全文获取类型
收费全文 | 710篇 |
免费 | 39篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 6篇 |
综合类 | 2篇 |
化学工业 | 213篇 |
金属工艺 | 8篇 |
机械仪表 | 21篇 |
建筑科学 | 13篇 |
能源动力 | 21篇 |
轻工业 | 53篇 |
水利工程 | 1篇 |
石油天然气 | 4篇 |
无线电 | 53篇 |
一般工业技术 | 139篇 |
冶金工业 | 85篇 |
原子能技术 | 42篇 |
自动化技术 | 90篇 |
出版年
2023年 | 21篇 |
2022年 | 25篇 |
2021年 | 36篇 |
2020年 | 21篇 |
2019年 | 25篇 |
2018年 | 24篇 |
2017年 | 19篇 |
2016年 | 35篇 |
2015年 | 25篇 |
2014年 | 35篇 |
2013年 | 34篇 |
2012年 | 22篇 |
2011年 | 44篇 |
2010年 | 41篇 |
2009年 | 35篇 |
2008年 | 27篇 |
2007年 | 23篇 |
2006年 | 16篇 |
2005年 | 25篇 |
2004年 | 17篇 |
2003年 | 14篇 |
2002年 | 16篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 20篇 |
1998年 | 16篇 |
1997年 | 13篇 |
1996年 | 9篇 |
1995年 | 3篇 |
1994年 | 11篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1988年 | 6篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 6篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 6篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1963年 | 1篇 |
1956年 | 1篇 |
1939年 | 1篇 |
排序方式: 共有751条查询结果,搜索用时 15 毫秒
51.
Valentin Segouin Mathieu Domenjoud Yves Bernard Laurent Daniel 《Journal of the European Ceramic Society》2019,39(6):2091-2102
The strain response of a polarised PZT was characterised using Digital Image Correlation (DIC). The DIC algorithm is based on a global approach and regularises the displacement field using the balance equations of solid mechanics. The measurement error is reduced by correcting the displacements that are mechanically not admissible. A ferroelectric test showed that the standard deviations of strain fields remain mostly under 1.2 × 10?4 for an element size of 64 px. The standard deviation on the average value is 3 × 10?6. The strain field is homogeneous and its average value is consistent with the strain obtained from a CCD laser measurement device. The longitudinal strain, transverse strain and polarisation response of the PZT were measured for bipolar and unipolar loadings ranging from 50 to 5000 V/mm. Material properties were extracted from these measurements. This work shows the advantages of a novel 2D-DIC algorithm for piezoelectric strain characterisation. 相似文献
52.
Valentin Magn Florent Blanchard Angela Marinetti Arnaud Voituriez Xavier Guinchard 《Advanced Synthesis \u0026amp; Catalysis》2016,358(21):3355-3361
N‐Propargyl‐ and N‐homoallenyl‐2‐bromo‐β‐tryptamines undergo gold(I)‐catalyzed dearomatizing cyclizations to afford 2‐bromospiroindolenines that are in situ hydrolyzed to furnish spirooxindoles in a one‐pot process. Tryptophane derivatives (R2=CO2Et) led upon cyclization to chiral spirooxindoles in excellent diastereoselectivities.
53.
Fate of ivermectin residues in ewes' milk and derived products 总被引:1,自引:0,他引:1
Cerkvenik V Perko B Rogelj I Doganoc DZ Skubic V Beek WM Keukens HJ 《The Journal of dairy research》2004,71(1):39-45
The fate of ivermectin (IVM) residues was studied throughout the processing of daily bulk milk from 30 ewes (taken up to 33 d following subcutaneous administration of 0.2 mg IVM/kg b.w.) in the following milk products: yoghurt made from raw and pasteurized milk; cheese after pressing; 30- and 60-day ripened cheese; and whey, secondary whey and whey proteins obtained after cheese-making (albumin cheese). The concentration of the H2B1a component of IVM was analysed in these dairy products using an HPLC method with fluorescence detection. The mean recovery of the method was, depending on the matrix, between 87 and 100%. Limits of detection in the order of only 0.1 microg H2B1a/kg of product were achieved. Maximum concentrations of IVM were detected mostly at 2 d after drug administration to the ewes. The highest concentration of IVM was found on day 2 in 60-day ripened cheese (96 microg H2B1a/kg cheese). Secondary whey was the matrix with the lowest concentration of IVM (<0.6 microg H2B1a/ kg). Residue levels fell below the limits of detection between day 5 (for secondary whey) and day 25 (for all cheese samples). In the matrices investigated, linear correlations between daily concentrations of IVM, milk fat and solid content were evident. During yoghurt production, fermentation and thermal stability of IVM was observed. During cheese production, approximately 35% of the IVM, present in the raw (bulk) milk samples, was lost. From the results it was concluded that the processing of ewes' milk did not eliminate the drug residues under investigation. The consequences of IVM in the human diet were discussed. Milk from treated animals should be excluded from production of fat products like cheese for longer after treatment with IVM than for lower fat products. 相似文献
54.
