Improvement of Creep Resistance at 950 °C and 400 MPa in Ru-Containing Single-Crystal Superalloys with a High Level of Co Addition

Microstructural features, including γ′ volume fraction and size, γ-γ′ lattice misfit, γ channel width, and dislocation substructure, are known to significantly influence the creep performance in Ni-base single-crystal superalloys. In this study, the microstructural characteristics of Ru-containing single-crystal superalloys with different levels of Co, Mo, and Ru additions were quantitatively investigated after ruptured and interrupted creep tests conducted at 1223 K (950 °C) and 400 MPa. The creep lifetime was slightly increased with the high level of Co addition and significantly increased with the coadditions of Mo and Ru. A minor effect of Co content on the γ channel width and γ′ volume fraction was found in experimental alloys. The alloy with high levels of Mo and Ru additions was determined to possess a more negative γ-γ′ lattice misfit, and a high density of stacking faults (SFs) was formed in the γ channels during creep. The combined effects of the SFs in the γ matrix serving as the barriers to dislocation movement, as well as the dense interfacial dislocation networks preventing dislocation to shear the γ′ phase, were considered as the main mechanism responsible for the improvement of creep resistance. Results from this study are helpful to understand the effect of microstructural features on creep performance and contribute to the knowledge of physical metallurgy in Ru-containing single-crystal superalloys.     

Effects of Microwave on Drug Release Property of Poly(Methyl Vinyl Ether-co-Maleic Acid) Matrix

ABSTRACT

The drug release behavior of beads made of poly(methyl vinyl ether-co-maleic acid) was investigated with respect to the influence of microwave irradiation. The beads were prepared by an extrusion method with sodium diclofenac as a model water-soluble drug. The beads were subjected to microwave irradiation at 80 W for 5 and 20 min, and at 300 W for 1 min 20 s and 5 min 20 s. The profiles of drug dissolution, drug content, drug-polymer interaction, and polymer-polymer interaction were determined by using dissolution testing, drug content assay, differential scanning calorimetry, and Fourier transform infra-red spectroscopy. Keeping the level of supplied irradiation energy identical, treatment of beads by microwave at varying intensities of irradiation did not bring about similar drug release profiles. The extent and rate of drug released from beads were markedly enhanced through treating the samples by microwave at 80 W as a result of loss of polymer-polymer interaction via the (CH₂)_n moiety, but decreased upon treating the beads by microwave at 300 W following polymer-polymer interaction via the O-H, COOH, and COO^? moieties as well as drug-polymer interaction via the N-H, O-H, COO^?, and C-O moieties. The beads treated by microwave at 300 W exhibited a higher level of drug release retardation capacity than those that were treated by microwave at 80 W in spite of polymer-polymer interaction via the (CH₂)_n moiety was similarly reduced in the matrix. The mechanism of drug release of both microwave-treated and untreated beads tended to follow zero order kinetics. The drug release was markedly governed by the state of polymer relaxation of the matrix and was in turn affected by the state of polymer-polymer and/or drug-polymer interaction in beads.     

Graft copolymerization of p‐acryloyloxybenzoic acid and p‐methacryloyloxybenzoic acid onto isotactic polypropylene and their thermal properties: Part I

The polymerization and grafting of the monomers p‐acryloyloxybenzoic acid and p‐methacryloyloxybenzoic acid were studied. Poly(acryloyloxybenzoic acid) was obtained by γ‐radiation‐induced solution polymerization and bulk melt polymerization initiated by dicumyl peroxide. Poly(methacryloyloxybenzoic acid) could be obtained only by bulk melt polymerization. The graft copolymerization of the monomers onto isotactic polypropylene was carried out in bulk. The maximum grafting was reached in shorter times at higher temperatures, and it also increased with the concentration of the monomers in the reaction medium. The thermal and crystallization behavior of the graft copolymers was studied with differential scanning calorimetry and wide‐angle X‐ray diffraction. The graft copolymerization of p‐acryloyloxybenzoic acid did not have any influence on the formation of both α forms (monoclinic) of polypropylene, whereas p‐methacryloyloxybenzoic acid led to the α₂ form. The β‐crystalline modification (hexagonal) formed in poly(acryloyloxybenzoic acid)‐g‐polypropylene products at 185°C and at higher grafting temperatures and also in the second run of differential scanning calorimetry studies after fast cooling. The β form was not observed in graft copolymers of poly(methacryloyloxybenzoic acid). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

层式通风——高温空调下的出路

节能减排是当前全球性的呼声。作为回应,东亚区域的若干个政府都提倡采用更高的夏季空调温度。要推广高温空调,就必须使公众相信,这样做不会降低室内环境品质,尤其是不会降低热舒适性。要实施高温空调,就必须筛选出在这样的非常规工况下性能良好的通风系统。因其在较高室温下的良好性能,本文以数间香港办公室为例,介绍并分析一种新型通风系统——层式通风。实验和模拟计算的结果显示,如果送风速度,送风量和送、排风口的设计正确,层式通风具有热舒适性好（具体表现为头脚温差小）、能耗低、特别是呼吸区空气品质好的特点。下一步的工作将对上述优点进行定量研究。     

