Analysis of Cs-adsorption behavior using a column filled with microcapsule beads of potassium copper hexacyanoferrate

Ash-washing technology is a crucially important technology for removing radioactive Cs from contaminated ash. For that technology, Cs⁺ removal from the ash-washing solution by the adsorbent is necessary. This study was conducted to establish rapid preparation of appropriate adsorption columns for Cs⁺ uptake. A one-site model was not used for analysis because the model cannot accommodate sites with different adsorption speed. Results demonstrated that the adsorption behavior of the column filled with the granules of potassium copper hexacyanoferrate was well reproduced by a two-site adsorption model with parameters chosen through analysis of batch adsorption test results.     

Crystal structure and ferroelectric properties of Ca(Cu3−xMx)Ti4O12 (M = Fe and Ni) ceramics

M-substituted Ca(Cu_3−xM_x)Ti₄O₁₂ (CCMTO) ceramics, where M = Fe and Ni, were synthesized and the influence of M substitutions for Cu on the crystal structure and ferroelectric properties of CCMTO ceramics were investigated in this study. From the variations in the lattice parameters of CCMTO ceramics, the solubility limit of Ni substitution for Cu in CaCu_3−xNi_xTi₄O₁₂ (CCNTO) ceramics was x = 0.2, whereas that of CaCu_3−xFe_xTi₄O₁₂ (CCFTO) ceramics was x = 0.05. The crystal structural analysis of CCMTO ceramics revealed that the single phase of CCMTO ceramics belongs to the I23 non-centrosymmetric space group of I23; as a result, the P_r and E_c values of CCFTO ceramics at x = 0.05 were 1.8 μC/cm² and 40 kV/cm, respectively. The ferroelectric behavior of CCMTO ceramics by the M substitutions for Cu may be related to the displacement of a Ti⁴⁺ cation in the TiO₆ octahedra and tilting of the Ti–O–Ti angle because of the non-centrosymmetric space group.     

Improvement of Electrical Contact Between TE Material and Ni Electrode Interfaces by Application of a Buffer Layer

A single ??-structure thermoelectric (TE) module based on p-type NaCo₂O₄, n-type Mg₂Si, and Ni electrode was fabricated by the spark plasma sintering (SPS) method. The NaCo₂O₄ powder was synthesized by using a metal?Ccitric acid complex decomposition method. Bulk Mg₂Si prepared by melt quenching was ground into a powder and sieved to particle size of 75???m or less. To obtain a sintered body of NaCo₂O₄ or Mg₂Si, the powder was sintered using SPS. Pressed Ni powder or mixed powder consisting of Ni and SrRuO₃ powder was inserted between these materials and the Ni electrode in order to connect them, and electrical power was passed through the electrodes from the SPS equipment. The open-circuit voltage (V _OC) values of a single module in which TE materials were connected to the Ni electrodes by using pressed Ni powder was 82.7?mV, and the maximum output current (I _max) and maximum output power (P _max) were 212.4?mA and 6.65?mW at ??T?=?470?K, respectively. On the other hand, V _OC of a single module in which TE materials and an Ni electrode were connected with a mixed powder (Ni:SrRuO₃?=?6:4 volume fraction) was 109?mV, and I _max and P _max were 4034?mA and 109?mW at ??T?=?500?K, respectively. These results indicate that the resistance at the interface between the TE materials and the Ni electrode can be decreased and the output power can be increased by application of a buffer layer consisting of Ni and SrRuO₃.     

Selective production of lactic acid in continuous anaerobic acidogenesis by extremely low pH operation

The selective production of lactic acid by anaerobic acidogenesis with low pH control was examined using a chemostat culture. By decreasing culture pH to 3.5 in a chemostat culture containing mixed microbial populations for anaerobic acidogenesis, heterolactic fermentation became dominant, resulting in the selective production of lactic acid and ethanol. This phenomenon was reversible between the acidic and neutral conditions, and was not affected by the dilution rate. The extremely low pH operation was effective for selective lactic acid production in anaerobic acidogenesis.     

