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31.
A facile route for the rapid in situ synthesis of platinum nanoparticles on spherical microflower carbon has been developed. An aqueous precursor slurry containing carbon black, polystyrene latex (PSL), polyvinyl alcohol, and platinum salt was spray‐dried, followed by calcination to simultaneously reduce platinum salt and to decompose PSL particles. Prepared Pt/C catalyst showed high‐performance electrocatalytic activity with excellent durability. The mass activity and specific activity values were 132.26 mA mg–1 Pt and 207.62 μA cm–2 Pt, respectively. This work presents a future direction for the production of high‐performance Pt/C catalyst in an industrial scale. 相似文献
32.
33.
Atsushi Kaneko Yasushi Tamada Shinji Hirai Toshihiro Kuzuya Tomoko Hashimoto 《大分子材料与工程》2012,297(3):272-278
Pulse electric current sintering is used to prepare a compact from resinificated hydrous silk powder. Compacts with no remnant silk powders are formed with 20 wt% added water, 20–40 MPa molding pressure, and >353 K molding temperature. The latter two are much lower than those used for conventional hot pressing. No dependence on molding pressure and temperature are found in XRD or FT‐IR analysis, except for a compact molded at 473 K, for which silk fibroin decomposition is confirmed by DSC, EGA‐MS, and molecular weight measurements. The compact's three‐point bending strength depends on the molding temperature, except for the temperature at which silk fibroin decomposes. The maximum three‐point bending strength resembles that of general‐purpose epoxy resin and is much higher than that of PLA.
34.
Tomoko Okuyama Jun Shirakawa Kazuki Tajima Yoko Ino Heidrun Vethe Yu Togashi Mayu Kyohara Ryota Inoue Daisuke Miyashita Jinghe Li Nozomi Goto Taiga Ichikawa Shingo Yamasaki Haruka Ohnuma Rie Takayanagi Yayoi Kimura Hisashi Hirano Yasuo Terauchi 《International journal of molecular sciences》2020,21(21)
35.
36.
Satohiro Yoshida Tsunehiro Tanaka Tomoko Hanada Takeshi Hiraiwa Hiroyoshi Kanai Takuzo Funabiki 《Catalysis Letters》1992,12(1-3):277-285
XANES of vanadium and niobium oxide on silica or alumina have been analyzed quantitatively by a deconvolution technique. Based on the results for reference compounds, local structures of supported vanadium and niobium species were identified. The composition was estimated from difference spectra for the samples which consisted of two kinds of species. 相似文献
37.
Summary
Static and dynamic light scattering measurements have been made on a sodium salt sample of succinoglycan in 0.01 M aqueous
NaCl at different temperatures between 25 and 75°C where the polysaccharide undergoes a thermally induced change from an ordered
(helical) to disordered conformation with raising temperature T. The weight-average molecular weight M
w, the z-average radius of gyration, and the hydrodynamic radius sharply decrease in a relatively narrow T range (around 55°C) in which the specific rotation was previously found to change sigmoidally with T. In particular, the value of M
w (4.55 × 105) in the ordered state at 25°C is twice as large as that (2.27 × 105) in the disordered state at 75°C, giving decisive evidence that the helical structure of the polysaccharide in aqueous NaCl
is composed of paired chains. It is concluded that this structure is a double-stranded helix and breaks directly into two
disordered chains with increasing T.
Received: 6 July 2001 / Accepted: 24 July 2001 相似文献
38.
Toshihiko Myojo Kensei Ehara Hiromi Koyama Kikuo Okuyama 《Aerosol science and technology》2013,47(12):1178-1184
We describe a newly constructed annular-type differential mobility analyzer (DMA) with an effective electrode length of 60 cm, which is longer than that of our original DMA (40 cm length). This long DMA was developed to extend the classification size of particles measuring up to 1.5 μm. As an application of this DMA, the mean diameters and standard deviations were determined for six samples of monodisperse polystyrene latex (PSL) particles ranging from 0.94 to 1.27 μm in nominal diameter. These PSL particles suspended in double-distilled water were aerosolized by a glass nebulizer and then introduced into the DMA. The mean diameters and standard deviations of these PSL particles were calculated by Ehara's method and compared with the nominal diameters and uncertainties. There was good correlation between the nominal diameters of these samples—particularly for recently certified samples—and the measured diameters. Classification of aerosol particles more than 1 micrometer in diameter using this DMA will be useful for many purposes. 相似文献
39.
Manabu Shimada Heru Setyawan Yutaka Hayashi Nobuki Kashihara Kikuo Okuyama Sugeng Winardi 《Aerosol science and technology》2013,47(5):408-414
The effects of gas flow rate on particle formation and film deposition during the preparation of silica thin film using a TEOS/O2 plasma were investigated. Particle formation and growth are suppressed with increasing gas flow rates. The film deposition rate increases with increasing gas flow rate, reaches a maximum value, and eventually decreases again. However, the uniformity of the film tends to degrade at high gas flow rates. At a high gas flow rate, some particles trapped in the sheath near the grounded electrode pass through the sheath to reach the substrate and are then embedded in the growing film. A self-consistent sheath model combined with particle force balance based on charge fluctuation was developed to explain these experimental findings qualitatively. The model reveals that charge fluctuation is a key factor for the particle to overcome the potential barrier of the negatively charged particles to pass through the sheath, eventually reaching the substrate. The model further shows that the probability of a particle being deposited on the substrate is higher for increased gas flow rates, which correctly predicts the experimentally observed trend. 相似文献
40.
Chan Soo Kim Kikuo Okuyama Juan Fernández de la Mora 《Aerosol science and technology》2013,47(10):791-803
Several modifications of the particle size magnifier (PSM) developed by Okuyama et al. have been introduced recently for detection of particles at diameters of 1 nm and below. However, their evaluation has been incomplete. Here we provide the first direct measurements of counting efficiencies near unity below 2 nm. We use the modified PSM described by Sgro and Fernández de la Mora, which separates thermally the PSM's original vapor generator from the water-cooled growth chamber by means of a narrow and short T where turbulent mixing with the aerosol takes place. The counting efficiency is seen to depend greatly on the aerosol flow, the amount of vapor, and temperature. With ethylene glycol vapor, under optimal conditions, the counting efficiency is 100% down to 1.6 nm (actual diameter of 1.2 nm), and negative particles are more easily activated than positive particles. The improved PSM is applied to the measurement of gold nanoparticle size distributions, and the results show it is a powerful aerosol detector for nanoparticles. 相似文献