Incremental constraint modelling in a feature modelling system

The techniques of constraint propagation have recently been successfully applied to feature-based design. Because of their speed, constraint propagation methods allow incremental design and rapid local modifcations of the part. However, cyclic constraints cause serious problems to current constraint propagation algorithms. Variational geometric design systems can, in principle, manage these cases. Unfortunately, this typically requires complete re-evaluation of the underlying set of constraint equations, making the method unsuitable for interactive use. The proposed system aims to localize the problem of constraint solving and maintenance. The constraint graph of the part or assembly is divided into several independent partial graphs, subsystems. Afterwards, each subsystem is handled separately using a selected constraint solving technique for the subsystem.     

Depressive vulnerability in parents and their 5-year-old child's temperament: A family system perspective.

The actor-partner interdependence model was used to test whether one parent's depressive vulnerability (self-criticism and dependency) was associated with the same parent's own (an intraparental association) and the other parent's (a cross-parental association) ratings of their 5-year-old child's temperament (536 parents, 268 dyads). The more vulnerable the parents were, the more the children showed negative affectivity and lack of effortful control. Significant interactions with the parent's gender and between the spouses' depressive vulnerabilities were found, highlighting the fact that child outcomes are dependent on family processes. All associations were independent of maternal and paternal depressive symptoms. The influence of personality-based depressive traits on child temperamental outcomes and effective parenting is discussed with reference to between-dyad family dynamics. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Hot electron-induced cathodic electrochemiluminescence of rhodamine B at disposable oxide-coated aluminum electrodes

Rhodamine B (RhB) exhibits strong cathodic electrogenerated chemiluminescence (ECL) in aqueous solutions during high-amplitude pulse polarization at thin oxide film-coated aluminum electrodes. This method allows the detection of RhB below nanomolar concentration level and provides linear calibration plots spanning over several orders of magnitude of concentration. In addition, a relatively long ECL lifetime of RhB provides a basis for time-resolved detection. Thus, widely used RhB-based labels can also be suggested to be usable as electrochemiluminescent labels in fully aqueous solutions in bioaffinity assays such as in immunoassays and DNA-probing assays. Support was obtained for the chemiluminescence generation mechanism to be essentially the same as that of radiochemiluminescence in aqueous solution.     

The effect of reaction conditions on the oxidation of veratryl alcohol catalyzed by cobalt salen-complexes

Cobalt salen-type [salen=N,N′-bis(salicylidene)ethylenediamine] complexes 1–6 were studied as catalysts for dioxygen activation in the oxidation of veratryl alcohol in basic aqueous conditions. The complexes Co(salen) (1), Co(CH₃salen) (2) [CH₃salen=N,N′-bis(methylsalicylidene)ethylenediamine], Co(4OHsalen) (3) [4OHsalen=N,N′-bis(4-hydroxosalicylidene)ethylenediamine], Co(sulfosalen) (4) [sulfosalen=N,N′-bis(5-sulfonatosalicylidene)ethylenediamine], Co(acacen) (5) [acacen=N,N′-bis(acetylacetone)ethylenediamine) and Co(N-Me-salpr) (6) [N-Me-salpr=bis(salicylideniminato-3-propyl)methylamine] were chosen to examine the influence of ligand structure on the catalytic activity. The effect of reaction conditions on the oxidation of veratryl alcohol was studied by varying temperature, pH, time or the nature and amount of the axial base needed to enhance the activity of complexes 1–5. The catalytic behaviour of the studied complexes was shown to be very depended on the applied conditions and distinct differences could be observed among the complexes. In all reactions, veratraldehyde was the only product observed. The unsubstituted complex 1 was the most efficient catalyst in the studied system achieving turnover numbers of up to 28 at 80 °C and pH 12.5.     

Optimization of metallurgical variables in fracture prevention

The effect of metallurgical variables on the two most important crack growth mechanisms - stable crack growth by environmentally assisted cyclic crack growth and unstable crack growth by cleavage - in light water reactor pressure vessel steels is evaluated. The analyses are based on micromechanisms of fracture and sensitivity analysis, when applicable. Metallurgical variables considered are non-metallic inclusions and carbides as well as other parameters through their effects on yield strength and other mechanical properties.     

