristics that provided good mechanical properties. Microstructural characterization and cooling curve analysis of the joints with lower and higher heat inputs evidenced deformation below and above the non-recrystallization temperature (Tnr) and dynamic recrystallization during microstructural evolution. Microscopy analyses showed acicular ferrite, bainitic ferrite, and coalesced bainite microstructures in the stir zone of the cold weld (lower heat input), while the stir zone of the hot weld (higher heat input) contained bainitic ferrite, acicular ferrite, coalesced bainite, martensite, and dispersed carbides. Granular bainite and dispersed carbides were observed in all the heat affected zones. Analysis of the microstructural transformations, together with the thermal history of the joints, showed that the variable that had the greatest influence on the morphology of the bainite (granular bainite/bainitic ferrite) was the deformation temperature. 相似文献
62.
Synthetic and Biological Studies of Sesquiterpene Polygodial: Activity of 9‐Epipolygodial against Drug‐Resistant Cancer Cells
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Dr. Ramesh Dasari Annelise De Carvalho Derek C. Medellin Kelsey N. Middleton Dr. Frédéric Hague Marie N. M. Volmar Prof. Liliya V. Frolova Dr. Mateus F. Rossato Jorge J. De La Chapa Nicholas F. Dybdal‐Hargreaves Akshita Pillai Prof. Véronique Mathieu Prof. Snezna Rogelj Prof. Cara B. Gonzales Prof. João B. Calixto Prof. Antonio Evidente Dr. Mathieu Gautier Dr. Gnanasekar Munirathinam Prof. Rainer Glass Prof. Patricia Burth Dr. Stephen C. Pelly Prof. Willem A. L. van Otterlo Prof. Robert Kiss Prof. Alexander Kornienko 《ChemMedChem》2015,10(12):2014-2026
Polygodial, a terpenoid dialdehyde isolated from Polygonum hydropiper L., is a known agonist of the transient receptor potential vanilloid 1 (TRPV1). In this investigation a series of polygodial analogues were prepared and investigated for TRPV1‐agonist and anticancer activities. These experiments led to the identification of 9‐epipolygodial, which has antiproliferative potency significantly exceeding that of polygodial. 9‐Epipolygodial was found to maintain potency against apoptosis‐resistant cancer cells as well as those displaying the multidrug‐resistant (MDR) phenotype. In addition, the chemical feasibility for the previously proposed mechanism of action of polygodial, involving the formation of a Paal–Knorr pyrrole with a lysine residue on the target protein, was demonstrated by the synthesis of a stable polygodial pyrrole derivative. These studies reveal rich chemical and biological properties associated with polygodial and its direct derivatives. These compounds should inspire further work in this area aimed at the development of new pharmacological agents, or the exploration of novel mechanisms of covalent modification of biological molecules with natural products. 相似文献
63.
Tiago Felipe de Abreu Santos Edwar Andrés Torres Antonio Jose Ramirez 《Welding International》2018,32(2):103-111
Duplex stainless steels are successful in a variety of applications such as the food industry, petrochemicals and plants for desalination of seawater, where high corrosion resistance and high mechanical strength are required. However, the beneficial microstructure may change during fusion welding steps, and it can compromise the performance of these materials. Friction stir welding is a solid-state process avoiding typical problems concerning solidification such as solidification cracks, liquation and segregation of alloying elements. Superduplex stainless steels can avoid unbalanced proportions of ferrite and austenite, formation of secondary deleterious phases and grain growth of ferrite in the heat-affected zone. Consolidated friction stir welded joints with full penetration 6 mm thick were obtained for UNS S32101 and S32205 duplex and S32750 and S32760 superduplex stainless steels. The friction stir welds were submitted to tensile tests indicating an improvement of strength in welded joints, showing increased yield and tensile strength for all studied cases. Regarding the microstructural characterization, an outstanding grain refinement was observed in the welded joint, achieving grain sizes as small as 1 μm. This refinement was associated with the combination of microstructural restoration mechanisms in the dual-phase microstructure promoted by severe deformation associated with a high temperature during the welding process. 相似文献
64.
A. T. Lima A. B. Ribeiro J. M. Rodríguez-Maroto E. P. Mateus A. M. Castro L. M. Ottosen 《Journal of Applied Electrochemistry》2010,40(9):1689-1697
A one-dimensional model is developed for simulating the electrodialytic and dialytic treatment of a fly ash containing cadmium,
copper and lead. Two experimental systems have been used, a column of ash and a stirred ash suspension. The movement of Cd,
Cu and Pb has been modeled taking into account the diffusion transport resulting from the concentration gradients of their
compounds through the membranes and boundary layers and the electromigration of their ionic, simple and complex species during
the operation. The model also includes the electromigration of the non-contaminant most important principal ionic species
in the system, H+ and OH−, proceeding of the electrolysis at the electrodes, Ca2+, CO3
=, SO4
=, etc. proceeding from the ash and Na+ and NO3
−, or citrate and ammonium ions incorporated as electrolyte solutions and/or as agent solution during the ash treatment. The
simulation also takes into account that OH− generated on the cathode, during the electrodialytic remediation, is periodically neutralized by the addition of nitric acid
in the cathode compartment. The anion and cation-exchange membranes are simply represented as ionic filters that preclude
the transport of the cations and anions, respectively, with the exception of H+ which is retarded but pass through the anion-exchange membrane. 相似文献
65.
