An algebraic formulation of inverse problems in MP dynamics

Metabolic P (MP) grammars are a particular class of multiset rewriting grammars introduced in the MP theory for modelling metabolic processes. In this paper, a new algebraic formulation of inverse problems, based on MP grammars and Kronecker product, is given, for further motivating the correctness of the LGSS (Log-Gain Stoichiometric Stepwise) algorithm, introduced in 2010s for solving inverse problems in the MP framework. At the end of the paper, a section is included that introduces the problem of multicollinearity, which could arise during the execution of LGSS, and that defines an algorithm, based on a hierarchical clustering technique, that solves it in a suitable way.     

Performance comparison between partial oxidation and methane steam reforming processes for solid oxide fuel cell (SOFC) micro combined heat and power (CHP) system

The aim of this research work is to describe in qualitative and quantitative form the performance of a micro Combined Heat and Power system for residential application based on Solid Oxide Fuel Cell fueled by natural gas with two different types of pre-reforming systems, namely Steam Reforming and Partial Oxidation and recirculation of anode and cathode gas.The comparative analysis among the different configurations will lead us to conclude that maximum efficiency is achieved when cathode and anode gas recirculation are used along with steam methane reforming. Further Steam Methane Reforming process produces a higher electrical system efficiency compared to Partial oxidation reforming process.Efficiency is affected when running the system in part load mode mainly due to heat loss, additional natural gas supplied to the burner to satisfy the required heat demand inside the system, and ejector efficiency drop in the recirculation system. Due to high temperature of operation heat loss strongly affects the system efficiency especially at part load operation.     

Hyperazeotropic ethanol salted-out by extractive distillation. Theoretical evaluation and experimental check

A distillation process for the production of hyperazeotropic ethanol from a dilute wine obtained from the fermentation of biomass has been studied. This process utilizes the coupling of a soft preconcentration stage and of a dehydration stage based on the salting-out effect produced by calcium chloride on the ethanol in an aqueous solution, with the disappearance of the azeotrope. The salt is employed in a close cycle, due to the presence of a regeneration stage, therefore no consumption of calcium chloride is noticed.

The distillation process utilizes one column consisting of two sections operating at different pressures in order to reach an efficient heat recovery.

In this paper, a simplified flow-sheet of the process and the principal operating conditions of the distillation column are illustrated. When compared with other processes, conventional or under development, this one is characterized by the promising reduction of the specific energy requirement.

The operating conditions chosen for the distillation with salt have been experimentally checked using a laboratory column running continuously with calcium chloride as salting-out agent. Moreover, the experiments confirmed the reliability of the mathematical model of the process. Further experiments are in progress with the aim of utilizing a mixture of salts which can be fed from the bottom of the dehydration section back to the fermentor, so that the salt regeneration stage can be reduced.     

Automatic end-of-line tuning for a motion inverter in agricultural tractors

End-of-line tuning is a crucial step for any mass-produced system endowed with automatic controllers. As a matter of fact, due to components tolerances and spreads in the production line, the controller tuning performed on a prototype system is never optimal on the final product. In many industrial applications, though, the end-of-line tuning is performed by human testers, and this does not always guarantee an objective assessment of the closed-loop system quality. This paper proposes a systematic way to design an automatic tuning procedure for a motion-inverter controller in agricultural tractors, which allows to significantly reduce the costs of end-of-line tuning and to obtain a homogeneous manoeuvre quality in all vehicles. The proposed automatic tuning system adapts the controller parameters governing the open-loop phase of the manoeuvre until a predefined manoeuvre quality is achieved. The parameters adaptation phase is guided by an on-line objective assessment of the manoeuvre quality from measured data, which allows to automatically classify the performed manoeuvre with respect to its quality attributes. The effectiveness of the proposed approach is assessed on a prototype vehicle.     

Assessment of bioenergy potential in Sicily: A GIS-based support methodology

A Geographical Information System (GIS) supported methodology has been developed in order to assess the technical and economic potential of biomass exploitation for energy production in Sicily. The methodology was based on the use of agricultural, economic, climatic, and infrastructural data in a GIS. Data about land use, transportation facilities, urban cartography, regional territorial planning, terrain digital model, lithology, climatic types, and civil and industrial users have been stored in the GIS to define potential areas for gathering the residues coming from the pruning of olive groves, vineyards, and other agricultural crops, and to assess biomass available for energy cultivation. Further, it was possible to assess the potential of biodiesel production, supposing the cultivation of rapeseed in arable crop areas. For the biomass used for direct combustion purposes, the economic availability has been assessed assuming a price of the biomass and comparing it with other fuels. This assessment has shown the strong competitiveness of firewood in comparison with traditional fossil fuels when the collection system is implemented in an efficient way. Moreover, the economic potential of biodiesel was assessed considering the on-going financial regime for fuel. At the same time, the study has shown a significant competitiveness of the finished biomass (pellets), and good potential for a long-term development of this market. An important result was the determination of biofuel production potential in Sicily. An outcome of the study was to show the opportunities stemming from the harmonisation of Energy Policy with the Waste Management System and Rural Development Plan.     

