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排序方式: 共有2034条查询结果,搜索用时 9 毫秒
61.
Diana Nanova Sebastian Beck Andreas Fuchs Tobias Glaser Christian Lennartz Wolfgang Kowalsky Annemarie Pucci Michael Kroeger 《Organic Electronics》2012,13(7):1237-1244
The degree of charge transfer in thin films of organic charge transfer (CT)-complexes, which are deposited via thermal evaporation, is examined via infrared-spectroscopy. We demonstrate a linear relationship between the shift in the excitation energy of the CN-stretching mode of CT-complexes with the acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ) and the charge transfer. The measured correlation corresponds very well with DFT calculations. For Na-TCNQ we observe a splitting in the peak of the CN-stretching mode, which can be explained by the coupling of two modes and was confirmed by the calculations. In CT-complexes with partial charge transfer the appearance of an electronic excitation is demonstrated. 相似文献
62.
Manufacturing companies face rising pressure due to increased competition. Traditionally, companies have merely concentrated on offering impeccable, cost-efficient products. Today, however, flexibility and on-time delivery are additional requirements to satisfy the customers. At the same time, disruptions in production, especially in low-volume assembly, still frequently occur, leading to economic losses and delayed customer deliveries. The approach proposed in this paper strives for improving the disruption situation in low-volume assemblies. A detailed disruption management methodology has been developed, aiming at realizing an efficient reduction of disruptions, while at the same time considering the specific characteristics of low-volume assembly. The methodology is supported by a catalog of pre-emptive measures. These measures are known to reduce the disruptions’ occurrence or to diminish their consequences. In general, the approach pursues the basic idea to implement particularly those measures, which have the best cost-benefit-ratio. Based on the analysis of the cost-benefit-ratio of each measure, the developed methodology aims at improving the disruption situation in assembly and thus providing a high on-time delivery rate. The usability of the methodology for the low-volume assembly context has been confirmed by assembly experts on the basis of an application of the methodology in an exemplary case study. 相似文献
63.
Franz B. Spingler Adam Phillips Tobias Schuler Michael C. Tucker Adam Z. Weber 《International Journal of Hydrogen Energy》2017,42(19):13960-13969
Reducing mass-transport losses in polymer-electrolyte fuel cells (PEFCs) is essential to increase their power density and reduce overall stack cost. At the same time, cost also motivates the reduction in expensive precious-metal catalysts, which results in higher local transport losses in the catalyst layers. In this paper, we use a hydrogen-pump limiting-current setup to explore the gas-phase transport losses through PEFC catalyst layers and various gas-diffusion and microporous layers. It is shown that the effective diffusivity in the gas-diffusion layers is a strong function of liquid saturation. In addition, it is shown how the catalyst layer unexpectedly contributes significantly to the overall measured transport resistance. This is especially true for low catalyst loadings. It is also shown how the various losses can be separated into different mechanisms including diffusional processes and mass-dependent and independent ones, where the data suggests that a large part of the transport resistance in catalyst layers cannot be attributed to a gas-phase diffusional process. The technique is promising for deconvoluting transport losses in PEFCs. 相似文献
64.
Markus Fröbel Ajay Perumal Tobias Schwab Malte C. Gather Björn Lüssem Karl Leo 《Organic Electronics》2013,14(3):809-813
We report efficient and bright organic light-emitting devices operated by capacitive energy coupling. In this approach, the organic layers are enclosed between sputter-deposited hafnium dioxide layers to prevent charge carrier injection. When a sinusoidal voltage signal is applied to the electrodes, the devices emit bright green light whereas no detectable emission is generated upon application of a constant voltage. The efficiency of the process depends heavily on the frequency of the applied voltage signal. By optimizing the driving scheme, a record luminous efficacy for AC driven OLEDs of 2.7 lm/W at 500 cd/m2 is achieved. 相似文献
65.
Elisangela F. Boffo Leila A. Tavares Antonio C.T. Tobias Márcia M.C. Ferreira Antonio G. Ferreira 《LWT》2012,49(1):55-63
The potential of NMR spectroscopy to differentiate honeys concerning to the nectar employed in its production was evaluated. The application of chemometric methods to 1H NMR spectra has allowed to discriminate the honeys produced in the state of São Paulo, being identified the signals of responsible substances for the discrimination. Application of PCA and HCA methods to 1H NMR data have resulted in the natural clustering of the samples. Wildflower honeys were characterized by higher concentration of phenylalanine and tyrosine. Citrus honeys showed higher amounts of sucrose than other compounds, while eucalyptus honeys had higher amount of lactic acid than the others. Assa-peixe honeys showed spectra similar to eucalyptus and citrus. Sugar-cane honeys showed some signals similar to eucalyptus and citrus honeys, but also showed the tyrosine and phenylalanine signals. Adulterated honeys showed 5-hydroxymethylfurfural, citric acid and ethanol signals. KNN, SIMCA and PLS-DA methods were used to build predictive models for honey classification. In the commercial honeys prediction KNN, SIMCA and PLS-DA models correctly classified 66.7; 22.2 and 72.2% of the samples, respectively. 相似文献
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68.
Venkatesh Ramakrishnan Tobias Veerkamp Gerd Ascheid Marc Adrat Markus Antweiler 《Journal of Signal Processing Systems》2012,69(1):41-53
Matrix decomposition of the channel matrix in the form of QR decomposition (QRD) is needed for advanced multiple input and multiple output (MIMO) demapping algorithms like sphere decoder. Due to the computation-intensive nature of the QRD, its implementation has to be highly efficient. Flexibility in several forms, e.g. support for different algorithms, reusability of wireless implementations, portability, etc. is highly sought in wireless devices. The contradictory nature of flexibility and efficiency requires tradeoffs to be made between them in system development. In this paper, we have analyzed such tradeoffs by implementing two minimum mean squared error-sorted QRD algorithms. The algorithms have been implemented in four different methods with varying degree of reusability and in five different forms of portability. The performance of the implementations is evaluated by using the real-time constraints from the LTE standard. For all the implementations, modular equations for accurately estimating the execution time are derived. 相似文献
69.
The ongoing integration of Information Technology (IT) into various areas of our lives has led to a plethora of digital products and services. To survive competition in the long run, these offerings not only have to keep up with constant technological developments, but also have to adapt from a business point of view. Managers of these digital businesses have to especially focus on the design and evolution of their business’ revenue mechanisms to ensure the viability of their offerings. The related decisions are not trivial, as managers have to be aware of the relevant contextual factors and have to react quickly to changes in the environment. This paper proposes a viability theory for digital businesses described by 17 propositions that may guide managers in the design of revenue mechanisms and thereby support the evolution as well as the viability of a digital business. 相似文献
70.