Electron transfer capacities and reaction kinetics of peat dissolved organic matter

Information about electron-transfer reactions of dissolved organic matter (DOM) is lacking. We determined electron acceptor and donor capacities (EAC and EDC) of a peat humic acid and an untreated peat DOM by electrochemical reduction and reduction with metallic Zn and H2S (EAC), and by oxidation with complexed ferric iron (EDC) at pH 6.5. DOC concentrations (10-100 mg L(-1)) and pH values (4.5-8) were varied in selected experiments. EAC reached up to 6.2 mequiv x (g C)(-1) and EDC reached up to 1.52 mequiv-(g C)(-1). EDC decreased with pH and conversion of chelated to colloidal iron, and the electron-transfer capacity (ETC) was controlled by the redox potential Eh of the reactant (ETC = 1.016x Eh - 0.138; R(2) = 0.87; p = 0.05). The kinetics could be adequately described by pseudo first-order rate laws, one or two DOM pools, and time constants ranging from 2.1 x 10(-3) d-1 to 1.9 x 10(-2) d(-1) for the fast pool. Reactions were completed after 24-160 h depending on the redox couple applied. The results indicate that DOM may act as a redox buffer over electrochemical potentials ranging from -0.9 to +1.0 V.     

Stability of rare‐earth‐doped spherical yttria‐stabilized zirconia synthesized by ultrasonic spray pyrolysis

Phase stability is one of the crucial requirements for any material that can be used at elevated temperature applications such as thermal barrier coating (TBC). The most traditional TBC material, partially stabilized zirconia, limits the operating temperature due to its phase transformation. Conversely, the low thermal conductivity of fully stabilized zirconia (YSZ) may enable effective reduction in the surface temperature on the coated component, while avoiding deleterious phase transitions, although still being subjected to sintering and grain growth. It has been reported that addition of rare‐earths as dopants to YSZ can significantly increase resistance to grain growth at high temperature. Keeping this under consideration, this work investigates the role of rare‐earths (lanthanum and gadolinium) in increasing thermal stability of YSZ microspheres, the building blocks for high‐temperature photonics for reflective TBC. The spheres were produced by ultrasonic spray pyrolysis, and the doping led to significant improvement of stability by significant inhibition of grain growth. While the individual dopants showed significant growth and sintering inhibition up to 900°C, co‐doping with 4% (in mol) of each (Gd and La) led to coarsening resistance up to 1000°C for 3 hours, when particles retained reasonable spherical features with nanometric crystallite sizes.     

Two‐Step Protein Labeling by Using Lipoic Acid Ligase with Norbornene Substrates and Subsequent Inverse‐Electron Demand Diels–Alder Reaction

Inverse‐electron‐demand Diels–Alder cycloaddition (DA_inv) between strained alkenes and tetrazines is a highly bio‐orthogonal reaction that has been applied in the specific labeling of biomolecules. In this work we present a two‐step labeling protocol for the site‐specific labeling of proteins based on attachment of a highly stable norbornene derivative to a specific peptide sequence by using a mutant of the enzyme lipoic acid ligase A (LplA^W37V), followed by the covalent attachment of tetrazine‐modified fluorophores to the norbornene moiety through the bio‐orthogonal DA_inv . We investigated 15 different norbornene derivatives for their selective enzymatic attachment to a 13‐residue lipoic acid acceptor peptide (LAP) by using a standardized HPLC protocol. Finally, we used this two‐step labeling strategy to label proteins in cell lysates in a site‐specific manner and performed cell‐surface labeling on living cells.     

Combining Acoustic Emission and Vibration Technologies Harbors Huge Potential for Material Characterization

The demand for raw materials is growing worldwide, in step with increasing world population and rising living standards of emerging countries. It is becoming more difficult to exploit primary raw materials because of declining ore grades and increasingly complicated mineralogies. Thus, the efficient and environmentally sustainable exploitation of primary resources using innovative technologies has emerged as an important research field to address these issues. An innovative approach is introduced to optimize process and quality control by combining acoustic emission (AE) and vibration technology. The general feasibility of these two technologies for material recognition and characterization is examined. The new approach was tested to determine whether coal could be distinguished from waste rock.     

