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991.
This study was aimed at comparing selected properties of starch citrate obtained from native or retrogrades of potato starch at various temperatures (100, 130 or 160 °C) and at various doses of reactant (10, 20 or 40 g per 100 g). Higher susceptibility to esterification was demonstrated for retrograded starch, whereas the degree of esterification of the produced esters varied considerably (1.4 to 10.0 g per 100 g preparation) and was increasing along with increasing roasting temperature and dose of citric acid. The process of pasting occurred only in the esters obtained at a temperature of 100  °C, which resulted in a significant decrease in swelling power and solubility in water of the citrates produced at higher temperatures. The resultant starch citrates were characterised by significant resistance to amylolysis (ranging from 22 to 100 g per 100 g). There was observed an increase in starch resistance along with the increase in the acid dose and roasting temperature. All analysed properties of starch citrates were not correlated with the degree of esterification, but appeared to depend on the roasting, which may point to a significant effect of this factor on the mechanism of starch cross‐linking with citric acid.  相似文献   
992.
During soya seeds germination in FeSO4 solutions their phytoferritin content is multiplied. Prepared soybean sprouts have been proposed as a safe and easily available source of iron supplementation. The preparation was compared with FeSO4 and ferritin isolates, using rats with induced iron deficiency anaemia. After the end of the 2-week supplementation experiment, it was observed that no statistically significant differences in haemoglobin concentration, mean corpuscular volume, mean corpuscular haemoglobin, and mean corpuscular haemoglobin concentration existed between those animals supplemented with sprouts enriched in ferritin, ferritin isolate and FeSO4 and healthy animals forming the control group. Moreover, the examined preparation had a beneficial influence on the recreation of ferritin reserves in both the liver and the blood serum, and also did not induce negative alterations in general growth parameters of animals. Use of an easily obtainable ferritin iron source may be a profitable alternative in supplementation due to its wide availability and food preservative properties.  相似文献   
993.
    
Meniscus-guided coating (MGC) is an efficient and promising route to grow small molecule and polymer organic semiconductors (OSCs) into highly ordered and uniaxially orientated thin films for electronic applications. In this work, the impact of domain size and molecular order on the charge carrier transport in field-effect transistors for a molecular organic semiconductor 4-tolyl-bithiophenyl-diketopyrrolopyrrole (DPP(Th2Bn)2) is investigated. The spherulitic domain growth of DPP(Th2Bn)2 in thin films is controlled in the evaporative regime of zone-casting by varying the substrate velocity. The decrease of coating velocity leads to a lower nucleation density and larger domain size of DPP(Th2Bn)2. At sufficiently low velocity, the spherulitic domains first elongate and then uniaxially grow in the coating direction. Although at the same time the molecular order decreases due to higher film thickness, the charge carrier transport improves for larger domain size and reduced density of boundaries in the transistor channel. These results provide insight on the relation between domain growth, molecular organization, and charge carrier transport in zone-cast OSC thin films that are important for the upscaling of the technique for practical applications.  相似文献   
994.
    
Infections and dysfunction are the most common complications related to catheter use. Here we describe a case of catheter rupture on the course of subcutaneous channel. Catheter fractures are relatively rare, but potentially hazardous complications. In case of partial breakage, a catheter exchange should be a simple solution.  相似文献   
995.
    
Gamma‐cyclodextrin/CL‐20 (γ‐CD/CL‐20) inclusion complex was prepared and characterized by infrared and 1H NMR spectroscopy. The study findings point to a weak interaction of CL‐20 protons with H3 and H5 protons, however relatively intense interactions with OH groups in a γ‐CD molecule, which allows to conclude that a CL‐20 molecule does not penetrate completely the toroid cavity formed by γ‐CD. The resulting complex was subject to nitration with 100 % nitric acid. Analysis of the 1H NMR spectrum demonstrated that an average of 21.6 OH groups in the starting γ‐CD underwent esterification. The nitrated complex is characterized by a higher density (1.81 g/cm3), and the sensitivity to impact (5 J) and friction (200 N) comparable to the starting complex. Thermogravimetric analysis of the nitrated γ‐Cyclodextrin/CL‐20 complex pointed to a two‐phase decomposition at 194 and 339 °C with a total significant exothermic effect amounting to 3230 J/g.  相似文献   
996.
    
