Effect of microstructure on electrical and mechanical properties of La5.4WO12-δ proton conductor

The relationships between microstructural characteristics and electrical as well as mechanical properties of La_5.4WO_12-δ (LWO54) materials were studied. Polycrystalline LWO54 samples revealed identical transport mechanisms regardless of the sample microstructure. The studied samples show predominately proton conductor behaviour below 800?°C and become predominant n-type and oxygen ion conductors above this temperature. The magnitude of the total conductivity is enhanced with larger grain size and lower porosity. Young’s modulus decreased by 20% with increasing temperature up to 1000?°C regardless of grain size and atmosphere. Fracture strength was determined via ring-on-ring bending tests, yielding values that strongly depended on microstructural characteristics and homogeneity of the microstructure. Elevated temperature deformation studies revealed that creep is governed by cation diffusion mechanism.     

一等奖:时间的层级

该竞赛方案是我们在国立雅典科技大学建筑工程学院的毕业论文项目的一部分.学校开展的大多数研究是关于雅典的城市环境问题处理,研究与干预的对象主要集中在城市特定区域.风景园林设计学科整合在建筑学院中.在过去3年的学习中,我们选择了大尺度的项目进行研究.然而,我们发现要对自然风景进行干预是极其困难的,甚至很小的一个举动就会在自然里留下痕迹.竞赛方案是有关于对柯蒂齐泻湖的干预.柯蒂齐泻湖位于希腊伯罗奔尼撒半岛西部,有温和的冬季和温暖的夏季,是希腊最重要的泻湖之一,也是往来非洲的候鸟栖息和中转的地方.     

Cone Calorimeter and Thermogravimetric Analysis of Glass Phenolic Composites Used in Aircraft Applications

The increasing use of composite materials in aircraft cabins and structures poses significant challenges in order to maintain and improve the fire safety of aviation. In this work, the flammability characteristics of a commercial glass-fibre reinforced phenolic composite (GFRP) used for aircraft cabin partitions and furnishing are investigated experimentally. Thermogravimetric analysis under inert atmosphere at several heating rates provided information on the thermal decomposition process. The degradation process is modelled with one and two-step mechanisms using the Ozawa–Flynn–Wall iso-conversional method and the GPYRO numerical code which utilizes a genetic algorithm optimization scheme. The estimated activation energy and pre-exponential factor values, especially in the two-step case (77.18 and 104.69 kJ/mol and 2.60 × 106 and 3.19 × 106 min−1 for the first and the second step respectively), recover reasonably well the conversion degree and its derivative. Tests with a cone calorimeter (CC), performed at different incident heat fluxes, provided information on the reaction to fire characteristics of the material and the influence of the heat flux on the combustion process. In general, combustion proceeds in two stages, flaming and smoldering combustion. The CC results assisted by scanning electron microscopy photos provide information on the charring characteristics of the material. The critical heat flux for ignition and the corresponding ignition temperature are estimated, correlating heat fluxes with time to ignition. Thermally thin and thick models are considered, as well as a modified technique bridging the gap between these limit cases and therefore valid for thermally thin and thick but also intermediate conditions (more pertinent in the present case). The results for this latter approach are $$\dot{q}^{\prime\prime}_{ig,cr}$$ ~ 20 kW/m2 and Tig = 469°C, providing also complementing information on thermophysical properties, such as thermal diffusivity, α = 1.23 × 10−7 m2/s, thermal conductivity, k = 0.325 W/(m K) and specific heat capacity, c = 1.330 kJ/(kg K). This work provides information on the reaction to fire characteristics of GFRP, but also on physical and flammability properties in a form suitable to be used in numerical codes, for the prediction of fire and evacuation scenarios. The influence of the reinforcement structure on the fire behaviour of the composite is also illustrated and discussed.     

Freestanding foils of nanotube arrays fused with metals

Novel freestanding foils of vertically aligned carbon nanotube arrays (VANTAs) fused with metals are fabricated in a scalable four-step process of (1) VANTA synthesis, (2) deposition of partially infused metal film, (3) removal from growth substrate, and (4) optional deposition of a second metal film on the back side. Mechanical and electrical testing demonstrates excellent contact between the VANTA and the interface-infused metal layers.     