Experimental investigation on self-leveling behavior in debris beds

During a hypothetical core-disruptive accident in a sodium-cooled fast breeder reactor, degraded core materials can form debris beds on the core-support structure and/or in the lower inlet plenum of the reactor vessel from rapid quenching and fragmentation of core material pool. Coolant boiling may lead ultimately to leveling of the debris bed that is crucial to the relocation of molten core and heat-removal capability of the debris bed. In the present study, we elected to use depressurization boiling to simulate an axially increasing void distribution in the debris bed. Bottom-heating boiling was also chosen to confirm that characteristics of the self-leveling process do not depend on the boiling mode. Particle size (between 0.5 and 6 mm), shape (spherical and non-spherical), bed volume (between 5 and 8 l) and density (namely of alumina, zirconia, lead and stainless steel) along with boiling intensity and total volume were taken as experimental parameters to obtain the general characteristics of the self-leveling process. A series of experiments with simulant materials were conducted and analyzed in detail. The good concordance of the transient processes obtained from the different boiling methods sufficiently demonstrates that the present results obtained using the depressurization boiling method exhibit these general self-leveling characteristics. Detailed comparisons of deduced time variations of the inclination angle provides qualitative tendencies based on the experimental parameters considered influential to self-leveling behavior. The rationale behind the definition introduced for equivalent power density is also presented.     

Changes in the Mechanical Properties of Silk Fabrics Modified with Epoxide and Their Relation to the Fabric Construction

An investigation is described in which the mechanical properties of silk fabrics treated with ethyleneglycol diglycidylether (EDGE) were measured in relation to variations in fabric structure in terms of weight gain. Their mechanical behaviour was determined in bending, in-plane shear, and compressional characteristics experiments. An examination of the mechanical properties of silk fabrics treated with EDGE led to the following conclusions. The value of the bending rigidity (B) in the weft direction clearly increased with an increase in weight gain, which suggested hardening of fabric. The value of the shearing stiffness (G) of the fabric in the warp direction remained unchanged in spite of the epoxide treatment, and the values of the shearing hysteresis (2HG) were linearly related to the weight gain. These results suggest that the observed changes in mechanical behaviour can be largely attributed to an increase in the contact pressure between warp and weft yarns.     

Studies on Effective Utilization of SOFC Exhaust Heat Using Thermoelectric Power Generation Technology

Solid oxide fuel cells (SOFCs) are being researched around the world. In Japan, a compact SOFC system with rated alternative current (AC) power of 700 W has become available on the market, since the base load electricity demand for a standard home is said to be less than 700 W AC. To improve the generating efficiency of SOFC systems in the 700-W class, we focused on thermoelectric generation (TEG) technology, since there are a lot of temperature gradients in the system. Analysis based on simulations indicated the possibility of introducing thermoelectric generation at the air preheater, steam generator, and exhaust outlet. Among these options, incorporating a TEG heat exchanger comprising multiple CoSb₃/SiGe-based TEG modules into the air preheater had potential to produce additional output of 37.5 W and an improvement in generating efficiency from 46% to 48.5%. Furthermore, by introducing thermoelectric generation at the other two locations, an increase in maximum output of more than 50 W and generating efficiency of 50% can be anticipated.     

Synthesis of Si nanowires with a thermally oxidized shell and effects of the shell on transistor characteristics

Silicon nanowires (SiNWs) with a single-crystalline Si core and a thermally oxidized shell (core-shell SiNWs) were synthesized by gold-catalyzed chemical vapor deposition followed by rapid thermal oxidation. To synthesize high-quality core-shell SiNWs, the relationship between the growth parameters and the crystallinity was studied. Furthermore, the formation process of the oxide shell was analyzed in detail by transmission electron microscopy. Using SiNWs as channels, back gate-type field effect transistors (FETs) were fabricated on p-type silicon wafers. FETs with core-shell SiNWs channels exhibited smaller hysteresis in the drain current (I_d) vs. gate voltage (V_GS) characteristics and higher on/off drain current ratio (I_ON/I_OFF) than those with bare SiNWs channels.     

Sol–Gel‐Derived High‐Performance Stacked Transparent Conductive Oxide Thin Films

Single‐ and multi‐layer transparent conductive oxide (TCO) thin films exhibiting high performance, good packing density and low surface/interface roughness are deposited on silica glass substrates by the sol–gel method. The crystal and microstructural properties of the TCO thin films are evaluated as an alternate to films prepared by ultra‐high vacuum deposition. Tin‐doped indium oxide (ITO) thin films produced using a two‐step drying process showed low surface roughness because of dense packing structure not only horizontal but also vertical directions. As a result, electrical conductivity, carrier concentration, carrier mobility, and optical transmittance of 2.3 × 10³ S/cm, 8 × 10²⁰ cm^?3, 18 cm²/Vs, and over 98% at 500 nm, respectively, were achieved. A multilayer ZnO/ITO stacked structure was also fabricated using the sol–gel process. Our findings suggest that solution‐based methods show promise as an alternative to existing ultra‐high vacuum methods to fabricate TCO thin films.