The Effect of Ageing on Exciton Dynamics,Charge Separation,and Recombination in P3HT/PCBM Photovoltaic Blends

A study of how light‐induced degradation influences the fundamental photophysical processes in the active layer of poly(3‐hexylthiophene)/[6,6]‐phenyl C₆₁‐butyric acid methyl ester (P3HT/PCBM) solar cells is presented. Non‐encapsulated samples are systematically aged by exposure to AM 1.5 illumination in the presence of dry air for different periods of time. The extent of degradation is quantified by the relative loss in the absorption maximum of the P3HT, which is varied in the range 0% to 20%. For degraded samples an increasing loss in the number of excitons within the P3HT domains is observed with longer ageing periods. This loss occurs rapidly, within the first 15 ps after photoexcitation. A more pronounced decrease in the population of polarons than excitons is observed, which also occurs on a timescale of a few picoseconds. These observations, complemented by a quantitative analysis of the polaron and exciton population dynamics, unravel two primary loss mechanisms for the performances of aged P3HT/PCBM solar cells. One is an initial ultrafast decrease in the polaron generation, apparently not related to the exciton diffusion to the polymer/fullerene interface; the second, less significant, is a loss in the exciton population within the photoexcited P3HT domains. The steady‐state photoinduced absorption spectra of degraded samples exhibits the appearance of a signal ascribed to triplet excitons, which is absent for non‐degraded samples. This latter observation is interpreted considering the formation of degraded sites where intersystem crossing and triplet exciton formation is more effective. The photovoltaic characteristics of same blends are also studied and discussed by comparing the decrease in the overall power conversion efficiency of solar cells.     

Integration von Energiemarkt und Verteilnetzbetrieb durch einen Flexibility Operator

The growing share of volatile distributed generation in the electric power grids results in increased local network utilisation and challenges the conventional strategies for maintaining the system balance. While grid extensions and smart grid solutions are considered for network utilisation issues, new market mechanisms are in focus for the balancing challenge. It can be expected that distributed generators on one hand will be able to supply only part of their available power to the grid in peak times, and on the other hand will have (potentially changing) contracts with different trans-regional virtual power plants. Against this background it will be necessary to define rules dealing with expected network access conflicts. One strategy also followed in this work is to find market mechanisms that support economically efficient network extension. Such mechanisms will have to include local flexibility markets that allow for compensating network bottlenecks. This work proposes strategies and technical interfaces for coordinating market and grid operation by means of a “Flexibility Operator”. Its integration into a holistic smart grid concept is discussed.     

On considering hierarchical modulation in the porting process of legacy waveforms to software defined radio

The novel software defined radio (SDR) technology allows taking the next step in the evolution of military tactical communications. SDRs allow military radio operators to change waveforms on-the-fly according to the mission needs. On the one hand, new wideband networking waveforms will offer new services like high data throughputs and mobile ad-hoc networking capabilities. On the other hand, legacy waveforms will ensure interoperability to legacy equipment in missions where both types of radios are deployed at the same time. In this article, we analyze if an added value can be provided to the operators at SDRs hosting an ‘enhanced’ legacy waveform. This enhancement shall be introduced such that interoperability to the legacy equipment is still guaranteed. The modern concept of hierarchical modulation allows fulfilling this side constraint. While the legacy waveform acts as base-layer, some enhancement-layers offer extra bit budget to transmit additional information. This spare bit budget can be exploited to increase the data rate (i.e. throughput), the error robustness (and with this communication range), or both.     

Molecular Origin of the Charge Carrier Mobility in Small Molecule Organic Semiconductors

Small‐molecule organic semiconductors are used in a wide spectrum of applications, ranging from organic light emitting diodes to organic photovoltaics. However, the low carrier mobility severely limits their potential, e.g., for large area devices. A number of factors determine mobility, such as molecular packing, electronic structure, dipole moment, and polarizability. Presently, quantitative ab initio models to assess the influence of these molecule‐dependent properties are lacking. Here, a multiscale model is presented, which provides an accurate prediction of experimental data over ten orders of magnitude in mobility, and allows for the decomposition of the carrier mobility into molecule‐specific quantities. Molecule‐specific quantitative measures are provided how two single molecule properties, the dependence of the orbital energy on conformation, and the dipole‐induced polarization determine mobility for hole‐transport materials. The availability of first‐principles based models to compute key performance characteristics of organic semiconductors may enable in silico screening of numerous chemical compounds for the development of highly efficient optoelectronic devices.     

Selective Functionalization of Microstructured Surfaces by Laser‐Assisted Particle Transfer

Microcavity arrays represent millions of different reaction compartments to screen, for example, molecular interactions, exogenous factors for cells or enzymatic activity. A novel method is presented to selectively synthesize different compounds in arrays of microcavities with up to 1 000 000 cavities per cm². In this approach, polymer microparticles with embedded pre‐activated monomers are selectively transferred into microcavities with laser radiation. After particle patterning, heating of the particle matrix simultaneously leads to diffusion and coupling of the monomers inside each microcavity separately. This method exhibits flexibility, not only in the choice of compounds, but also in the choice of particle matrix material, which determines the chemical reaction environment. The laser‐assisted selective functionalization of microcavities can be easily combined with the intensively growing number of laser applications for patterning of molecules and cells, which is useful for the development of novel biological assays.     

A Low Temperature Route toward Hierarchically Structured Titania Films for Thin Hybrid Solar Cells

The requirement of high‐temperature calcination for titanium dioxide in (solid‐state) dye‐sensitized solar cells (DSSCs) implies challenges with respect to reduced energy consumption and the potential for flexible photovoltaic devices. Moreover, the use of dye molecules increases production costs and leads to problems related with dye bleaching. Therefore, fabrication of dye‐free hybrid solar cells at low temperature is a promising alternative for current DSSC technology. In this work the authors fabricate hierarchically structured titania thin films by combining a polystyrene‐block‐polyethylene oxide template assisted sol–gel synthesis with nano‐imprint lithography at low temperatures. The achieved films are filled with poly(3‐hexylthiophene) to form the active layer of hybrid solar cells. The surface morphology is probed via scanning electron microscopy and atomic force microscopy, and the bulk film morphology is examined with grazing incidence X‐ray scattering. Good light absorption by the active layer is proven by UV–vis spectroscopy. An enhancement in light absorption is observed and ascribed to light scattering in mesoporous titania films with imprinted superstructures. Accordingly a better photovoltaic performance is found for nano‐imprinted solar cells at various angles of light incidence.     

The link between ethnic diversity and scientific impact: the mediating effect of novelty and audience diversity

Scientometrics - Understanding the nature and value of scientific collaboration is essential for sound management and proactive research policies. One component of collaboration is the composition...     

Architecture Takes Time

Though condensed between the stages of design and completion, the conventional process of designing a building is time consuming, involving various stakeholders, planning processes and a wide team of consultants and contractors. What happens, though, if the time period of an architect's involvement is expanded? How might a more process-orientated approach shift the role of the architect? Tobias Armborst, Daniel D'Oca and Georgeen Theodore , principals of Interboro Partners in New York, describe how they have developed projects that have sought opportunities in expanding the timescale and remit of traditional practice.