Photocatalytic Inactivation of Legionella Pneumophila and an Aerobic Bacteria Consortium in Water over TiO2/SiO2 Fibres in a Continuous Reactor

A continuous photoreactor, working in a total recycle mode and irradiated by a low-pressure Hg lamp, has been used to study the bactericidal effect of a photocatalyst, formed by TiO₂ embedded in SiO₂ fibres, on Legionella pneumophila and a consortium of common gram-negative aerobic bacteria: (Escherichia coli, Klebsiella sp., Pseudomona sp. and Proteus sp.) in water. The kinetic modeling of the inactivation process, carried out with the measured values of viable bacteria concentration at the outlet of photoreactor, evidenced that for each pass inside the photoreactor the ratio between the outlet and inlet cell concentrations was of order of 0.01 for the inactivation of L. pneumophila. For the other aerobic bacteria, which are usually taken as reference in photocatalytic bacteria inactivation studies, this ratio was of order of 0.3 for the first hour of illumination, while upon prolonged irradiation (up to 9 h) this ratio increased to 0.7. Several factors inducing this latter decrease of efficiency are possible, as e.g. competition for photocatalytic attack between microorganisms and organic compounds released by damaged bacteria or photoinduced alteration of a small fraction of still viable bacteria making them less interactive with the photocatalyst. The inactivation mechanism normally proposed for common bacteria involves an initial attack of the photogenerated radicals to the outer membrane; the consequent membrane dispersion allows the radicals to damage the cytoplasmic membrane. The higher lethality of the photocatalytic method observed towards Legionella: (in comparison to the other aerobic bacteria) is explained considering that the radicals attack the Legionella secretion system, which is adapted for high virulence and would become activated for and through adhesion to the TiO₂ surface. This attack would then be able to inactivate L. pneumophila without dispersing the outer membrane. Apart from this, the water flow through the catalyst fibres can facilitate the bacteria transport towards the anatase surface, and additionally the generated shear stress may help adhesion, at least for some bacteria as E. coli, contributing further to improve the photokilling efficiency; both factors may contribute to the efficiency of this photoreactor configuration.     

Isolation of a hydroxytyrosol-rich extract from olive leaves (<Emphasis Type="Italic">Olea Europaea</Emphasis> L.) and evaluation of its antioxidant properties and bioactivity

In this research, a phenol extract of high hydroxytyrosol (OLPE) content was obtained from olive leaves (Olea europaea L.), and subsequently tested under different contexts. The method used to obtain the OLPE basically involved two steps: the use of strongly-acid aqueous steam, generated from 10% HCl (v/v) at 100°C, to directly hydrolyse the native complex phenols from integral olive leaves, and OLPE recovery by liquid–liquid extraction with ethyl acetate. Hydrolysis time was 1 h. Finally, the dried extract was dissolved in distilled water. The OLPE total phenols were determined by Folin–Ciocalteu’s method and by HPLC analysis. Hydroxytyrosol was about 92% of the total phenols present in OLPE, and the yield was about 0.2% on fresh leaves. OLPE showed antioxidant effects on different food lipids and did not inhibit lactic acid bacteria growth; however, it showed cytotoxicity on NIH/3T3 fibroblasts and human umbilical vein endothelial cells at concentrations higher than 0.32 mM (as hydroxytyrosol).     

Self-piercing riveting for aluminium alloys-composites hybrid joints

In the paper, the growing interest on hybrid joints developed between composite panels and aluminium alloys blanks is focused. The self-piercing riveting operation is considered and its feasibility for the proposed joints verified. The most relevant process parameters were investigated in order to determine a suitable process window and, what is more, the mechanical performances of the developed joints were investigated in order to determine process parameters aimed to maximise them. Finally, the failure mechanics of the obtained joints were considered in order to highlight the mechanisms which occur and determine the lost of the load carrying capability of the joints. The developed experiments demonstrated that self-piercing riveting can be effectively used to join fibreglass composite panels and aluminium blanks.     

The canonical processes of a dramatized approach to information presentation

This paper describes the application “Carletto the spider” in terms of the mapping with the canonical processes of media production. “Carletto the spider” is a character-based guide to a historical site and implements the Dramatour approach for the design of drama-based interactive presentations. Dramatization makes presentations more engaging, thus improving the reception of the content by the user. The major technical issue of the approach is the segmentation of the presentation into audiovisual units that are edited on-the-fly in a way that guarantees dramatic continuity while adapting to the user response. We describe the workflow of the application and its mapping to the canonical processes of media production, envisaging possible standardizations for the application portability.     

Synthesis of Yb nanoparticles by laser ablation of ytterbium target in sodium bis(2-ethylhexyl)sulfosuccinate reverse micellar solution

Surfactant-coated ytterbium nanoparticles were produced by Nd:YAG laser ablation of a Yb bulk target immersed in sodium bis(2-ethylhexyl)sulfosuccinate (AOT)/n-heptane micellar solution. In our experimental conditions, as highlighted by IR spectroscopy, AOT molecules are not decomposed by the intense laser pulses but play a pivotal role in the stabilisation of Yb nanoparticles. The formation of Yb nanoparticles in the liquid phase was monitored by UV-Vis spectroscopy whereas the Yb/AOT composites obtained by evaporation of the organic solvent were characterised by XPS and TEM. Data analysis consistently shows the presence of surfactant-coated, nearly spherical and non-interacting Yb nanoparticles of mean diameter of 3 nm.Moreover, the presence of bigger polycrystalline nanoparticles (about 30%) in coexistence with smaller mono crystalline ones indicates that, after the rapid formation of the pristine Yb nanoparticles from plume condensation, two processes effectively compete for their size distribution: nanoparticle agglomeration and surfactant adsorption.