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951.
The knowledge of the solubility in pure solvents and solvent mixtures is crucial for designing the crystallization process. However, it is practically impossible to scan all possible solvent mixtures and mixture compositions experimentally. Therefore, a physically well‐founded thermodynamic model which allows for solubility predictions in pure solvents and solvent mixtures based only on a small amount of experimental data is required. In this work, we demonstrated the applicability of the Perturbed‐Chain Statistical Associating Fluid Theory (PC‐SAFT) equation of state to model and to predict the solubility, especially of pharmaceuticals and complex (bio‐) molecules, in pure solvents and solvent mixtures. 相似文献
952.
Kasprzyk I Grinn-Gofroń A Strzelczak A Wolski T 《The Science of the total environment》2011,409(5):949-956
Ganoderma spores are one of the most airspora abundant taxa in many regions of the world, and are considered to be important allergens. The aerobiology of Ganoderma basidiospores in two cities in Poland was examined using the volumetric method, (Burkard and Lanzonii Spore Traps), from selected days in 2004, 2005 and 2006. Spores of Ganoderma were present in the atmosphere from June to November, with peak concentrations generally occurring from late July to mid-October. ANN (artificial neural network) and MRT (multivariate regression trees), models indicated that atmospheric phenomenon, hour and relative humidity were the most important variables influencing spore content. The remaining variables (air temperature, dew point, air pressure, wind speed and wind direction), also contributed to the high network performance, (ratio above 1), but their impact was less distinct. Those results are consistent with the Spearman's rank correlation analysis. 相似文献
953.
Delgado J Barba-Brioso C Nieto JM Boski T 《The Science of the total environment》2011,409(19):3666-3679
Recent studies have demonstrated that the Guadiana Estuary contains metal concentrations in excess of background values. Therefore, this work aims to document the potential environmental hazards associated with the availability of these metals in this environment of high ecological value. Mineralogical analysis shows that the sediments are composed mainly of quartz, albite, and clay minerals (illite, smectite, kaolinite, and vermiculite) along with several small, reactive compounds (including soluble sulphated salts, Fe-Mn oxyhydroxides, organic matter, and pyrite) capable of retaining metals, which can be subsequently released, causing environmental degradation. BCR sequential extraction shows that As, Cd, Cu, Mn, Pb, and Zn present mobile fractions with respect to the total metal content (41, 100, 57, 53, 70, and 69%, respectively) in any of the described reactive phases (F1 + F2 + F3).Calculated environmental risk indices demonstrate moderate to considerable ecological risk for almost the entire estuary, associated mainly with acid mine drainage from the nearby Iberian Pyrite Belt. In addition, the indices highlight several zones of extremely high risk, which are related to industrial and urban dumps in the vicinity of the estuary and to heavy traffic on the international bridge. 相似文献
954.
Agnieszka Matuszewska Beata Nowak Anna Nikodem Anna Merwid-Ld Benita Wiatrak Tomasz Tomkalski Diana Jdrzejuk Ewa Szelg Tomasz Sozaski Maciej Danielewski Paulina Jawie Ireneusz Ceremuga Marta Szandruk-Bender Marek Bolanowski Jarosaw Filipiak Adam Szelg 《International journal of molecular sciences》2021,22(13)
Bone structure abnormalities are increasingly observed in patients chronically treated with antiepileptic drugs (AEDs). The majority of the available data concern older conventional AEDs, while the amount of information regarding newer AEDs, including stiripentol, is limited. The aim of the study was to assess the effect of stiripentol on bones. For 24 weeks, male Wistar rats, received 0.9% sodium chloride (control group) or stiripentol (200 mg/kg/day) (STP group). In the 16th week of the study, we detected lower serum PINP levels in the STP group compared to the control group. In the 24th week, a statistically significant lower 1,25-dihydroxyvitamin D3 level, higher inorganic phosphate level and higher neutrophil gelatinase-associated lipocalin (NGAL) levels in serum were found in the STP group compared to the control. Micro X-ray computed tomography of the tibias demonstrated lower bone volume fraction, lower trabecular thickness, higher trabecular pattern factor and a higher structure model index in the stiripentol group. Considering the results of this experiment on rats which suggests that long-term administration of stiripentol may impair the cancellous bone microarchitecture, further prospective human studies seem to be justified. However, monitoring plasma vitamin D, calcium, inorganic phosphate and kidney function in patients on long-term stiripentol therapy may be suggested. 相似文献
955.