Andreas Brodehl Alexey Meshkov Roman Myasnikov Anna Kiseleva Olga Kulikova Brbel Klauke Evgeniia Sotnikova Caroline Stanasiuk Mikhail Divashuk Greta Marie Pohl Maria Kudryavtseva Karin Klingel Brenda Gerull Anastasia Zharikova Jan Gummert Sergey Koretskiy Stephan Schubert Elena Mershina Anna Grtner Polina Pilus Kai Thorsten Laser Valentin Sinitsyn Sergey Boytsov Oxana Drapkina Hendrik Milting 《International journal of molecular sciences》2021,22(7)
About 50% of patients with arrhythmogenic cardiomyopathy (ACM) carry a pathogenic or likely pathogenic mutation in the desmosomal genes. However, there is a significant number of patients without positive familial anamnesis. Therefore, the molecular reasons for ACM in these patients are frequently unknown and a genetic contribution might be underestimated. Here, we used a next-generation sequencing (NGS) approach and in addition single nucleotide polymor-phism (SNP) arrays for the genetic analysis of two independent index patients without familial medical history. Of note, this genetic strategy revealed a homozygous splice site mutation (DSG2–c.378+1G>T) in the first patient and a nonsense mutation (DSG2–p.L772X) in combination with a large deletion in DSG2 in the second one. In conclusion, a recessive inheritance pattern is likely for both cases, which might contribute to the hidden medical history in both families. This is the first report about these novel loss-of-function mutations in DSG2 that have not been previously identi-fied. Therefore, we suggest performing deep genetic analyses using NGS in combination with SNP arrays also for ACM index patients without obvious familial medical history. In the future, this finding might has relevance for the genetic counseling of similar cases. 相似文献
55.
Anna Schüller Daniel Matzner Dr. Christina E. Lünse Prof. Dr. Valentin Wittmann Dr. Catherine Schumacher Sandra Unsleber Prof. Dr. Heike Brötz‐Oesterhelt Prof. Dr. Christoph Mayer Prof. Dr. Gabriele Bierbaum Prof. Dr. Günter Mayer 《Chembiochem : a European journal of chemical biology》2017,18(5):435-440
The ever‐growing number of pathogenic bacteria resistant to treatment with antibiotics call for the development of novel compounds with as‐yet unexplored modes of action. Here, we demonstrate the in vivo antibacterial activity of carba‐α‐d ‐glucosamine (CGlcN). In this mode of action study, we provide evidence that CGlcN‐mediated growth inhibition is due to glmS ribozyme activation, and we demonstrate that CGlcN hijacks an endogenous activation pathway, hence utilizing a prodrug mechanism. This is the first report describing antibacterial activity mediated by activating the self‐cleaving properties of a ribozyme. Our results open the path towards a compound class with an entirely novel and distinct molecular mechanism. 相似文献
56.
In this letter, we derive 2λπP/((α - 2)g(α - 2) as a closed-form approximation of the expected interference around a receiver in wireless networks. We use a geometric path loss model, assume that nodes are randomly distributed, and that only nodes outside a guard zone around the receiver simultaneously transmit. The derived solution depends on the path loss exponent α, node density λ, transmission power per node P, and the radius g of the guard zone. The simplicity of this solution makes it widely applicable in wireless network analysis. 相似文献
57.
PtRu nanoparticles supported on nitrogen-doped multiwalled carbon nanotubes as catalyst for methanol electrooxidation 总被引:1,自引:0,他引:1
Raghuram Chetty Shankhamala Kundu Michael Bron Wolfgang Schuhmann Valentin Chirila Thomas Reinecke 《Electrochimica acta》2009,54(17):4208-108
Nitrogen-doped carbon nanotubes (N-CNT) obtained by plasma treatment were compared to the conventional acid-treated carbon nanotubes (O-CNT) as catalyst support for platinum-ruthenium (PtRu) nanoparticles in the anodic oxidation of methanol in direct methanol fuel cells. PtRu catalysts were prepared by an impregnation-reduction method from chloride precursors with metal loadings of 20 wt.%, and were characterised by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and electrochemical methods. Voltammetry and chronoamperometry studies showed that the performance of PtRu/N-CNT was significantly higher compared to PtRu/O-CNT and also to the commercial E-TEK PtRu/C catalyst, indicating that N-CNT are an interesting support material for fuel cell electrocatalyst. Nitrogen plasma treatment produced pyridinic and pyrrollic species on the CNT surface, which acts as the anchoring sites for the deposition of PtRu particles. A mechanism for the deposition of PtRu on N-CNT is tentatively proposed and discussed. 相似文献
58.
We study the complexity of the 2-dimensional knapsack problem , where . The problem is defined in terms of real numbers and we study it where an integral solution is sought under a real number
model of computation. We obtain a tight complexity bound , where .
Received: November 1998 / Accepted: December 1998 相似文献
59.
This Paper investigates the sensitivity to frequency-selective fading of different modulation techniques commonly used in digital radio systems. The modulation methods considered are phase-shift-keying (M ary PSK), nonoffset and offset quadrature amplitude modulation (M -ary QAM), and quadrature partial response signaling (QPRS). The performances of these methods during multipath fading are compared on the basis of the "signatures" calculated for idealized systems. Results are presented from which the relative outage probability was determined, assuming a propagation channel with frequency-selective Rician fading. 相似文献
60.
The addition of acetates and nitrates for the synthesis of single-wall carbon nanotubes via laser ablation was explored. Targets containing nominal amounts of acetates or nitrates in addition to Ni and Co catalysts were compared to a standard target containing only Ni and Co at temperatures ranging from 1000 to 1200 °C. The as produced web-like soot was characterized by transmission electron microscopy, Raman spectroscopy and optical absorption spectroscopy. All samples showed a linear increase in SWCNT mean diameter with temperature; however, the rate of mean diameter change with temperature differed for the various targets, more so at lower temperatures. The addition of nitrates improved the SWCNT relative yield over all the temperatures used, whereas the inclusion of acetates improved the relative yield only at lower temperatures. The above results were discussed and analyzed according to the porous structure of the targets resulting from the decomposition of the acetates and nitrates and consequential thermal diffusion changes. 相似文献