Soldering of Mg Joints Using Zn-Al Solders

Magnesium has applications in the automotive and aerospace industries that can significantly contribute to greater fuel economy and environmental conservation. The Mg alloys used in the automotive industry could reduce mass by up to 70 pct, providing energy savings. However, alongside the advantages there are limitations and technological barriers to use Mg alloys. One of the advantages concerns phenomena occurring at the interface when joining materials investigated in this study, in regard to the effect of temperature and soldering time for pure Mg joints. Eutectic Zn-Al and Zn-Al alloys with 0.05 (wt pct) Li and 0.2 (wt pct) Na were used in the soldering process. The process was performed for 3, 5, and 8 minutes of contact, at temperatures of 425 °C, 450 °C, 475 °C, and 500 °C. Selected, solidified solder-substrate couples were cross-sectioned, and their interfacial microstructures were investigated by scanning electron microscopy. The experiment was designed to demonstrate the effect of time, temperature, and the addition of Li and Na on the kinetics of the dissolving Mg substrate. The addition of Li and Na to eutectic Zn-Al caused to improve mechanical properties. Higher temperatures led to reduced joint strength, which is caused by increased interfacial reaction.     

Improving Steam Boiler Operation by On-Line Monitoring of the Strength and Thermal Performance

The operation of steam boilers with high efficiency requires control of thermo-hydraulic and strength parameters in the on-line mode. During operation under transient conditions, there are significant temperature differences over the circumference of the horizontal pressure vessels. This occurrence is caused by the different values of heat transfer coefficients on the inner surface of the boiler drum in the water and steam region. Large thermal stresses can occur in partially filled horizontal vessels. This takes place in large steam generator drums, superheater headers, and steam pipelines. The paper presents a method for determination of thermo-flow parameters for steam boilers. This method allows performing the calculations of the boiler furnace chamber and heating flow rates absorbed by superheater stages. These parameters are important for monitoring the performance of the power unit and determining the degree of the furnace chamber slagging. Knowledge of these parameters allows determining the degree of the furnace chamber slagging. The calculation can be performed in online mode and use to monitoring of steam boiler. The presented method allows to the operation of steam boiler with high efficiency.     

A three-dimensional heterogeneity analysis of electrochemical energy conversion in SOFC anodes using electron nanotomography and mathematical modeling

In this paper a fully three dimensional, multiphase, micro-scale solid oxide fuel cell anode transport phenomena numerical model is proposed and verified. The Butler-Volmer model was combined with empirical relations for conductivity and diffusivity - notably the Fuller-Shetler-Giddings equation, and the Fickian model for transport of gas reagents. FIB-SEM tomography of a commercial SOFC stack anode was performed and the resulting images were processed to acquire input data. A novel method for estimating local values of Triple Phase Boundary length density for use in a three-phase, three-dimensional numerical mesh was proposed. The model equations are solved using an in-house code and the results were verified by comparison to an analytical solution within the range of its applicability. A limited parametric study was performed to qualitatively assess simulation performance and impact of heterogeneity. Despite the high dependence of the SOFC anode performance on the geometry of its anisotropic, three-phase microstructure there are very few micro-scale numerical models simulating transport phenomena within these electrodes.     

Control System for Free-Floating Space Manipulator Based on Nonlinear Model Predictive Control (NMPC)

Manipulator mounted on an unmanned satellite could be used for performing orbital capture maneuver in order to repair satellites or remove space debris from orbit. Use of manipulators for such purposes presents unique challenges, as high level of autonomy is required and the motion of the manipulator influences the position and orientation of the manipulator-equipped satellite. This paper presents a new control system that consists of two modules: trajectory planning module (based on trajectory optimization algorithm) and Model Predictive Controller. Both modules take into account the free-floating nature of the satellite-manipulator system. Proposed control system was tested in numerical simulations performed for a simplified planar case. In the first set of simulations Nonlinear Model Predictive Control (NMPC) was used to ensure realization of a square reference end-effector trajectory, while in the second set control system was used for optimizing and then ensuring realization of the trajectory that leads to grasping of the rotating target satellite. Simulations were performed with disturbances and with the assumed non-perfect knowledge of parameters of the satellite-manipulator system. Results obtained with NMPC are better than results obtained with the controller based on the Dynamic Jacobian inverse and with the Modified Simple Adaptive Control (MSAC).     