Testing endocrine disruption in biota samples: a method to remove interfering lipids and natural hormones

A cleanup method was developed to remove coextracted lipids and natural hormones from biota samples in order to test the endocrine-disrupting (ED) capacity of their extracts in in vitro bioassays. Unspiked and spiked fish tissues were cleaned with a combination of dialysis, gel permeation chromatography (GPC), and normal-phase liquid chromatography (NP-HPLC). The spiking mixture consisted of a broad range of environmental pollutants (endocrine disruptors and genotoxic compounds). Chemical recoveries of each test compound, and thyroid-hormone-like and (anti)androgenic activities of the cleaned extracts were investigated. Despite the chemical and toxicological complexity of the spiking mixture and the sequential sample treatment, chemical analysis revealed acceptable recoveries on average: 89 ± 8% after each cleanup step separately and 75 ± 3% after the whole extraction and cleanup procedure in the extracts. In addition, recovered activities in the bioassays were in good agreement with the spiking levels. The developed cleanup method proved to be capable of lipid and natural hormone removal from fish extracts, enabling the measurement of selected endocrine-hormone-like activities in T(4)*-TTR and AR-CALUX bioassays. The method can be used as a sample preparation method of biota samples for toxicity profiling and effect-directed analysis (EDA).     

Aerobic Oxidation of Benzylic Alcohols in Water by 2,2,6,6‐Tetramethylpiperidine‐1‐oxyl (TEMPO)/Copper(II) 2‐N‐Arylpyrrolecarbaldimino Complexes

Novel copper(II) 2‐N‐arylpyrrolecarbaldimine‐based catalysts for the aerobic oxidation of benzylic alcohols mediated by the 2,2,6,6‐tetramethylpiperidine‐1‐oxyl (TEMPO) radical are reported. The catalytic activity for both synthesized and in situ made complexes in alkaline water solutions was studied revealing high efficiency and selectivity (according to GC selectivity always >99%) for both of these catalytic systems. For example, quantitative conversion of benzyl alcohol to benzaldehyde can be achieved with the in situ prepared bis[2‐N‐(4‐fluorophenyl)‐pyrrolylcarbaldimide]copper(II) catalysts in 2 h with atmospheric pressure of O₂ at 80 °C. Interestingly, these catalysts can utilize dioxygen as well as air or hydrogen peroxide as the end oxidants, producing water as the only by‐product.     

Generation of urban road dust from anti-skid and asphalt concrete aggregates

Road dust forms an important component of airborne particulate matter in urban areas. In many winter cities the use of anti-skid aggregates and studded tires enhance the generation of mineral particles. The abrasion particles dominate the PM10 during springtime when the material deposited in snow is resuspended. This paper summarizes the results from three test series performed in a test facility to assess the factors that affect the generation of abrasion components of road dust. Concentrations, mass size distribution and composition of the particles were studied. Over 90% of the particles were aluminosilicates from either anti-skid or asphalt concrete aggregates. Mineral particles were observed mainly in the PM10 fraction, the fine fraction being 12% and submicron size being 6% of PM10 mass. The PM10 concentrations increased as a function of the amount of anti-skid aggregate dispersed. The use of anti-skid aggregate increased substantially the amount of PM10 originated from the asphalt concrete. It was concluded that anti-skid aggregate grains contribute to pavement wear. The particle size distribution of the anti-skid aggregates had great impact on PM10 emissions which were additionally enhanced by studded tires, modal composition, and texture of anti-skid aggregates. The results emphasize the interaction of tires, anti-skid aggregate, and asphalt concrete pavement in the production of dust emissions. They all must be taken into account when measures to reduce road dust are considered. The winter maintenance and springtime cleaning must be performed properly with methods which are efficient in reducing PM10 dust.     

美卓超滤膜技术——提高水和涂料的循环利用率

造纸行业日趋承受着节水、节能以及环保的压力。也就是说,造纸企业必须寻找新技术,将注意力转移到生产中的整个水质和高效的原料回收系统上。     

Application of a Technofunctional Caseinate Hydrolysate to Replace Surfactants in Ice Cream

There is a demand for a clean label of ice cream in the food industry. To meet this requirement, alternative surfactants and hydrocolloids without an additive number have to be found. Here, a caseinate hydrolysate with improved interfacial properties was investigated as such an additive. Replacing only the surfactant resulted in ice cream characteristics, comparable to using a commercial emulsifier (INS 472b). Thus, a clean labeling of the surfactant using this hydrolysate is possible. By contrast, replacing the hydrocolloid additionally led to an unfavorable ice cream texture and stability.