Potential of a simple HPLC-based approach for the identification of the spoilage status of minced beef stored at various temperatures and packaging systems

The shelf life of minced beef stored (i) aerobically, (ii) under modified atmosphere packaging (MAP), and (iii) under MAP with oregano essential oil (MAP/OEO) at 0, 5, 10, and 15 °C was investigated. The microbial association of meat and the temporal biochemical changes were monitored. Microbiological analyses, including total viable counts (TVC), Pseudomonas spp., Brochothrix thermosphacta, lactic acid bacteria, Enterobacteriaceae, and yeasts/moulds, were undertaken, in parallel with sensory assessment, pH measurement and HPLC analysis of the organic acid profiles. Spectral data collected by HPLC were subjected to statistical analysis, including principal component analysis (PCA) and factorial discriminant analysis (FDA). This revealed qualitative discrimination of the samples based on their spoilage status. Partial least squares regression (PLS-R) was used to evaluate quantitative predictions of TVC, Pseudomonas spp., Br. thermosphacta, lactic acid bacteria, Enterobacteriaceae, and yeasts/moulds. Overall, the HPLC analysis of organic acids, was found to be a potential method to evaluate the spoilage and microbial status of a meat sample regardless of the storage conditions. This could be a very useful tool for monitoring the quality of meat batches during transportation and storage in the meat food chain.     

Biodiesel emissions profile in modern diesel vehicles. Part 2: Effect of biodiesel origin on carbonyl, PAH, nitro-PAH and oxy-PAH emissions

In the present study, the effects of different biodiesel blends on the unregulated emissions of a Euro 4 compliant passenger car were examined. Two fresh and two oxidized biodiesel fuels of different source materials were blended with an ultra low sulphur automotive diesel fuel at proportions of 10, 20, and 30% v/v. Emission measurements were conducted on a chassis dynamometer with a constant volume sampling (CVS) technique, over the New European Driving Cycle (NEDC) and the Artemis driving cycles. The experimental results revealed that the addition of biodiesel led to important increases in most carbonyl compounds. Sharp increases were observed with the use of the oxidized biodiesel blends, especially those prepared from used frying oil methyl esters. Similar to carbonyl emissions, most PAH compounds increased with the addition of the oxidized biodiesel blends. It can be assumed that the presence of polymerization products and cyclic acids, along with the degree of unsaturation were the main factors that influenced carbonyl and PAH emissions profile.     

Occurrence and Antibiotic Susceptibility Profile of Streptococcus spp. Isolated from Ewe＇s Milk

The purpose of this study was to determine the occurrence and antimicrobial resistance of Streptococcus spp. isolated from fresh ewe＇s milk and consequently to draw conclusions concerning the health condition of the animal flocks and the current trends of antibiotic use in small ruminants. A total of 77 mountainous sheepfolds were investigated representing 10% of all transhumant sheep and goats flocks in the area. Duplicate milk samples were collected from January to February transferred to the laboratory and analyzed for the presence of Streptococcus spp. by using the serial dilution method and plating on the surface of Slanetz and Bartley agar. The isolates were tested against nine antimicrobial agents with the Kirby-Bauer disk diffusion method. The results showed that Streptococcus spp. occurred in 84.4% of the samples and in counts ranged between 1.8 log CFU/mL and 4.6 log CFU/mL. Concerning susceptibility, only 1.3% of the isolates were resistant to all antimicrobials while 27.3% were fully susceptible. Resistance to cefepime was the most common （93.1%） observation followed by resistance to ampicillin （82.1%）, ciprofloxacine （58.3%） and meropenem （51.9%）. The isolates were vancomycin susceptible at a rate of 83.6%. Multidrug resistance to at least three antibiotics was observed to be 22.1% of Streptococcus spp.. Given the prevalence of Streptococcus spp. and the elevated resistance of isolates to various antibiotics it is concluded that further examinations and even interventions are required in order to pertain the appropriate animal health and milk quality.