Conduction studies on Ta2O5 layer under different metallic electrodes

Rectification studies on Ta₂O₅ anodic oxide layers with vacuum-deposited Au, Ag, Pb, Bi, Sb contacts have been made. No correlation between critical voltage and work function for metal electrodes was found. Non-uniform and unpredictable behaviour of Ta₂O₅ films under different metals have indicated the dominant dependence of conduction on the flaw density in the oxide film.     

Magnetic field effect on electron emission from plasma

The influence of external magnetic field on the significant parameters of electrons from laser induced plasma (LIP) is investigated. A Q-switched Nd:YAG laser (1064 nm, 9-14 ns, 10 mJ, 1.1 MW) is focused on annealed, 4N pure (99.99%) Silver target (2 × 2 × 0.2 cm³) for production of plasma under vacuum ∼10⁻³ torr. Temperature, density and energy measurements for electrons were made by self fabricated Langmuir probe both in the absence and presence of external magnetic field (∼1.2 T) at different positions. The signals are recorded on 200 MHz UTT 2202 digital storage oscilloscope. The results thus obtained reveal decrease in electron temperature, energy and density in presence of external magnetic field. Confinement of plasma is also observed.     

Simultaneous Determination of Metronidazole Benzoate Methylparaben, and Propylparaben by High-Performance Liquid Chromatography

The simultaneous determination of metronidazole benzoate (MB), methylparaben (MP), and propylparaben (PP) in an oral suspension formulation was developed using high-performance liquid chromatography (HPLC). The method was developed using a Novapak C₁₈ (3.9 × 150 mm, 4 μm) column, methanol-water (50:50, v/v) as the mobile phase and an ultraviolet (UV) detector at 254 nm. The peak area response versus concentration was linear in a concentration range from 40 to 400 μg/ml of MB, 0.8 to 8.0 μg/ml of MP, and 0.2 to 2.0 μg of PP. The correlation coefficients were 0.9997 for MB, 0.9987 for MP, and 0.9983 for PP, with relative standard errors of 1.12%, 1.28%, and 1.67%, respectively.     

Options for support tower design of a sensitive equipment under ambient vibrations

This paper describes the options and methodology adopted for the design of an 18‐m high support tower for a vibration sensitive optical telescope. The telescope was to be housed inside an existing building that provided shielding from atmospheric wind and thermal variations. However, proper functioning of the telescope was dependent on the support tower's structural configuration and stiffness to limit angular distortion of the telescope platform to less than 2 µ radians or 0·4 arc‐sec. This level of sensitivity required investigation of support tower response under ambient vibrations resulting from normal operation of the existing facility. The measured peak ambient vibration acceleration ranged from 0·04 m/s/s to 0·27 m/s/s for various recorded events. Two options for the tower were investigated viz. steel braced frame and concrete shaft. The effect of soil structure interaction (SSI) was also examined. It was concluded that the concrete tower option provided the desired performance for both fixed base and SSI cases. On the other hand, the steel tower performed well for the fixed base case but its performance was close to the threshold when SSI was also considered. Effect of soil properties variation on SSI was also examined for both tower options and was found to be relatively insignificant. Copyright © 2008 John Wiley & Sons, Ltd.     

Energy use in the rural areas of India: setting up a rural energy data base

Aggregating and forecasting demand are crucial parts of energy planning. While a large number of energy consumption surveys have been conducted in the past in the rural energy sector of India, the lack of sufficient data and its compilation, coupled with doubt about the quality of data, has made the task extremely difficult. This paper summarizes our recent effort to compile, computerize and analyze data from 638 village energy consumption surveys covering over 39,000 households, carried out by different organisations between 1985 and 1989. The details of the level of information provided in the survey reports, area of survey, land use pattern, asset ownership, etc., of the collated studies are presented. Results based on the analysis of the energy consumption data compiled are then discussed. The national average for rural domestic thermal energy consumption (excluding water and space heating) estimated through this work (629 kcal or 2.63 MJ per capita daily) is much similar to the rural domestic thermal energy requirement assumed in most energy planning exercises in India in the past. The useful thermal energy consumption varies from 325 to 1065 kcal/cap/d (1.36-4.46 MJ/cap/d) in the East Coast Plain and Hills and the Eastern Himalayan Regions, respectively. Reconfirming the predominance of firewood, the data reveals that the contribution of firewood to the domestic thermal energy consumption has remained at about 58% over the last three decades; dungcake and agricultural residues contribute almost equally in the remaining share. At the national level, our estimates indicate that at least 180 million tonnes of firewood, 40 million tonnes of dungcakes and 30 million tonnes of agricultural residues were consumed in the rural sector for meeting the domestic thermal energy requirement in 1991. The paper also compares the estimates with those based on other surveys in India.     