Andrzej Kołodziej Mieczysław Jaroszyński Bożena Janus Tadeusz Kleszcz Joanna Łojewska Tomasz Łojewski 《Chemical Engineering Communications》2013,200(8):932-949
Catalytic wire gauzes have been used for many years for ammonia oxidation. The flow and transfer properties of stacked gauzes, however, have not been sufficiently examined in the literature. This study presents an experimental program designed to characterize the pressure drops observed across stacked woven and knitted wire gauzes. This work generated an extensive database of measurements and reveals that each gauze requires its own correlation equation. Furthermore, previously published general models were not able to describe all four cases with high accuracy. After surveying the literature, we present some modifications to the models based on our collected experimental results. 相似文献
956.
This paper presents a practical realization of the system for the active control of boundary conditions during the dynamic thermal characterization of electronic components. The control of boundary conditions is exercised by the dual cold plate cooling assembly equipped with Peltier thermo-electric modules and an appropriate control circuit. Additionally, a tensometer bridge is used to assure the parallel alignment of surfaces and to adjust the contact thermal resistance between particular layers. The operation of the entire control system is illustrated based on a practical example where Peltier module currents are adjusted in real time so as to impose isothermal or constant heat flux boundary conditions on a power diode package surface during measurements performed with time varying power dissipation in the device. 相似文献
957.
Christoph Held Gabriele Sadowski Aristides Carneiro Oscar Rodríguez Eugénia A. Macedo 《American Institute of Chemical Engineers》2013,59(12):4794-4805
The Perturbed‐Chain Statistical Association Fluid Theory is applied to simultaneously describe various thermodynamic properties (solution density, osmotic coefficient, solubility) of aqueous solutions containing a monosaccharide or a disaccharide. The 13 sugars considered within this work are: glucose, fructose, fucose, xylose, maltose, mannitol, mannose, sorbitol, xylitol, galactose, lactose, trehalose, and sucrose. Four adjustable parameters (three pure‐sugar parameters and a kij between sugar and water that was allowed to depend linearly on temperature) were obtained from solution densities and osmotic coefficients of binary sugar/water solutions at 298.15 K available in literature. Using these parameters, the sugar solubility in water and in ethanol could be predicted satisfactorily. Further, osmotic coefficients and solubility in aqueous solutions containing two solutes (sugar/sugar, sugar/salt) were predicted (no additional kij parameters between the two solutes) reasonably. The model was also applied to predict the solubility of a sugar in a solvent mixture (e.g., water/ethanol) without additional fitting parameters. © 2013 American Institute of Chemical Engineers AIChE J, 59: 4794–4805, 2013 相似文献
958.
Wojciech A. Pisarski Joanna Pisarska Izabela Czopek Tomasz Goryczka Radosław Lisiecki Witold Ryba‐Romanowski 《Journal of the American Ceramic Society》2013,96(6):1685-1687
Lead tungstate PbWO4 nanocrystals in transparent lead borate glass‐ceramics containing Er3+ ions were fabricated. Luminescence spectra at about 1530 nm due to main 4I13/2–4I15/2 laser transition of Er3+ ions were examined for glass samples before and after heat treatment. Near‐infrared luminescence of Er3+ ions in glass‐ceramics is enhanced and long‐lived in comparison to precursor glasses. It suggests that the Er3+ ions are partially incorporated into PbWO4 crystalline phase. 相似文献
959.
Przemysław Korytkowski Szymon Rymaszewski Tomasz Wiśniewski 《The International Journal of Advanced Manufacturing Technology》2013,67(1-4):231-241
This paper proposes a heuristic method based on ant colony optimization to determine the suboptimal allocation of dynamic multi-attribute dispatching rules to maximize job shop system performance (four measures were analyzed: mean flow time, max flow time, mean tardiness, and max tardiness). In order to assure high adequacy of the job shop system representation, modeling is carried out using discrete-event simulation. The proposed methodology constitutes a framework of integration of simulation and heuristic optimization. Simulation is used for evaluation of the local fitness function for ants. A case study is used in this paper to illustrate how performance of a job shop production system could be affected by dynamic multi-attribute dispatching rule assignment. 相似文献
960.
4,10-Dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.05,903,11]dodecane (TEX) was obtained by nitrolysis of 1,4-diformyl-2,3,5,6-tetrahydroxypiperazine reaction using a mixture of fuming nitric acid and concentrated sulfuric acid. The optimal process temperature was 54–56°C. The yield of the synthesis depends inter alia on the rate the reactants are introduced into the reaction medium and on the time of conditioning of the reaction mixture. A maximal yield of ca. 40% was achieved at the reactant addition time of 2 h and conditioning time of 2 h. None of the other nitrating mixtures examined proved superior to the conventional nitrating mixture. The product was examined by high-performance liquid chromatography (HPLC), nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), and differential scanning calorimetry (DSC) techniques and the results are reported. 相似文献