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301.
The kinetics of changes in the bound water content in dietetic sucrose-free sponge cakes (DC) during storage was investigated. The effect of edible films of polymyxan, pectin, xanthan, and carboxymethylcellulose upon this kinetics was also investigated. The quantitative changes in both states of water (slightly bound water and strongly bound water) were registered by combined dynamic analysis (thermogravimetry analysis, TGA, and differential thermal analysis, DTA). The moisture changes in DC crumb were analyzed by drying out to constant mass. The rate constants were determined according the equation q = qoe-kt. The values of rate constants 'k', in day-1, concerning the different edible films were as follows: for crumb moisture is (8.00 ≤ k ≤ 12.47) × 10-3, for bound water is (3.07 ≤ kw ≤ 6.26) × 10-2, for slightly bound water is (4.22 ≤ k1 ≤ 8.49) × 10-2 and for strongly bound water is (2.02 ≤ k2 ≤ 5.62) × 10-2 as compared to 18.53 × 10-3, 7.16 × 10-2, 9.04 × 10-2, and 5.36 × 10-2 in the uncovered DC, respectively. The best water-retaining effect in respect to crumb moisture during storage was ascertained in the use of polymyxan and xanthan films. The lowest rate constant values for bound water and its two states were measured for DC covered with pectin. The relation between the kinetics of both bound water states during storage and ageing of the crumb of DC covered with different edible films and the crumb microstructure was represented. By means of scanning electron microscope was read the smallest change in crumb microstructure of pectin-covered DC on the sixth day of storage. 相似文献
302.
N. A. Sivov A. I. Martynenko G. N. Bondarenko M. P. Filatova E. Yu. Kabanova N. I. Popova A. N. Sivov E. B. Kruts’ko 《Petroleum Chemistry》2006,46(1):41-59
Structures and compositions of the monomers guanidine acrylate and guanidine methacrylate, their homopolymers, and copolymers with diallyldimethylammonium chloride enriched in acrylate comonomer units were determined. It was shown that ampholytic copolymers, owing to their ionic nature, contained comonomeric guanidine acrylate or methacrylate units and diallyldimethylammonium chloride units, as well as the acrylate comonomer with the diallyl counterion and polymeric acrylate and diallyl ion pairs. It follows from IR and 1H NMR data that guanidine methacrylate has the same structure (with two hydrogen bonds) in the solid state and in solutions. Guanidine acrylate structures in the solid state and in dimethylsulfoxide are identical and analogous to guanidine methacrylate structure in this solvent. In water, the guanidine acrylate structure has another type of hydrogen bonding (with one hydrogen bond, where the proton is shifted toward the guanidine group). These features of hydrogen bonding of guanidine acrylate and guanidine methacrylate are also retained in their homopolymers and copolymers with diallyldimethylammonium chloride. It was shown that the thermal stability of the copolymers was higher than that of their homopolymers, confirming the formation of intramolecular ion pairs of oppositely charged units of ampholytic copolymers. Moreover, the thermal stability of guanidine methacrylate-diallyldimethylammonium chloride copolymers is higher than that of guanidine acrylate-diallyldimethylammonium chloride copolymers. 相似文献
303.
304.
H. Furuse N. Mori H. Kubo H. Momose M. Kondow 《Journal of Materials Science: Materials in Electronics》2007,18(1):81-85
We have measured optical transmittance through germanium in the mid-infrared region at room temperature using the Osaka free-electron laser (FEL). In spite of the fact that germanium is transparent in the mid-infrared region, we observed strong suppression of optical transmission under high-intensity FEL excitation. We found that the observed suppression is due to optical absorption in germanium. To analyze the experimental results, we have calculated optical transmittance of germanium within Keldysh theory 相似文献
305.
Model-driven development - Guest editor's introduction 总被引:1,自引:0,他引:1
306.
It is established that the capillary rise of a liquid has an oscillatory character, in contrast to the commonly accepted opinion that a vertical capillary is filled at a monotonically varying velocity. The value of the tangential shear stress arising in an ascending liquid is evaluated for ethyl alcohol and distilled water. 相似文献
307.
A. M. Kozodaev O. V. Shvedov V. N. Konev B. Yu. Sharkov V. V. Vasil'ev E. B. Volkov N. V. Lazarev A. M. Raskopin G. G. Shimchuk P. V. Bogdanov A. I. Kiryushin V. V. Petrunin E. I. Azhnin E. I. Tyurin I. I. Titaev Yu. P. Severgin A. Yu. Konstantinov 《Atomic Energy》2003,94(1):56-60
The purpose and current construction status, at the Institute of Theoretical and Experimental Physics, of an experimental electronuclear setup, combining a pulsed proton linear accelerator (36 MeV, 0.5 mA) and a subcritical blanket thermal-power assembly 100 kW, are discussed. The main equipment is already available or is being built in industry. The setup can be used to investigate the dynamics of the interaction of a linac–driver and a subcritical reactor and problems concerning the accelerator–driver and the target–blanket assembly. The proton beams and neutron fluxes will be used for applied purposes. In the future it will be possible to increase substantially the current and energy of the proton beam. 相似文献
308.
A. M. Kut’in V. S. Polyakov M. F. Churbanov G. E. Snopatin 《Inorganic Materials》2007,43(9):1018-1023
Using a flow method, we have measured the vapor pressure of tellurium tetraiodide, an attractive reagent for chemical vapor deposition technology. The results, combined with earlier tensimetric data, have been used to evaluate the basic thermodynamic functions of TeI4 and its thermolysis products. 相似文献
309.
We discuss specific features of Te-based compounds that made them the best materials for the phase-change data storage. It is demonstrated that the phase-change recording is due to a switch of Ge atoms between octahedral and tetrahedral symmetry positions within the Te face-centered cubic lattice. It is this nature of the transition that makes the Te-based media fast and stable. The driving force for this transition is also discussed. The chapter is concluded by introduction of a concept of the super-resolution near-field structure (super-RENS) disc that allows to reduce a bit size well below the diffraction limit and makes 100 GB/disc storage a reality. 相似文献
310.
A. D. Pogrebnyak M. V. Il’yashenko V. S. Kshnyakin V. V. Ponaryadov Sh. M. Ruzimov Yu. N. Tyurin 《Technical Physics Letters》2003,29(12):1028-1030
Chromium carbide-nickel coatings were deposited onto a technical grade copper substrate by means of a high-velocity plasma
jet of a plasmatron operating in specially selected regimes. An analysis of the coatings showed evidence of the formation
of a Ni-based solid solution, a complex chromium carbide (Cr7C3), and an fcc crystal phase with a lattice parameter of 3.614 Å. The surface of the coatings exhibits a characteristic relief
resulting from a dynamic interaction between melted and fused particles of the initial powder. The local hardness on some
areas of the surface and in depth of the coating reaches 66±4.5 HRC, while the coating adhesion strength varies from 25 to
300 MPa. 相似文献