Numerical Simulation of Anisotropic Shrinkage in a 2D Compact of Elongated Particles

Microstructural evolution during simple solid-state sintering of two-dimensional compacts of elongated particles packed in different arrangements was simulated using a kinetic, Monte Carlo model. The model used simulates curvature-driven grain growth, pore migration by surface diffusion, vacancy formation, diffusion along grain boundaries, and annihilation. Only the shape of the particles was anisotropic; all other extensive thermodynamic and kinetic properties such as surface energies and diffusivities were isotropic. We verified our model by simulating sintering in the analytically tractable cases of simple-packed and close-packed, elongated particles and comparing the shrinkage rate anisotropies with those predicted analytically. Once our model was verified, we used it to simulate sintering in a powder compact of aligned, elongated particles of arbitrary size and shape to gain an understanding of differential shrinkage. Anisotropic shrinkage occurred in all compacts with aligned, elongated particles. However, the direction of higher shrinkage was in some cases along the direction of elongation and in other cases in the perpendicular direction, depending on the details of the powder compact. In compacts of simple-packed, mono-sized, elongated particles, shrinkage was higher in the direction of elongation. In compacts of close-packed, mono-sized, elongated particles and of elongated particles with a size and shape distribution, the shrinkage was lower in the direction of elongation. The results of these simulations are analyzed, and the implication of these results is discussed.     

Ultrasonic behavior of plastically deformed and heat treated steel

Studies were made on the longitudinal ultrasonic velocity and its attenuation characteristics in medium carbon steel forging subjected to 0–60% hot upsetting followed by heat treatment. The fineness of ferrite and pearlite increased with increasing deformation and cooling rate during heat treatment. The area fraction of pearlite increased from 21% to 45% as well as the mean interlamellar spacing in pearlite decreased from 8.79 μm to 0.689 μm in the 40% deformed (upsetted) normalized sample It was observed that the ultrasonic velocity decreased with increasing degree of deformation. The velocity was found to be highest in the normalized steel acquiring a value of 5920 m/s and lowest in hardened steel acquiring a value of 4979 m/s. The attenuation decreased with increasing deformation resulting in increased back wall echo heights. The residual stresses on the surface of typical 60% deformed and annealed steel samples using x-ray diffractometry were measured to be — 39.7 MPa (compressive) and — 188.0 MPa (compressive) respectively.     

Short- and long-term components of working memory in the rat.

In Experiment 1 of this report, we examined the neuropharmacological nature of short-term working memory of rats trained to retrieve food from all arms of a 12-arm radial maze. Delay intervals of varying length were placed between Choices 6 and 7. Lanthanum (LaCl?) and glutamate (GLU) injected bilaterally into the hippocampus effectively impaired retention over short delay intervals, which suggests a possible role for calcium and/or potassium and for glutamate in working memory. However, another equally likely explanation for the amnesic effects of LaCl? and GLU is that these drugs impaired reference memory. To test more directly the hypothesis that LaCl?, GLU, or ANI might differentially affect working and reference memory, we tested the effects of these drugs on performance of rats trained to retrieve food from only 8 arms of the 12-arm maze in Experiment 2. The remaining 4 arms were never baited, in order to test reference memory function. We predicted that rats would make errors only in baited arms (i.e., errors of working memory). Instead, results of Experiment 2 showed that LaCl?, GLU, or ANI injection produced errors in unbaited arms even before a 120-min delay. If rats were injected with LaCl? or GLU, baited-arm errors were observed only after the delay period. No impairment of performance on baited arms were observed after injection of ANI. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Susceptibility of several varieties of soybean to Ephestia cautella (Walker) (Lepidoptera: Phycitidae)

Ephestia cautella (Walker) was reared on 39 varieties of soybean at 30 ± 1°C, 80 ± 5% r.h. and 12 hr light: 12 hr dark photoperiod. Larvae were reared individually on whole grains and flours of each variety and larval period, pupal period, per cent pupation and per cent adult formation were recorded. Larvae failed to develop on grains of 13 varieties while grains of Grant, Clark glabrous, Clark dense, Henry, Harrowmanchu and Hawkey-63 were highly susceptible to this pest. On the other hand larvae completed development successfully on all 39 varieties when seeds were ground into flours. It was also clear that UPSM-158 was somewhat tolerant to the attack of this pest while UPSM-120, Hawkey-63, Clark-63, Chippewa, UPSM-57, Harrowmanchu, Hampton, Goldsoy, Davis, Hood, and Kohachugatsu were also less efficient in supporting the development. Addition of 5% yeast to these varieties produced remarkable improvement in the quality of the diet which indicated that the flours of these varieties were deficient in one or more essential nutrients.     

Synthesis and characterization of butyl acrylate/methyl methacrylate/glycidyl methacrylate latexes

The butyl acrylate (BA)/methyl methacrylate (MMA), and glycidyl methacrylate (GMA) composite copolymer latex was synthesized by seeded emulsion polymerization technique taking poly(methyl methacrylate) (PMMA) latex as the seed. Four series of experiments were carried out by varying the ratio of BA : MMA (w/w) (i.e. 3.1 : 1, 2.3 : 1, 1.8 : 1, and 1.5 : 1) and in each series GMA content was varied from 1 to 5% (w/w). The structural properties of the copolymer were analyzed by FTIR, ¹H‐, and ¹³C‐NMR. Morphological characterization was carried out using transmission electron microscopy (TEM). In all the experiments, monomer conversion was ～99% and final copolymer composition was similar to that of feed composition. The incorporation of GMA into the copolymer chain was confirmed by ¹³C‐NMR. The glass transition temperature (T_g) of the copolymer latex obtained from the differential scanning calorimetry (DSC) curve was comparable to the values calculated theoretically. With increase in GMA content, particles having core‐shell morphology were obtained, and there was a decrease in the particle size as we go from 2–5% (w/w) of GMA. The adhesive strength of the latexes was found to be dependent on the monomer composition. With increase in BA : MMA ratio, the tackiness of the film increased while with its decrease the hardness of the film increased. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010