Flood frequency and routing processes at a confluence of the middle Yellow River in China

Floods cause environmental hazards and influence on socio‐economic activities. In this study, we evaluated the historic flood frequency at a confluence in the middle Yellow River, China. A non‐parametric, multivariate, empirical, orthogonal function matrix model, which consists of time correlation coefficients of flood discharge at different gauge stations and flood events was used for the analysis of flood frequency. The model addresses the characteristics of confluent floods such as frequency and the probability in multiple tributary rivers. Flood frequency analysis is often coupled with studies of hydrological routing processes that reduce the flood capacity of the rivers. Flood routing to the confluence were simulated using kinematic wave theory. Results of this flood frequency analysis showed that flooding frequency has intensified in the past 500 years, especially during the 19th century. Flooding in streams above the confluence was more frequent than in streams below the confluence. Over the last 2000 years, concurrent flooding in multiple tributary rivers accounted for 67.5% of the total flooding in the middle Yellow River. Simulation of flood routing processes shows that the decreased flooding capacity and elevated river bed of the shrunken main channel leads to an increased flood wave propagation time (24–52.3 h) in the study area after 1995. The model indicates that human activities, such as constructions of the Sanmenxia Dam, have changed flood routing boundary conditions and have contributed to the increased flood frequency at the confluence. Copyright © 2007 John Wiley & Sons, Ltd.     

奥氏体耐热钢21-4N碳化物析出行为研究

通过对奥氏体耐热钢21-4N碳化物析出行为的研究,探讨了对性能的影响,提出了改善其综合性能的措施和方法.     

Densitometry determination of dioxins using gold nanoparticlemodified dioxin response element probes

This study aims to develop a rapid and sensitive densitometry bioassay of dioxins. It is known that dioxin ligand can bind heterodimeric aryl hydrocarbon receptor (AhR) and trigger the formation of the complex of dioxin-AhR, AhR nuclear translocator (Arnt), and dioxin-responsive element (DRE). We have established a rapid and sensitive method using nanoparticle-modified DRE probes based on dioxin-dependent binding of DRE to AhR complex. Dioxins can trigger the binding of nanoparticle-modified DRE probe to AhR complex. The nanoparticle-modified DRE probes in the dioxin-AhR-Arnt-DRE complexes immobilized on the microplates were detected by measuring optical density after silver enhancement. Results showed that as little as 0.01 pM of TCDD could be detected. Dioxins could be quantified accurately with the linear range from 1 nM to 0.01 pM. The coefficient of variation was 5≈8% in this bioassay. The optical density of nanoparticle-based silver enhancement was produced in a dose- and time- dependent manner. The dioxin concentrations in fly ash samples determined by this bioassay were comparable with that by the standard HRGC/HRMS. Thus this bioassay is a sensitive and convenient cell-free bioassay of dioxin that is suitable for screening of dioxins in environmental or food matrices.     

现代模具技术及其进展

论述了现代模具种类和学科特点、模具工业特点、模具领域新技术、模具CAD/CAM集成化技术的发展及展望。     

填充料细度对水工沥青混凝土性能的影响

近年来沥青混凝土作为防渗材料，在我国水工建筑中得到了广泛应用。与道路工程的沥青混凝土不同的是，水工沥青混凝土具有良好的粘弹性及抗渗性。目前，国家规范对填充料的细度尚无明确规定，通过调整沥青混凝土的填充料细工，对沥青混凝土的各项性能进行了系统的试验和分析，研究表明：适宜的填充料细度及掺量，能有效地改善沥青混凝土性能，提高其抗渗性。     

乳胶厚度对卤化银反射全息图衍射特性的影响

实验研究了自制的超细颗粒卤化银乳剂SDUF－1分别在AAC显影、改进的R－10漂白处理及改进的GP－8溶解物理显影处理条件下，其乳胶厚度对反射全息图衍射特性的影响。实验结果表明，在这两种不同处理条件下衍射效率与胶厚的关系有相当大的差别，合适的乳胶厚度分别为12μm和6μm左右。     

碳酸二甲酯的市场需求和生产技术进展

介绍了碳酸二甲酯的价格、生产情况及国内外市场需求 ,指出碳酸二甲酯在我国具有极大的市场潜力。综述了生产碳酸二甲酯的三类主要方法 ,介绍了光气法、酯交换法和氧化羰基化法的各种具体方法及尚未实现工业化仍在研究中的其他方法。并对各种工业化的生产方法从技术、经济和清洁性的角度进行了分析 ,指出适合我国采用的工业合成方法是气相氧化羰基化法和甲醇与 CO2 直接合成法     

活性炭中甲烷水合物的生成动力学

在温度275．75－279．95K和压力5．6－9．6MPa的静置条件下，测定了14组甲烷水合物在活性炭中的生成动力学数据（压力－时间关系），分析了甲烷水合物在活性炭中生成的物理过程，结合边界层理论和结晶学原理，提出了单液膜传质控制机理的生成动力学模型，并求得了解析解,使用Levenberg-Marquardt方法拟合模型参数，模型预测值与实验值符合良好。     

凝析气藏物质平衡方程的改进与应用

为了提高凝析气藏油气采收率，通常采用目前最有效的循环注气保持地层压力的开采方式。在此开采方式下，直接采用气藏物质平衡方程进行地质储量计算将出现很大偏差。针对这种情况，将气藏物质平衡方程进行了改进，得到凝析气藏在注气开发方式下的物质平衡方程。     

真空热处理工艺参数的选取

通过多种材料、多种工件、多批次的加工，对常见真空热处理工艺参数的确定，摸索出一些经验公式，并在实际生产中取得很好效果。