Multifunctional iron and iron oxide nanoparticles in silica

Iron and iron oxide nanoparticles in silica layers deposited by sol–gel techniques on Si wafers were formed and studied. It was shown that multifunctional nanoparticles of different iron oxides possessing various physical properties can be fabricated by means of post-growth annealing of (SiO₂:Fe)/SiO₂/Si samples in various atmospheres. The hematite, maghemite, and iron nanoparticles were found to be dominant upon annealing the samples in air, argon, and hydrogen atmosphere, respectively. The physical properties of produced hybrid structures were studied by Raman and FT-IR spectroscopy, spectroscopic ellipsometry, AFM, and magnetic measurements. The sol–gel technique with subsequent annealing procedure is demonstrated to be an effective method for the formation of multifunctional hybrid structures composed of iron or iron oxide nanoparticles in silica matrix.     

Formation and characterization of melt-spun polypropylene fibers with propolis for medical applications

The search of possibilities to improve the functional properties of textile materials has been continuing for years with the aim to provide higher hygiene characteristics offer advanced therapeutic functionality. One of available approaches to provide new properties for textiles is the inclusion of natural ingredients. Propolis extracts are successfully used in practical therapeutics for accelerated wound healing and cell proliferation processes. In this study, pure multi-filament yarns and yarns saturated with propolis were developed and characterized. The effect of preparation and formulation parameters on the characteristics of yarns was evaluated; the release of propolis extract components from yarns and their possible cytotoxicity on cell formation was also determined.     

Measurements and analysis of the electromagnetic fields of mobile communication antennas

The owner of a mobile telephone is exposed to radiation from both the mobile telephone and base stations. They are often installed on the roofs of residential buildings. The article deals with electromagnetic fields generated by mobile communication antennas in the residential area. Measurements of electrical strength, magnetic strength and the electromagnetic field energy flux density were performed and compared to the established hygiene norms. Tests were conducted in the near and far zones of the antenna, in residential premises located directly in front of antenna, within the main radiation lobe of the antenna.     

Impact of lipid oxidation-derived aldehydes and ascorbic acid on the antioxidant activity of model melanoidins

As the heat-induced formation of antioxidants throughout the Maillard reaction is known, this study was undertaken to evaluate the impact of lipid oxidation-derived aldehydes and ascorbic acid in Maillard model systems on the resulting antioxidant activity. For this purpose, various fractions of melanoidin-like polycondensation products were obtained from mixtures of amino acids (glycine, lysine, arginine) and lipid oxidation-derived aldehydes (hexanal, (E)-2-hexenal), in the presence or absence of glucose or ascorbic acid. All fractions showed a significant radical scavenging capacity (DPPH assay) and ferric reducing power (FRAP assay). The activity varied according to the composition of the model system tested, although some similar trends were discovered in both assays applied. The presence of lipid oxidation products in the browning products augmented the antioxidant activity in specific cases. For instance, the combined presence of arginine, hexanal and glucose in heated model systems resulted in a significantly higher antioxidant capacity. With an exception of ascorbic acid-containing model systems, melanoidin-like polycondensation products possessed significantly stronger antioxidant activities than the corresponding unheated initial reactant mixtures. Water-soluble high molecular weight (>12kDa) and nonsoluble fractions comprised the major part of the antioxidants derived from amino acid/lipid oxidation product model systems, with or without glucose or ascorbic acid.     

Colossal Magnetoresistance Properties of La0.83Sr0.17MnO3 Thin Films Grown by MOCVD on Lucalox Substrate

The magnetoresistance (MR) of polycrystalline La_0.83Sr_0.17MnO₃ thin films have been studied in high pulsed magnetic fields up to 38 T in the temperature range 100–300 K. The lucalox substrates were used to obtain polycrystalline structures with naturally formed grain boundaries (GBs) and crystallites whose dimensions were determined by film deposition temperature. It was found that the MR value is highest in the films having smallest crystallites. The main behaviour of high-field MR was analysed using modified Mott’s hopping model assuming that the GBs might be ferromagnetic with a Curie temperature T _C being reduced in comparison with that of the crystallites interior.     

Rye and Wheat Bran Extracts Isolated with Pressurized Solvents Increase Oxidative Stability and Antioxidant Potential of Beef Meat Hamburgers

Rye and wheat bran extracts containing phenolic compounds and demonstrating high DPPH? (2,2‐diphenyl‐1‐picrylhydrazyl), ABTS^?+ (2,2′‐azino‐bis(3‐ethylbenzthiazoline‐6‐sulphonic acid) scavenging and oxygen radical absorbance capacities (ORAC) were tested in beef hamburgers as possible functional ingredients. Bran extracts significantly increased the indicators of antioxidant potential of meat products and their global antioxidant response (GAR) during physiological in vitro digestion. The extracts also inhibited the formation of oxidation products, hexanal and malondialdehyde, of hamburgers during their storage; however, they did not have significant effect on the growth of microorganisms. Hamburgers with 0.8% wheat bran extract demonstrated the highest antioxidant potential. Some effects of bran extracts on other quality characteristics such as pH, color, formation of metmyoglobin were also observed, however, these effects did not have negative influence on the overall sensory evaluation score of hamburgers. Consequently, the use of bran extracts in meat products may be considered as promising means of increasing oxidative product stability and enriching with functional ingredients which might possess health benefits.     

Graphene supported platinum–cobalt nanocomposites as electrocatalysts for borohydride oxidation

In the study presented herein a rapid microwave heating method was used to prepare the graphene supported PtCo catalysts with Pt:Co molar ratio 1:7, 1:22 and 1:44. The transmission electron microscopy was employed to characterize the catalysts. Inductively coupled plasma optical emission spectrometry was used for estimation of Pt and Co metal loadings. The electrocatalytic activity of the synthesized catalysts towards the oxidation of borohydride was investigated by means of cyclic voltammetry and chronoamperometry. The kinetics of the catalytic hydrolysis of NaBH₄ in the presence of the synthesized catalysts was investigated.     

The second harmonic generation in semiconductors in the DC magnetic field

The second harmonic radiation in millimeter wave region is found in semiconductors in the absence of the dc electric field. The observed resonant maximum of radiation intensity is shown to be related to the excitation of the free-electron plasma oscillations in the dc magnetic field.