Hydrometallurgical process for the recycling of copper using anodic oxidation of cuprous ammine complexes and flow-through electrolysis

Flow-through electrolysis for copper electrowinning from cuprous ammine complex was studied in order to develop a hydrometallurgical copper recycling process using an ammoniacal chloride solution, focusing on the anodic oxidation of cuprous to cupric ammine complexes. The current efficiency of this anodic oxidation was 96% at a current density of 200 A m⁻² under a batch condition. In a flow-through electrolysis using a sub-liter cell and a carbon felt anode, the anodic current efficiency increased with the flow rate and was typically higher than 97%. This tendency was explained by the backward flow of the cupric ammine complex, which was formed on the anode, through the diaphragm. The anodic overpotential was lower than 0.3 V even at an apparent current density of 1500 A m⁻². A similar current efficiency and overpotential were also achieved in a liter scale cell, which indicates the scale flexibility of this electrolysis. The power consumption requirements for copper electrowinning in this cell were 460 and 770 kWh t⁻¹ at the current densities of 250 and 500 A m⁻², respectively, which were much lower than that of the conventional copper electrowinning despite the longer interpolar distance.     

Synthesis and application of fluorescein- and biotin-labeled molecular probes for the chemokine receptor CXCR4

The design, synthesis, and bioevaluation of fluorescence- and biotin-labeled CXCR4 antagonists are described. The modification of D-Lys8 at an epsilon-amino group in the peptide antagonist Ac-TZ14011 derived from polyphemusin II had no significant influence on the potent binding of the peptide to the CXCR4 receptor. The application of the labeled peptides in flow cytometry and confocal microscopy studies demonstrated the selectivity of their binding to the CXCR4 receptor, but not to CXCR7, which was recently reported to be another receptor for stromal cell-derived factor 1 (SDF-1)/CXCL12.     

Degradation characteristics of polylactide in thermophilic anaerobic digestion with hyperthermophilic solubilization condition

To test whether hyperthermophilic treatment promotes polylactide (PLA) dissolution and methane conversion under anaerobic digestion conditions, a single thermophilic control reactor (55 °C) and a two-phase system consisting of a hyperthermophilic reactor (80 °C) and a thermophilic reactor (55 °C) were continuously fed with a mixture of PLA and artificial kitchen garbage. In Runs 1 and 2, the PLA dissolution ratios in the two-phase system were 79.2 ± 6.5% and 85.2 ± 7.0%, respectively, higher than those of the control. Batch experimental results indicated that hyperthermophilic treatment could promote PLA dissolution to a greater degree as compared with single thermophilic treatment and that ammonia addition also had a promotional effect on PLA dissolution. In the two-phase system, after hyperthermophilic treatment, dissolved PLA was converted to methane gas under the subsequent thermophilic condition.     

Enhancement of serotonergic neural activity contributes to cyclosporine-induced tremors in mice

Patients suffering from inflammatory or dysimmunitary diseases may develop various clinical responses to corticotherapy. This brief article describes the various cellular and molecular mechanisms which underly the genetic, endocrine and immunitary factors involved in corticosensitivity, corticoresistance and corticodependence.     

Stress-induced martensite formation in Cu−Al−Ni alloys

A study has been made of superelasticity and the strain-memory effect in Cu?Al?Ni alloys in the composition range 14 wt pct Al and 2 to 3 wt pct Ni. These alloys have a bcc structure on quenching and show a low temperature martensitic transformation which is responsible for both the superelastic and strain-memory effects. Tests on both single and polycrystalline specimens showed that the maximum superelasticity occurred close toA _s. At higher temperatures the effect gradually decreased, whilst at lower temperatures it decreased very quickly. The magnitude of the effect was large in single crystal specimens (>5.8 pct), but small in polycrystal specimens (<1.5 pct). The superelastic effect was caused by stress-induced martensite (SIM). Two types of SIM were observed; thin plates of thermoelastic martensite which were always reversible, and wide plates of burst-type martensite. This burst-type martensite was responsible for the major portion of SIM, and whether it was reversible or not on removal of the stress controlled the amount of superelasticity observed. The strain-memory effect occurred on deformation either in the martensitic state (temperature <M _f) or in the temperature range where the martensite once formed was stable (temperature close toM _s). Deformation caused reorientation of the martensite plates and when the specimen was heated, the martensite disappeared and the specimen reverted back to its original shape. This effect was explained on the basis of development of martensite plates of favorable orientation on stressing.     