Changes in volatile composition during fruit development and ripening of ‘Alphonso’ mango

BACKGROUND: Volatile blends of five developing and five ripening stages of mango (Mangifera indica L. cv. Alphonso) were investigated along with those of flowers and leaves. Raw and ripe fruits of cv. Sabja were also used for comparison. RESULTS: A total of 55 volatiles belonging to various chemical classes such as aldehydes, alcohols, mono‐ and sesquiterpene hydrocarbons, lactones and furanones were identified. In all Alphonso tissues monoterpenes quantitatively dominated, with 57–99% contribution; in particular, (Z)‐ocimene was found in the highest amount. Ripeness was characterized by the de novo appearance of lactones and furanones in the blend of monoterpenes. Sabja was distinguished by the abundance of monoterpene hydrocarbons in the raw fruit, and that of sesquiterpene hydrocarbons and their derivatives in the ripe stage. CONCLUSION: Various stages of the Alphonso fruit during transition from flower to ripe fruit are characterized by unique volatile signatures that are distinguished from each other by the qualitative and quantitative appearance of different volatile compounds. Thus volatiles can be highly informative markers while studying the development and ripening of mango. Copyright © 2009 Society of Chemical Industry     

A genetic algorithm for the two-dimensional knapsack problem with rectangular pieces

Given a set of rectangular pieces and a rectangular container, the two-dimensional knapsack problem (2D-KP) consists of orthogonally packing a subset of the pieces within the container such that the sum of the values of the packed pieces is maximized. If the value of a piece is given by its area, the objective is to maximize the covered area of the container. A genetic algorithm (GA) is proposed addressing the guillotine case of the 2D-KP as well as the non-guillotine case. Moreover, an orientation constraint may optionally be taken into account and the given piece set may be constrained or unconstrained. The GA is subjected to an extensive test using well-known benchmark instances. Compared with recently published methods, the GA yields competitive results.     

Consumption behavior and the aspiration for conformity and consistency.

The (socio-)psychological concepts of individual aspiration for conformity and consistency are integrated into the rational choice framework. By using this integrative approach, it is shown that, after a shock, the aspiration for conformity results in a steady state that deviates from the homo oeconomicus's behavior toward the consumption of the peer group, whereas the aspiration for consistency leads to the result that the steady-state consumption is not reached at once. With the combination of these effects, a new consumption path is derived. After a shock, the individual consumption converges step by step to the new steady-state consumption. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

All-solid-state tunable continuous-wave ultraviolet source with high spectral purity and frequency stability

We present a novel approach for the generation of higly frequency-stable, widely tunable, single-frequency cw UV light that is suitable for high-resolution spectroscopy. Sum-frequency generation (SFG) of two solid-state sources with a single cavity resonant for both fundamental waves is employed. Using a highly stable, narrow-linewidth frequency-doubled cw Nd:YAG laser as a master laser and slaving to it the SFG cavity and the other fundamental wave from a Ti:sapphire laser, we generate UV radiation of 33-mW output power around 313 nm. Alternatively, we use a diode laser instead of the Ti:sapphire laser and produce an output power of 2.1 mW at 313 nm. With both setups we obtain a continuous tunability of >15 GHz, short-term frequency fluctuations in the submegahertz range, a long-term frequency drift below 100 MHz/h, and stable operation for several hours. The theory of optimized doubly resonant SFG is also given.     

Vector Image Segmentation by Piecewise Continuous Approximation

In this article we present an approach to the segmentation problem by a piecewise approximation of the given image with continuous functions. Unlike the common approach of Mumford and Shah in our formulation of the problem the number of segments is a parameter, which can be estimated. The problem can be stated as: Compute the optimal segmentation with a fixed number of segments, then reduce the number of segments until the segmentation result fulfills a given suitability. This merging algorithm results in a multi-objective optimization, which is not only resolved by a linear combination of the contradicting error functions. To constrain the problem we use a finite dimensional vector space of functions in our approximation and we restrict the shape of the segments. Our approach results in a multi-objective optimization: On the one hand the number of segments is to be minimized, on the other hand the approximation error should also be kept minimal. The approach is sound theoretically and practically: We show that for L ²-images a Pareto-optimal solution exists and can be computed for the discretization of the image efficiently.