Co Effect on As-cast and Heat-Treated Microstructures in Ru-Containing Single-Crystal Superalloys

The effect of Co on the as-cast and heat-treated microstructures was investigated in two experimental Ni-based single-crystal superalloys containing low levels of Re and Ru. The experimental results indicated that increasing the Co content from 7.9 to 15.8 wt pct decreased the volume fraction of (γ + γ′) eutectic and the solidification segregation ratio of W. High levels of Co additions were also found to decrease the solvus temperatures of the γ′ phase and (γ + γ′) eutectic as well as the solidus temperature. During the long-term thermal exposure at 1373 K (1100 °C), no TCP phases precipitated in either alloy. However, the coarsening and coalescence of γ′ precipitates in the alloy containing 15.8 wt pct Co was slower than that in the other alloy with 7.9 wt pct Co. In the current study, high levels of Co additions decreased the equilibrium volume fraction of γ′ phase, leading to a change in the partitioning ratios of TCP-forming elements Cr, Mo, Re, and W between the γ and γ′ phases. This change resulted in a lower degree of elemental supersaturation in the γ matrix and improved the phase stability of the γ/γ′ microstructure. These experimental results were then compared with those obtained from multi-component thermodynamic calculations, and good agreement was observed.     

Kinetics of Sub-Micron Grain Size Refinement in 9310 Steel

Recent efforts have focused on the development of novel manufacturing processes capable of producing microstructures dominated by sub-micron grains. For structural applications, grain refinement has been shown to enhance mechanical properties such as strength, fatigue resistance, and fracture toughness. Through control of the thermo-mechanical processing parameters, dynamic recrystallization mechanisms were used to produce microstructures consisting of sub-micron grains in 9310 steel. Starting with initial bainitic grain sizes of 40 to 50 μm, various levels of grain refinement were observed following hot deformation of 9310 steel samples at temperatures and strain rates ranging from 755 K to 922 K (482 °C and 649 °C) and 1 to 0.001/s, respectively. The resulting deformation microstructures were characterized using scanning electron microscopy and electron backscatter diffraction techniques to quantify the extent of carbide coarsening and grain refinement occurring during deformation. Microstructural models based on the Zener–Holloman parameter were developed and modified to include the effect of the ferrite/carbide interactions within the system. These models were shown to effectively correlate microstructural attributes to the thermal mechanical processing parameters.     

BZn18—20锌白铜圆线断裂原因分析

针对ＢＺｎ１８－２０锌白铜圆线实际生产中存在的质量问题,分析探讨了各生产工序中影响产品质量的因素,并以此提出解决措施,收效良好。     

自限温型PTC电热带的性能评价

简要介绍了自限温型 PTC(正温度系数 )电热带的结构、工作原理及性能特点 ;重点论述了其作为防冻保温器件的主要性能标准及评价方法 ,为自限温电热带规范化生产提供指导。     

The effect of resin finish on the dimensional stability of cotton knitted fabric

In this article, the effect of resin finish on the degree of set is discussed. Furthermore, the relationship of the degree of set and dimensional stability is analyzed. After relaxation treatments, the yarns in a fabric would be set at a certain level. As the fabric is subjected to prolonged relaxation treatments, the yarn will become more set until the shape of the unraveled yarn is similar to the shape of the loop in the fabric. The yarn that is removed from a knitted fabric has a curvature value close to zero, and the curvature is exactly as the corresponding position at the knitted loop. From previous research, it is known that the degree of set affects the dimensional properties in a plain knitted fabric. In this article, the degree of set increases with resin level. It explains why the resin finish can stabilize the dimensional properties indirectly.     

A direct complementarity approach for the elastoplastic analysis of plane stress and plane strain structures

This paper presents a direct complementarity approach for carrying out the elastoplastic analysis of plane stress and plane strain structures. Founded on a traditional finite‐step formulation, our approach, however, avoids the typically cumbersome implementation of iterative predictor–corrector procedures associated with the ubiquitous return mapping algorithm. Instead, at each predefined step, the governing formulation—cast in its most natural mathematical programming format known as a mixed complementarity problem—is directly solved by using a complementarity solver run from within a mathematical modeling system. We have chosen the industry‐standard General Algebraic Modeling System/PATH mixed complementarity problem solver that is called from within the General Algebraic Modeling System environment. We consider both von Mises and Tresca materials, with perfect or hardening (kinematic and isotropic) behaviors. Our numerical tests, five (benchmark) examples of which are presented in this paper, have been carried out using models constructed from the mixed finite element of Capsoni and Corradi (Comput. Methods Appl. Mech. Eng. 1997; 141 :67–93), which beneficially offers a locking‐free behavior and coarse‐mesh accuracy. The results indicate, in addition to an isochoric locking‐free behavior, good accuracy and the ability to circumvent the difficult singularity problem associated with the corners of Tresca yield surfaces. Copyright © 2012 John Wiley & Sons, Ltd.