Atomic layer deposition of calcium oxide and calcium hafnium oxide films using calcium cyclopentadienyl precursor

Calcium oxide and calcium hafnium oxide thin films were grown by atomic layer deposition on borosilicate glass and silicon substrates in the temperature range of 205–300 °C. The calcium oxide films were grown from novel calcium cyclopentadienyl precursor and water. Calcium oxide films possessed refractive index 1.75–1.80. Calcium oxide films grown without Al₂O₃ capping layer occurred hygroscopic and converted to Ca(OH)₂ after exposure to air. As-deposited CaO films were (200)-oriented. CaO covered with Al₂O₃ capping layers contained relatively low amounts of hydrogen and re-oriented into (111) direction upon annealing at 900 °C. In order to examine the application of CaO in high-permittivity dielectric layers, mixtures of Ca and Hf oxides were grown by alternate CaO and HfO₂ growth cycles at 230 and 300 °C. HfCl₄ was used as a hafnium precursor. When grown at 230 °C, the films were amorphous with equal amounts of Ca and Hf constituents (15 at.%). These films crystallized upon annealing at 750 °C, showing X-ray diffraction peaks characteristic of hafnium-rich phases such as Ca₂Hf₇O₁₆ or Ca₆Hf₁₉O₄₄. At 300 °C, the relative Ca content remained below 8 at.%. The crystallized phase well matched with rhombohedral Ca₂Hf₇O₁₆. The dielectric films grown on Si(100) substrates possessed effective permittivity values in the range of 12.8–14.2.     

About the influence of the content and composition of the aggregates on the rheological behaviour of self-compacting concrete

Within the scope of a parameter study the influence of the mixture composition of different self-compacting concretes on the fresh concrete properties was investigated. For this purpose the standard test methods as well as the fresh concrete rheometer “BTRHEOM” were used. The concrete was modelled as a two-phase system, consisting of the fluid phase paste and the solid phase aggregates. The consistency control parameters paste volume, mortar volume and the coarse aggregate volume could be transferred into the model parameter thickness of excess paste. By means of this model parameter the characteristic values of the standard test methods like slump flow test and V-funnel test as well as the fundamental rheological parameters yield stress and the plastic viscosity could be described. A comparative study showed that the yield stress and the plastic viscosity of self-compacting concrete can be estimated based on the characteristic values of the slump flow test.     

Normalising OLAP cubes for controlling sparsity

A poorly designed OLAP (on-line analytical processing) cube can have a size much larger than the volume of information, potentially leading to problems with performance and usability. We give a new normal form for OLAP cube design and synthesis and decomposition algorithms to produce normalised OLAP cube schemata. OLAP cube normalisation controls the structural sparsity resulting from inter-dimensional functional dependencies. We assume that functional dependencies are used to describe the constraints of the application universe of discourse. Our methods help the user to identify cube schemata with structural sparsity, and to change the design in order to obtain more economy of space.     

Analysis of class E amplifier with both linear and nonlinear shunt capacitance at any duty cycle,grading coefficient and supply modulation

This work studies the effects of the drain pn capacitance grading coefficient, duty cycle and supply modulation on the operation of class E amplifier. The class E operation analysis with a combination of nonlinear and linear output capacitances is revisited and duty cycle is added to the equations to allow further investigations for optimum class E circuit tuning. The presented analysis method can be used for synthesis as well, where necessary load components are calculated for a transistor with a specific grading coefficient both in the output capacitance and in the nonlinear feedback capacitance. Further, the grading coefficient of the nonlinear output capacitance is varied in the paper while investigating the changes in normalized peak voltages and harmonics. Drain efficiency, supply-to-amplitude modulation (V _dd /AM) and supply-to-phase modulation (V _dd /PM) are studied. It is shown that by varying the device duty cycle, one can scale the optimum load and the level of peak voltages over the switching device. Also, the choice of grading coefficient affects the drain efficiency, V _dd /AM and V _dd /PM behaviour of the class E amplifier. Last, a case study about increasing the efficiency of a class E amplifier with hyperabrupt output junction capacitance is shown.     

Partial electrode method for loss and physical parameter determination of piezoceramics: Simplification,error investigation and applicability

The IEEE standard to determine physical parameters of piezoceramics has been utilized for decades by many researchers, yet it omits presence of important loss factors and possesses serious deficits that restrict accurate parameter determination. To resolve these issues, the partial electrode (PE) method was previously proposed, though the focus has been merely made on development of the method itself. In this study, we provide method simplification and more detailed analysis. The omission of unnecessary samples greatly boosts experiment and analysis process. To prove that the PE method is reliable, possible causes of errors were investigated; it is shown that they were either negligibly small or can be resolved with proper calibration. Furthermore, Applicability of PE method to various types of piezoceramic materials and compatibility with impedance analyzers are shown. Finally, PE method is proved to be reliable and can be alternative to IEEE Standard on Piezoelectricity.     

The association of distress and sleeping problems with physicians’ intentions to change profession: The moderating effect of job control.

The present study examined whether job control moderated the association between stress indicators (distress and sleeping problems) and intentions to change profession among 2,650 Finnish physicians. Ordinal logistic regression analysis was applied. The authors found that high levels of distress and sleeping problems were associated with higher levels of intentions to change profession, whereas high job control was associated with lower levels of intentions to change profession even after adjusting for the effects of gender, age, and employment sector. In addition, high job control was able to mitigate the positive association that distress and sleeping problems had with intentions to change profession. Our findings highlight the importance of offering more job control to physicians to prevent unnecessary physician turnover. (PsycINFO Database Record (c) 2010 APA, all rights reserved)