Synthesis and chiroptical properties of helical poly(phenylacetylene) bearing optically active chiral oxazoline Pendants

The novel optically active (S)-4-benzyl-2-(ethynylphenyl)-oxazoline (BnEPhOx) was successfully prepared and polymerized using rhodium catalyst ([Rh(nbd)Cl]₂) to obtain the moderate molecular weight poly(phenylacetylene)s bearing chiral oxazoline derivatives with high yields (≥90%). The ¹H NMR spectra demonstrated that the resulting polymers had high stereoregular structures. Moreover, the poly(phenylacetylene)s bearing chiral oxazoline exhibited better thermal stability than poly(phenylacetylene). The resulting polymers showed higher absolute values of optical specific rotation than the monomer. The polymers also exhibited intense CD signal in the region of the π-π1 band of the conjugated polyacetylene backbone in chloroform solution. The results of specific rotation and CD spectroscopy indicated that all the polymers adopted higher-order structure with predominantly one-handed screw sense.In addition, the resulting polymers emitted fluorescence under UV irradiation.     

A new Landsat 8 cloud discrimination algorithm using thresholding tests

ABSTRACT

In this work, we propose a Cloud Discrimination Algorithm for Landsat 8 (CDAL8) to improve a high-frequency automatic land change detection system developed at the National Institute of Advanced Industrial Science and Technology (AIST), Japan for large-scale satellite image analysis. Although the land change detection system can process several kinds of satellite remote sensing data, improvements are needed to enable practical applications using Landsat 8 data. Cloud discrimination is a necessary pre-processing step for land cover change detection. Currently, most of the prediction errors on land change detection are caused by the false cloud discrimination results as a pre-processing step. Therefore, we introduce an improved cloud discrimination algorithm (CDAL8) in this study to improve the overall performance of our land change detection system. The algorithm was developed based on a Moderate Resolution Imaging Spectroradiometer (MODIS) cloud mask algorithm and Cloud and Aerosol Unbiased Decision Intellectual Algorithm (CLAUDIA). CDAL8 is distinct in that it switches judgment tests and their thresholds using a threshold brightness temperature and uses separate features in cloud judgment and clear-sky judgment. To evaluate the accuracy of the proposed algorithm, we compared it with the Automated Cloud-Cover Assessment algorithm (ACCA) and Function of Mask (Fmask) version 3.3 using US Geological Survey Landsat 8 cloud cover assessment validation data, which contain 96 cloud masks. Our proposed cloud discrimination algorithm (CDAL8) have promising results with an accuracy of 88.1%, which was greater than that of the ACCA (82.5%) and Fmask (84.6%). Furthermore, we also confirmed that the average accuracy of CDAL8 was approximately 91.2% when low solar elevation scenes were removed.     

Cultural variation in the use of current life satisfaction to predict the future.

Three studies examined cultural and situational influences on the tendency for people to use their current life satisfaction to predict future life events. On the basis of the self-enhancement literature, it was predicted that either writing about a positive personal experience or reading about another's negative experience would lead European Americans to focus their attention on internal attributes and thus would lead them to use their current life satisfaction in predicting the future. Conversely, on the basis of the self-criticism literature, it was predicted that these same conditions would lead Asian Americans to focus their attention on external factors and, therefore, would decrease their likelihood of using their current life satisfaction to predict the future. Studies 1 and 2 supported these hypotheses. Study 3 showed that these patterns could be obtained by subliminally priming concepts associated with individualism and collectivism. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Residential mobility, self-concept, and positive affect in social interactions.

The present research examined (a) the link between personal history of residential mobility and the self-concept and (b) the implications of such a link for positive affect in social interactions. Study 1 showed that the personal self was more central to the self-definition of frequent movers than to that of nonmovers, whereas the collective self was more central to the self-definition of nonmovers than to that of frequent movers. Results from a laboratory and a 2-week event sampling study (Studies 2 and 3) demonstrated that frequent movers felt happier when an interaction partner accurately perceived their personal selves, whereas nonmovers felt happier when a partner accurately perceived their collective selves. These findings present the first direct evidence on how personal history of residential mobility is linked to important individual differences in the self and positive affect in social interactions. (PsycINFO Database Record (c) 2010 APA, all rights reserved)