Hydrogen adsorption on KOH activated carbons from mesophase pitch containing Si, B, Ti or Fe 总被引:1,自引:0,他引:1
Different activated carbons with large micropore volume (0.78-0.99 cm3/g) have been prepared by KOH activation of mesophase pitch obtained by co-pyrolysis of a petroleum residue and small amounts of different compounds, triphenylsilane, borane pyridine complex, tetrabutyl orthotitanate or ferrocene. During the preparation, the Ti introduced in the petroleum residue concentrate into the activated carbon, whereas some loss of Si and Fe occurs. The compounds modify the size of mesophase structure formed during the co-pyrolysis process, as well as the apparent height of lamelae stack, Lc, both having an important effect in the development of the porosity of the activated carbon. However, there is a scarce influence of all heteroatoms in the adsorption capacity of H2 at −196 °C and at 25 °C, which seems to be mainly influenced by the volume and size of micropores of the activated carbon. Only the activated carbon containing Fe adsorbs a higher amount of hydrogen at 25 °C and 10 MPa than the expected one according to its micropore volume. 相似文献
66.
67.
Nuno Mateus Joana Oliveira João Pissarra Ana M. González-Paramás Julian C. Rivas-Gonzalo Celestino Santos-Buelga Artur M.S. Silva Victor de Freitas 《Food chemistry》2006
A new pyranoanthocyanin–vinylphenol pigment was detected in an aged Port red wine. The UV–Vis spectrum of this pigment was found to have a λmax of 538 nm that is bathochromically shifted from that of original anthocyanins, exhibiting a more purple hue in acidic solution. This newly formed pigment was synthesized in model solution through the reaction between malvidin 3-O-glucoside–pyruvic acid adduct and vinylphenol and its structure was assigned by NMR and mass spectrometry. This pigment is reported herein for the first time. 相似文献
68.
Sílvia DAS Ramôa Guilherme MO Barra Ricardo VB Oliveira Márcia G de Oliveira Mateus Cossa Bluma G Soares 《Polymer International》2013,62(10):1477-1484
Electrically conducting rubbery composites based on thermoplastic polyurethane (TPU) and carbon nanotubes (CNTs) were prepared through melt blending using a torque rheometer equipped with a mixing chamber. The electrical conductivity, morphology, rheological properties and electromagnetic interference shielding effectiveness (EMI SE) of the TPU/CNT composites were evaluated and also compared with those of carbon black (CB)‐filled TPU composites prepared under the same processing conditions. For both polymer systems, the insulator–conductor transition was very sharp and the electrical percolation threshold at room temperature was at CNT and CB contents of about 1.0 and 1.7 wt%, respectively. The EMI SE over the X‐band frequency range (8–12 GHz) for TPU/CNT and TPU/CB composites was investigated as a function of filler content. EMI SE and electrical conductivity increased with increasing amount of conductive filler, due to the formation of conductive pathways in the TPU matrix. TPU/CNT composites displayed higher electrical conductivity and EMI SE than TPU/CB composites with similar conductive filler content. EMI SE values found for TPU/CNT and TPU/CB composites containing 10 and 15 wt% conductive fillers, respectively, were in the range ?22 to ?20 dB, indicating that these composites are promising candidates for shielding applications. © 2013 Society of Chemical Industry 相似文献
69.
Mateus Carlesso Renan Giacomelli Stefan Günther Dietmar Koch Stephen Kroll Stefan Odenbach Kurosch Rezwan 《Journal of the American Ceramic Society》2013,96(3):710-718
We present an interesting processing route for obtaining alumina/mullite‐based ceramics with controlled porosity and airflow resistance leading to promising microstructures for application as sound absorbers. The use of ceramic materials aims for potential applications where high temperatures or corrosive atmospheres are predominant, e.g., in combustion chambers of gas turbines. For the production of the porous ceramics we combined freeze gelation and sacrificial templating processes to produce near‐net‐shaped parts with low shrinkage (<3%) based on environmental‐friendly and low cost conditions. The obtained microstructure presents a bimodal pore size distribution, with small pores derived from the freeze gelation process (~30 μm) connecting large pores (2–5 mm diameter) originated from the expanded polystyrene template particles. These connections, called “windows” in this study, show a significant impact on the sound absorption properties, allowing the pressure diffusion effect to take place, resulting in a significant improvement of the sound absorption coefficient. By varying the template particle content and the slurry solid content, it is possible to control the sound absorption behavior at different frequencies of the open‐celled ceramics. These ceramics feature a high open porosity, from 77% to 82%, combined with sufficient compressive strength ranging from 0.27 to 0.68 MPa and sound absorption coefficients of 0.30–0.99, representing a highly promising combination of properties for noise control and reduction at corrosive environments and high temperatures. 相似文献
70.
Sintering of porous alumina obtained by biotemplate fibers for low thermal conductivity applications
Tiago Delbrücke Rogério A. Gouvêa Mário L. Moreira Cristiane W. Raubach José A. Varela Elson Longo Margarete R.F. Gonçalves Sergio Cava 《Journal of the European Ceramic Society》2013,33(6):1087-1092
In this research report, a sintering process of porous ceramic materials based on Al2O3 was employed using a method where a cation precursor solution is embedded in an organic fibrous cotton matrix. For porous green bodies, the precursor solution and cotton were annealed at temperatures in the range of 100–1600 °C using scanning electron microscopy (SEM) and thermogravimetric (TG) analysis to obtain a porous body formation and disposal process containing organic fibers and precursor solution. In a structure consisting of open pores and interconnected nanometric grains, despite the low porosity of around 40% (calculated geometrically), nitrogen physisorption determined a specific surface area of 14 m2/g, which shows much sintering of porous bodies. Energy dispersive X-ray (EDX) and X-ray diffraction (XRD) analytical methods revealed a predominant amount of α-Al2O3 in the sintered samples. Thermal properties of the sintered Al2O3 fibers were obtained by using the Laser Flash which resulted in the lower thermal conductivity obtained by α-Al2O3 and therefore improved its potential use as an insulating material. 相似文献