Comparison of the electrochemical properties of intermediate temperature solid oxide fuel cells based on protonic and anionic electrolytes

The physico-chemical properties of two protonic electrolytes BaCe_0.8Y_0.2O_3-δ and BaCe_0.9Y_0.1O_3-δ were investigated. The BaCe_0.8Y_0.2O_3-δ electrolyte showed better crystallographic purity and lower amount of carbonate phase on the surface. A comparison between the BaCe_0.8Y_0.2O_3-δ protonic electrolyte supported cell and an anionic (Ce_0.8Gd_0.2O_1.95) one was made. The maximum power densities (IR-free) of 183 mW cm⁻² and 400 mW cm⁻² were obtained in H₂ (R.H. 3%) at 700 °C, for the protonic and anionic electrolyte based cells, respectively.     

Effect of Al addition on pressureless sintering of B4C

The effect of Al addition on pressureless sintering of B₄C ceramic was analyzed in the present work. Different amounts of Al, from 0 to 5 wt.% were added to the base material and pressureless sintering was conducted at 2050 and 2150 °C under argon atmosphere. Microstructure, crystal phases and density evolution were studied and correlated to Al additions and firing temperature. Density and grain size of sintered samples, increased significantly with Al load while less evidence is the effect of sintering temperature; 94% dense material was obtained by adding 4 wt.% Al regardless of the maximum firing temperature.     

Three dimensional mechanical model for simulating the NSM FRP strips shear strength contribution to RC beams

Shear strengthening of Reinforced Concrete (RC) beams by means of Near Surface Mounted (NSM) Fiber Reinforced Polymer (FRP) strips is an emerging technique for structural rehabilitation that is gaining increasing interest in the FRP community, mainly because of some advantages it provides with respect to the better consolidated technique of the Externally Bonded Reinforcement (EBR). Those advantages mainly encompass a better exploitation of material and a higher protection against vandalism, along with a relative faster applicability. Yet, the behavior of such NSM FRP strips is extremely complex, as can be gathered by experimental evidence, due to the complex geometry, the nonlinear mechanical properties of bond, and the scatter affecting the concrete tensile properties, along with their nonlinearity. In an attempt to provide valuable contribution to a better understanding of their behavior, a three dimensional mechanical model for simulating the shear strength contribution provided by a system of NSM FRPs to a RC beam throughout the loading process is herein presented along with the main findings. It correctly interprets the experimental evidence, taking into account complex phenomena such as the interaction between bond transferred force and concrete fracture, along with the interaction between adjacent strips.     

Localized formation and size tuning of CdS nanocrystals upon irradiation of metal precursors embedded in polymer matrices

We present a method of spatial and dimensional controlled formation of CdS quantum dots into polymer matrices by light irradiation. The initial samples consist of Cd thiolate precursors doped in TOPAS polymer matrix. Under pulsed UV laser irradiation the precursors are photolysed driving to the nucleation of CdS nanocrystals, with increasing size and concentration, related to the number of UV pulses. The formed quantum dots are localized in the irradiated area, while the host polymer remains macroscopically unaffected by the UV irradiation. In this study we investigate how the formation of the nanocrystals (size, dimensions, and concentration) is affected by the use of different irradiation conditions (wavelength, number of pulses), revealing information about the different pathways followed during the formation. The change of the size of the dots results in the change of the peak of their emission due to the quantum size effect, which is studied by fluorescence measurements. The results are reinforced by TEM microscopy and by XRD measurements. The main advantages of the presented method are the size tuning of the produced dots and their spatial confinement inside the host matrix, not possible by the other methods used until now (thermal annealing, mixing etc.).     

Two-dimensional stress analysis of multiregion functionally graded materials using a field boundary element model

In the work a field boundary element model able to solve elastic functionally graded materials solids response is presented.Integral equilibrium equations are derived using as weight function the homogeneous elasticity fundamental solution that does not depend on the variability of the material properties. It is then possible to apply the proposed formulation when fundamental solutions are not available. In the model a domain integral arises, yielding to field boundary integral equations. However, in many practical applications, the variability of constitutive laws take place at the interface of homogeneous regions, where graded transition is obtained by the technological process. In such cases, because volume elements describe only the graded part of the structure, the computational effort is strongly reduced.     

Ultra-small graphene oxide functionalized with polyethylenimine (PEI) for very efficient gene delivery in cell and zebrafish embryos

Efficient DNA delivery is essential for introducing new genes into living cells. However, effective virus-based systems carry risks and efficient synthetic systems that are non-toxic remain to be discovered. The bottle-neck in synthetic systems is cytotoxicity, caused by the high concentration of DNA-condensing compounds required for efficient uptake of DNA. Here we report a polyethyleneimine (PEI) grafted ultra-small graphene oxide (PEI-g-USGO) for transfection. By removing the free PEI and ensuring a high PEI density on small sized graphene, we obtained very high transfection efficiencies combined with very low cytotoxicity. Plasmid DNA could be transfected into mammalian cell lines with up to 95% efficiency and 90% viability. Transfection in zebrafish embryos was 90%, with high viability, compared to efficiencies of 30% or lower for established transfection technologies. This result suggests a novel approach to the design of synthetic gene delivery vehicles for research and therapy.      

Bioactive and Antioxidant Activity from Citrus bergamia Risso (Bergamot) Juice Collected in Different Areas of Reggio Calabria Province,Italy

The chemical composition and antioxidant activity of juice extracted from seven samples of bergamot (Citrus bergamia Risso) collected in different areas of Reggio Calabria Province were investigated. The ascorbic acid, total polyphenol, and flavonoid contents were determined. Total flavonoids and polyphenols were analyzed by ultraviolet spectra, while flavanone content was analyzed by high-performance liquid chromatography. The antioxidant activity of the fractions was assessed using three representative assays: 2,2′-azinobis(3-ethylbenzothiazoline 6-sulfonic acid), 1,1-Diphenyl-2-picryl-hydrazyl radical quenching and β-carotene bleaching test. The main flavanones were naringin, neohesperedin, and neoeriocitrin, and their average content 242.4 ± 1.8, 183.0 ± 0.6, and 247.0 ± 1.4 mg mL^–1, respectively. The results showed that bergamot juice possessed a good quality and a valuable source of health promoting constituents. In fact it contained eriocitrin, naringin, neoeriocitrin, and neohesperedin, which may contribute differentially to the antioxidant capacity.     

中国古代祭天坛庙建筑中的学问

通过对中国古代祭天坛庙建筑一些相关含义的探讨，深入研究其本初的涵义，以解读其中易被当代人忽略的传统学问。重点探讨祭天建筑之玄学意义，阐述“天、地、人”的基本概念并以北京天坛为重点案例展开对坛庙建筑中数的神秘含义学的讨论。