New and efficient method for synthesis of 1,3,7,9‐tetranitrobenzo[c]cinnoline‐5‐oxide (TNBCO) via direct nitration of benzo[c]cinnoline‐5‐oxide was described. TNBCO and precursor were fully characterized by using spectroscopic (IR, NMR) and thermal analysis methods (DTA/TG). Activation energy of decomposition process was calculated by using Kissinger's equation. Standard enthalpy of formation was calculated by using experimentally determined heat of combustion. Detonation parameters were calculated with CHEETAH code and are comparable or higher than those known for E‐2,2’,4,4’,6,6’‐hexanitrostilbene (HNS) and 2,4,6‐trinitrotoluene (TNT).  相似文献   
997.
    
This article investigates the influence of marine collagen of various molecular weights (Collagen Amino Acids—150 Da, Hydrolyzed Collagen—12,000 Da and Soluble Collagen—300,000 Da) on the functional properties of bath liquids for children based on anionic surfactants—sodium laureth sulfate. In addition to the aspects related to safety-in-use, which were presented in the authors' first work about marine collagen, consumers also expect bath cosmetics for children to have specific functional characteristics including viscosity or foaming properties. An increase in the molecular mass of marine collagen was found to be accompanied by an increase in dynamic viscosity and foaming ability and a decrease in the ability to emulsify fatty soil in the formulations under study. It can, therefore, be concluded that the addition of the highest molecular weight of marine collagen (300,000 Da) to bath liquids for children contributes not only to reducing the irritant effect caused by anionic surfactants, but also improves the usable properties of these types of cosmetics.  相似文献   
998.
Abstract

In this paper, the counterexamples to the general theory related to the state-feedback IMC plants are given and investigated. It is shown, that the maximum-speed multivariable perfect control schemes do not necessitate the maximum-energy of the control input variables. In that way, the IMC peculiarities involving the nonzero perfect control closed-loop poles are indicated, which constitutes a solid counterweight to the well-known general system theory. A new geometric approach results in counterexamples for both full and non-full rank plants, giving rise to the introduction of a complete analytical paradigm in the nearest future. Numerical examples confirm the intriguing issues covering the paper.  相似文献   
999.
    
In recent years, organic Rankine cycle (ORC) micro-turbine distributed energy systems have become increasingly popular. Design methods for this type of fluid-flow machinery are still being developed. In this paper, a 2.5-kW radial-flow four-stage ORC micro-turbine with HFE7100 is experimentally and numerically analysed. CFX ANSYS was used for the numerical analysis as well as a computational fluid dynamics (CFD) in-house code based on finite volume discretisation with Godunov-type upwind differencing, a high-resolution essentially non-oscillatory (ENO) scheme and a turbulence model with two-equation shear stress transport (SST). The experimental stand and measurements are described. The numerical results are compared with experimental ones and prove to be satisfactory. The developed micro-turbine does not require the use of any traditional lubricant (oil-free technology) because the bearings are lubricated with the vapour of the low-boiling HFE7100. The developed micro-turbine is an innovative solution providing maintenance-free operation and high durability with low friction losses. The experimental studies have also confirmed a considerable reduction in noise and vibration levels.  相似文献   
1000.
    
To facilitate true regeneration, a vascular graft should direct the evolution of a neovessel to obtain the function of a native vessel. For this, scaffolds have to permit the formation of an intraluminal endothelial cell monolayer, mimicking the tunica intima. In addition, when attempting to mimic a tunica media‐like outer layer, the stacking and orientation of vascular smooth muscle cells (vSMCs) should be recapitulated. An integral scaffold design that facilitates this has so far remained a challenge. A hybrid fabrication approach is introduced by combining solution electrospinning and melt electrowriting. This allows a tissue‐structure mimetic, hierarchically bilayered tubular scaffold, comprising an inner layer of randomly oriented dense fiber mesh and an outer layer of microfibers with controlled orientation. The scaffold supports the organization of a continuous luminal endothelial monolayer and oriented layers of vSM‐like cells in the media, thus facilitating control over specific and tissue‐mimetic cellular differentiation and support of the phenotypic morphology in the respective layers. Neither soluble factors nor a surface bioactivation of the scaffold is needed with this approach, demonstrating that heterotypic scaffold design can direct physiological tissue‐like cell organization and differentiation.  相似文献   
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