Measurement of mechanical properties in a 316L stainless steel welded joint

The aim of this study was to measure the mechanical properties of weld material taken from a single weld bead laid down on a 316L steel plate. Due to the low available volume of weld material, microsamples with a total length of 5.5 mm were used. The Digital Image Correlation method (DIC), which enables measurement of mechanical properties of very small samples, was employed for the strain measurements in a uniaxial tensile test. Samples were cut out from three different zones of the specimen: plate, weld, and the heat affected zone. The material from heat affected zone showed the highest value of the Ultimate Tensile Strength (UTS) (580 ± 7 MPa) and yield strength (339 ± 6 MPa). Plate material had lower UTS (559 ± 5 MPa) and yield strength (304 ± 7 MPa). The lowest values of UTS (526 ± 6 MPa) and yield strength (291 ± 8 MPa) have been revealed for the weld. The values obtained for UTS, yield strength and elongation to failure for the plate material were compared with data obtained using standard test specimens. No significant differences between results obtained for the microsamples and standard samples have been found.     

Evaluation of the mechanical behavior of W7-X central support connections by means of semi-automated FE analysis

The stellarator Wendelstein 7-X is under construction at the Max-Planck-Institut für Plasmaphysik in Greifswald. Its superconducting coil system is fixed by a massive structure. During machine operation the coils exert high forces and moments against each other and the central support structure (CSS). Therefore, the detailed analysis of the coil to CSS connections, the so-called central support elements (CSE), is a critical item. The major details of the design have been frozen; nevertheless, there is still need for detailed analysis of the CSEs due to assembly issues, and later on for exploring operational limits of the machine. These analyses have to be performed quickly, reliably, and shall provide results in a standardized form to enable timely responses to the assembly team. Special numerical tools – finite element (FE) parametric models of CSEs – have been developed for the purpose of such analyses. In the models, the geometry, material properties, contact conditions, loads as well as results presentation are defined in a parametric way. The use of the developed models for the definition of the final weld parameters, bolt preloads, assessment of acceptable tolerances, and optimal positions of the CSE-wedges before welding is also discussed.     

Raspberry seed extract effect on the ferroxidase activity of ceruloplasmin isolated from plasma

In this study, the effect of the raspberry seed extract (RSE) on the ferroxidase activity of ceruloplasmin (Cp) isolated from healthy male subject serum was analyzed. The ferroxidase activity of Cp was determined by spectrophotometry using Fe(II) – histidine complex and ferrozine as a chromogenic reagent. The ferroxidase activity of ceruloplasmin was demonstrated in dose-dependent way within the range 22–66 μg/ml. The effect of RSE on Fe(II) concentration, measured as the decrease of Fe(II) concentration in samples and expressed as ΔFe(II), was found to be a dose-dependent within the range 1.20–51.56 μg dm/ml. The ferroxidase activity of Cp was influenced by the RSE within its studied range. However, the addition of the highest concentration of RSE (51.56 μg dm/ml) to the sample containing the highest level of Cp (66 μg/ml) did not affect its ferroxidase activity. It may be suggested that the competition for Fe(II) as the substrate limits the effect of RSE on Cp activity and causes no further changes in Fe(II) elimination.     

Bioinspired Computational Framework for Enhancing Creativity, Optimality, and Robustness in Design

This paper presents results of transdisciplinary research on the development of a bioinspired computational framework for engineering design. This framework is intended to support design by addressing three critical design objectives, including novelty, optimality, and robustness. It provides several computational models and methods, which are inspired by fundamental processes occurring in nature, and discusses their potential for enhancing design. They include models and methods for evolutionary, developmental, and coevolutionary design. Their use is illustrated with examples from the area of steel structural design ranging from a simple cantilever beam design problem to a much more complex problem of designing wind bracings in tall buildings. The paper also shows how several methods and models can be integrated and form a coherent bioinspired computational framework for engineering design.