Grain morphology of Cu damascene lines

The evolution of the grain structure through annealing of narrow damascene Cu interconnects is important for any further design of highly integrated circuits. Here we present a comprehensive transmission electron microscopy study of damascene lines between 80 nm and 3000 nm wide. Experimental results clearly indicate that morphology evolutions through annealing are strongly influenced by the line width. If the lines are wider than 250 nm a strong connection between the grain structure within the lines and the overburden copper is present at least after sufficient annealing. Once the lines are as small as 80 nm the grain structure within the lines are only weakly connected to the overburden copper grown above.     

高温处理对镍诱导晶化硅上的薄膜晶体管性能的影响

采用标准双栅 CMOS工艺在镍诱导非晶硅横向晶化形成的多晶硅上制造了高性能的薄膜晶体管 ,并详细研究了器件制备前高温预处理对薄膜晶体管性能的影响 .实验发现不同的温度处理 ,将引起器件性能的显著变化 .在10 0 0℃预处理温度下获得了最好的器件性能 .10 0 0℃在 NMOS管中测得的电子迁移率达 314 cm2 / (V· s) ,分别比在 110 0℃和未做高温处理下的大 10 %和 2 2 % .10 0 0℃下器件的最大开关电流比也达到了 3× 10 8.对器件的进一步重复性研究证实了上述结果的可靠性     

Lithium-Ion Desolvation Induced by Nitrate Additives Reveals New Insights into High Performance Lithium Batteries

Electrolyte additives have been widely used to address critical issues in current metal (ion) battery technologies. While their functions as solid electrolyte interface forming agents are reasonably well-understood, their interactions in the liquid electrolyte environment remain rather elusive. This lack of knowledge represents a significant bottleneck that hinders the development of improved electrolyte systems. Here, the key role of additives in promoting cation (e.g., Li⁺) desolvation is unraveled. In particular, nitrate anions (NO₃⁻) are found to incorporate into the solvation shells, change the local environment of cations (e.g., Li⁺) as well as their coordination in the electrolytes. The combination of these effects leads to effective Li⁺ desolvation and enhanced battery performance. Remarkably, the inexpensive NaNO₃ can successfully substitute the widely used LiNO₃ offering superior long-term stability of Li⁺ (de-)intercalation at the graphite anode and suppressed polysulfide shuttle effect at the sulfur cathode, while enhancing the performance of lithium–sulfur full batteries (initial capacity of 1153 mAh g⁻¹ at 0.25C) with Coulombic efficiency of ≈100% over 300 cycles. This work provides important new insights into the unexplored effects of additives and paves the way to developing improved electrolytes for electrochemical energy storage applications.     

IP over terrestrial ATSC DTV channels: performance evaluations on data transmission throughput

The throughput of IP (UDP and TCP) data transmission over terrestrial ATSC DTV channels was evaluated. A testbed was developed for this purpose. Various issues affecting the throughput of IP data transmission over DTV channels were analyzed, such as channel noise, traffic load, IP packet size and return link capacity. Results obtained from these tests offer valuable information for broadcasters who plan to implement datacasting services over ATSC DTV systems.     

Quantitative coherent anti-Stokes Raman scattering microspectroscopy using a nanosecond supercontinuum light source

We describe and characterize a multiplex CARS microspectroscopic system that uses a nanosecond supercontinuum generated from a photonic crystal fiber and a sub-nanosecond pulse laser. This system has a high spectral resolution (<0.1 cm^?1) and an ultrabroadband spectral coverage (>2500 cm^?1). The estimated spatial resolutions are 0.45 μm (lateral) and 4.5 μm (axial), respectively. This system enables us to obtain CARS spectra and corresponding images in the fingerprint region as well in the CH stretch region. Using this system, we have successfully obtained label-free and multi-mode vibrational images of a yeast cell.     

