High-temperature oxidation of intermetallics formed by group IV transition metals with chromium

We have studied the oxidation resistance of chromium intermetallics: TiCr₂, HfCr₂, and ZrCr₂, in the temperature interval 873–1473 K with isothermal holding of the specimens for up to 20 h. We have shown that the intermetallics TiCr₂ and HfCr₂ are oxidized 2–3 times more slowly than pure titanium and hafnium, but more than 1–2 orders of magnitude faster than chromium at T≤1273 K and 4–6 times faster at 1473 K. In this temperature interval, the intermetallic ZrCr₂ is rapidly oxidized at an increasing rate as the heating temperature rises. The scaling resistance of intermetallics of Group IV d metals with chromium is determined by formation of scales in which the major role is played by the oxides TiO₂, HfO₂, and ZrO₂, with weak protective properties.     

Express Method for Estimation of Tensile Strength and Crack Resistance of Brittle Media

The procedure is proposed for estimating the crack resistance and tensile strength of rocks by the results of experiments on disk samples with holes. The gradient approach to the strength problem is employed in processing the experimental data.     

Simulation of the Accelerating Systems of Cyclotrons for Applications

The results of a comparative numerical investigation of three types of resonator systems of a cyclotron for acceleration of negative hydrogen and deuterium ions up to maximum energy 30 and 15 MeV, respectively, are presented. It is shown that a vertical system with two half-wave resonators excited in-phase has the smallest active losses and the smallest differential of the amplitude of the accelerating voltage along the edge of the dees and is effective for accelerating particles at dual working frequencies.     

Kolmogorov's Contributions to the Foundations of Probability

Andrei Nikolaevich Kolmogorov was the foremost contributor to the mathematical and philosophical foundations of probability in the twentieth century, and his thinking on the topic is still potent today. In this article we first review the three stages of Kolmogorov's work on the foundations of probability: (1) his formulation of measure-theoretic probability, 1933; (2) his frequentist theory of probability, 1963; and (3) his algorithmic theory of randomness, 1965–1987. We also discuss another approach to the foundations of probability, based on martingales, which Kolmogorov did not consider.     

Three-dimensional structure of the cloud of a carbon pellet evaporated in plasma of Wendelstein 7-AS stellarator

Experiments performed on a Wendelstein 7-AS stellarator revealed asymmetry of the cloud of an ablating carbon pellet. The cloud is elongated in the direction of large radius toward stronger fields, that is, opposite to the direction expected due to the toroidal drift. In order to study the effect in more detail, the three-dimensional structure of the cloud was analyzed by computer tomography. The results confirmed asymmetry of the cloud. This asymmetry is related to a drift flow existing in the plasma and directed along large radius toward stronger fields. The drift velocity is numerically estimated at ～300 m/s.     

Determination of shear strength values according to EN 408

This paper presents the results of 382 shear tests carried out according to EN 408. The test pieces consisted of spruce (Picea abies) and varied in density and ring width orientation (radial, tangential and at an angle of 45° to the steel plates). In addition pieces containing pith and knots were tested. The paper discusses problems observed when using this test configuration and shows that the test results do not support the characteristic shear strength values as given in EN 338. Moreover, the test results do not support the relationship between characteristic shear strength and characteristic bending strength as given in EN 384.

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Résumé Cet article présente les résultats de 382 essais de cisaillement menés conformément à EN 408. Les éprouvettes d’essai sont en épicéa (Picea abies) et présentent une variabilité en termes de masse volumique et d’orientation des cernes d’accroissement (radiale, tangentielle, à un angle de 45° par rapport aux plaques métalliques). Des éprouvettes supplémentaires contenant du cœur et des nœuds ont également été testées. L’article évoque les problèmes qui ont été mis en évidence lors de l’utilisation de ce dispositif expérimental et montre que les résultats expérimentaux ne sont pas en accord avec les valeurs caractéristiques de résistance au cisaillement données dans EN 338. De plus, ces résultats ne confirment pas la relation entre résistance caractéristique au cisaillement et résistance caractéristique à la flexion telle que stipulée dans EN 384.

     

Micromechanism of corrosion fracture of the plates of heat exchangers

We have studied the micromechanism of corrosion fracture of heat-transfer plates of a heat exchanger. The operation of heat exchangers under conditions of contamination of the plates with a sediment from water leads to their local corrosion under the sediment. The conditions of operation of the heat exchangers being equal, heat-transfer plates made of AiSi316Ti steel worked 2.36 times as long as those of AiSi304L steel. The corrosion fracture of plates under the sediment began from pitting initiation near nonmetallic inclusions of a certain nature. Afterwards, these pittings built up into corrosion spots by the mechanism of stress corrosion and hydrogen embrittlement. __________ Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 1, pp. 110–116, January–February, 2007.     

Nonlinear model predictive control with polytopic invariant sets

Ellipsoidal invariant sets have been widely used as target sets in model predictive control (MPC). These sets can be computed by constructing appropriate linear difference inclusions together with additional constraints to ensure that the ellipsoid lies within a given inclusion polytope. The choice of inclusion polytope has a significant effect on the size of the target ellipsoid, but the optimal inclusion polytope cannot in general be computed systematically. This paper shows that use of polytopic invariant sets overcomes this difficulty, allowing larger stabilizable sets without loss of performance. In the interests of online efficiency, consideration is focused on interpolation-based MPC.     

Uranium(III) in aqueous solutions: Preparation,properties, synthesis of solid compounds

Published data on the preparation procedures, stability, and complexation of U(III) in aqueous solutions are summarized and correlated. Reactions with inorganic and organic free radicals studied by the flash radiolysis method, the spectroscopic properties, the extraction and ion-exchange behavior of U(III), and methods for isolation of solid U(III) compounds from aqueous solutions are discussed.     

Beyond Boundary Objects: Collaborative Reuse in Aircraft Technical Support

Boundary objects are a critical, but understudied, theoretical construct in CSCW. Through a field study of aircraft technical support, we examined the role of boundary objects in the practical achievement of safety by service engineers. Their resolution of repair requests was preserved in the organization’s memory via three compound boundary objects. These crystallizations did not manifest a static interpretation, but instead were continually reinterpreted in light of meta-negotiations. This suggests design implications for organizational memory systems which can more fluidly represent the meta-negotiations surrounding boundary objects.