Application of local error method to SSSF simulation of vector propagation in dispersion compensated optical links

A local error method based on an analytical scheme previously developed for the scalar optical fiber channel is applied to the second-order symmetrized split-step Fourier simulation of polarization multiplexed signal propagation through dispersion compensated optical fiber links. It is found that the global simulation accuracy for the vector propagation can be satisfied using the local error bound from a scalar propagation model for the same global error over a large range of simulation accuracy, chromatic dispersion, and differential group delay. Furthermore, carefully designed numerical simulations are used to show that similar local simulation error are obtained for vector simulations and that the similar local error leads to higher computational efficiency compared to other prevalent step-size selection schemes. The scaling of the global simulation error with respect to the number of optical fiber spans is demonstrated, and global error control for multi-span simulations is proposed. Combining the local error and global error control, the developed simulation scheme can significantly speed up the time-consuming simulations in coherent optical fiber communication system analysis and design.     

Interfacial Strain Gradients Control Nanoscale Domain Morphology in Epitaxial BiFeO3 Multiferroic Films

Domain switching pathways fundamentally control performance in ferroelectric thin film devices. In epitaxial bismuth ferrite (BiFeO₃) films, the domain morphology is known to influence the multiferroic orders. While both striped and mosaic domains have been observed, the origins of the latter have remained unclear. Here, it is shown that domain morphology is defined by the strain profile across the film–substrate interface. In samples with mosaic domains, X‐ray diffraction analysis reveals strong strain gradients, while geometric phase analysis using scanning transmission electron microscopy finds that within 5 nm of the film–substrate interface, the out‐of‐plane strain shows an anomalous dip while the in‐plane strain is constant. Conversely, if uniform strain is maintained across the interface with zero strain gradient, striped domains are formed. Critically, an ex situ thermal treatment, which eliminates the interfacial strain gradient, converts the domains from mosaic to striped. The antiferromagnetic state of the BiFeO₃ is also influenced by the domain structure, whereby the mosaic domains disrupt the long‐range spin cycloid. This work demonstrates that atomic scale tuning of interfacial strain gradients is a powerful route to manipulate the global multiferroic orders in epitaxial films.     

Toward Stable Cycling of a Cost-Effective Cation-Disordered Rocksalt Cathode via Fluorination

The recently developed Li-excess cation-disordered rock salts (DRXs) exhibit an excellent chemical diversity for the development of alternative Co/Ni-free high-energy cathodes. Herein, the synthesis of a highly fluorinated DRX cathode, Li_1.2Mn_0.6Ti_0.2O_1.8F_0.2, based on cost-effective and earth-abundant transition metals, via a solid-state reaction, is reported. The fluorinated DRX cathode using ammonium fluoride precursor exhibits more uniform particle size and delivers a specific discharge capacity of 233 mAh g⁻¹ and specific energy of 754 Wh kg⁻¹, with 206 mAh g⁻¹ retained after 200 cycles. The combined synchrotron X-ray absorption spectroscopy and resonant inelastic X-ray scattering spectroscopy analysis reveals that the remarkable cycling performance is attributed to the high fluorination and thus enhanced Mn content, enabling the utilization of more Mn redox than the oxide analog. This study demonstrates a great promise to develop next-generation cost-effective DRX cathodes with enhanced capacity retention for high-energy Li-ion batteries.     

Impact of Blend Morphology on Interface State Recombination in Bulk Heterojunction Organic Solar Cells

This work is a reinvestigation of the impact of blend morphology and thermal annealing on the electrical performance of regioregular‐P3HT:PC₆₀BM bulk heterojunction organic solar cells. The morphological, structural, and electrical properties of the blend are experimentally investigated with atomic force microscopy, X‐ray diffraction, and time‐of‐flight measurements. Current–voltage characteristics of photodiode devices are measured in the dark and under illumination. Finally, the existence of exponential electronic band tails due to gap states is experimentally confirmed by measuring the device spectral response in the subband gap regime. This method reveals the existence of a large density of gap states, which is partially and systematically reduced by thermal annealing. When the band tails are properly accounted for in the drift and diffusion simulations, experimentally measured charge transport characteristics, under both dark and illuminated conditions and as a function of annealing time, can be satisfactorily reproduced. This work further confirms the critical impact of tails states on the performance of solar cells.