Effect of P2O5 on the Structural and Magnetic Properties of Magnetite‐Based Glass‐Ceramics

The specific morphology and magnetic properties of magnetite‐based glass‐ceramics obtained by crystallization of Fe‐containing borosilicate glassmelts in the presence of P₂O₅ as nucleating agent are investigated. We found that the distribution of the tiny nanoparticles of magnetite determines the low temperature response to magnetic field. The observed effects are discussed with respect to the following factors: (1) the existence of a multimodal size distribution of the tiny grains as revealed by Mössbauer spectroscopy, magnetometry, and high‐resolution electron microscopy; (2) the existence of a disordered layer at the grain surface which is driven by field in a magnetically ordered state; and (3) the interplay between the relaxation mechanisms in different temperature ranges.     

Sorption/release of diclofenac sodium in/from free‐standing poly(acrylic acid)/poly(ethyleneimine) multilayer films

Polyelectrolyte multilayer films deposited onto various substrates have been used extensively as drug delivery systems. However, little attention has been paid to the release of drugs from free‐standing polymeric films. Herein, we report the construction of thermal crosslinked free‐standing poly(acrylic acid) (PAA)/branched poly(ethyleneimine) (PEI) multilayer films composed of 25 double layers [(PAA/PEI)₂₅] and their use in sorption/release of diclofenac sodium (DS). The (PAA/PEI)₂₅ multilayer films were characterized by scanning electron microscopy, potentiometric titrations and Fourier transform infrared spectroscopy, while the sorption/release of DS was monitored by UV – Vis spectroscopy. The DS sorption equilibrium data were fitted with five isotherm models (Langmuir, Freundlich, Sips, Dubinin–Radushkevich, and Temkin). The maximum equilibrium sorption capacity, q_m, given by the Langmuir model was 32.42 mg DS/g. The Korsmeyer–Peppas semiempirical equation showed that the release of DS from the free‐standing (PAA/PEI)₂₅ films proceeded by pseudo‐Fickian diffusion, irrespective of the releasing media. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43752.     

Electrochemical impedance spectroscopy and corrosion behaviour of Al2O3-Ni nano composite coatings

In this paper, the results on the electrochemical impedance spectroscopy and corrosion properties of electrodeposited nanostructured Al₂O₃-Ni composite coatings are presented. The nanocomposite coatings were obtained by codeposition of alumina nanoparticles (13 nm) with nickel during plating process. The coating thickness was 50 μm on steel support and an average of nano Al₂O₃ particles inside of coatings at 15 vol.% was present. The structure of the coatings was investigated by scanning electron microscopy (SEM). It has been found that the codeposition of Al₂O₃ particles with nickel disturbs the nickel coating's regular surface structure. The electrochemical behavior of the coatings in the corrosive solutions was investigated by polarization potentiodynamic and electrochemical impedance spectroscopy methods. As electrochemical test solutions 0.5 M sodium chloride and 0.5 M potassium sulphate were used in a three electrode open cell. The corrosion potential is shifted to more negative values for nanostructured coatings in 0.5 M sodium chloride. The polarization resistance in 0.5 M sodium chloride decreases in 24 h, but after that increases slowly. In 0.5 M potassium sulphate solution the polarization resistance decreases after 2 h and after 30 h of immersion the polarization resistance is higher than that of the beginning value. The corrosion rate calculated by polarization potentiodynamic curves obtained after 30 min from immersion in solution is smaller for nanostructured coatings in 0.5 M potassium sulphate (4.74 μm/year) and a little bit bigger in 0.5 M sodium chloride (5.03 μm/year).     

Robustness of quantized control systems with mismatch between coder/decoder initializations

This paper analyzes the stability of linear systems with quantized feedback in the presence of mismatch between the initial conditions at the coder and decoder. Under the assumption of the perfect channel, we show that using the scheme proposed in [Liberzon, D., & Neši?, D. (2007). Input-to-state stabilization of linear systems with quantized state measurements. Institute of Electrical and Electronic Engineers Transaction on Automatic Control, 52, 767-781] it is possible to achieve stability with exponential convergence of linear systems with quantized feedback when the coder and decoder are initialized at different initial conditions.     

Summarizing transactional databases with overlapped hyperrectangles

Transactional data are ubiquitous. Several methods, including frequent itemset mining and co-clustering, have been proposed to analyze transactional databases. In this work, we propose a new research problem to succinctly summarize transactional databases. Solving this problem requires linking the high level structure of the database to a potentially huge number of frequent itemsets. We formulate this problem as a set covering problem using overlapped hyperrectangles (a concept generally regarded as tile according to some existing papers); we then prove that this problem and its several variations are NP-hard, and we further reveal its relationship with the compact representation of a directed bipartite graph. We develop an approximation algorithm Hyper which can achieve a logarithmic approximation ratio in polynomial time. We propose a pruning strategy that can significantly speed up the processing of our algorithm, and we also propose an efficient algorithm Hyper+ to further summarize the set of hyperrectangles by allowing false positive conditions. Additionally, we show that hyperrectangles generated by our algorithms can be properly visualized. A detailed study using both real and synthetic datasets shows the effectiveness and efficiency of our approaches in summarizing transactional databases.     

Preferred color gamut boundaries for wide‐gamut and multiprimary displays

Preferred chroma enhancement and its dependence on hue are studied in a two‐part experiment using a wide‐gamut multiprimary display. Earlier research showed a clear dependence on hue but was limited by the gamut of the display it employed; the present work builds on this while easing the gamut constraints. In the first part of the present experiment, a tuning task was used to refine the preference for chroma boost starting with standard‐gamut (Rec. 709) images. The overall median preferred boost is roughly 20%, but it is not uniform over hues: the preferred boost for orange, yellow, green, and cyan colors is greater than that for blue, magenta, and red colors. Dependence on image content and observer is noted, though a content‐independent chroma boost created by aggregating preference over many images performs well. An adjustment parameter for overall chroma, which incorporates the hue dependence averaged over image content, should be sufficient to handle the vast majority of interobserver variance in preference. In the second part of the experiment, various chroma boost algorithms were evaluated through a paired comparison task. The prescribed hue‐dependent chroma boost is preferred over all other variations, and all hue‐preserving chroma boost variations are preferred over both colorimetrically accurate and na??ve same‐drive‐signal renderings. The results may be applied in display design to select gamut boundaries that maximize satisfaction over the observer population. © 2012 Wiley Periodicals, Inc. Col Res Appl, 39, 169–178, 2014     

The master sintering curves for BaTi0.975Sn0.025O3/BaTi0.85Sn0.15O3 functionally graded materials

The most important aim in the design and processing of functionally graded materials (FGMs) is to produce devices free from any deformation. Smart choices of different combination of graded layers, as well as the heating rate during sintering, are important for the fabrication of high-quality FGMs. In this study, BaTi_0.975Sn_0.025O₃/BaTi_0.85Sn_0.15O₃ (noted as BTS2.5 and BTS15, respectively) FGM was used as a model system for the construction of master sintering curves (MSCs) and estimation of the effective activation energies of sintering for different BTS graded layers. The MSCs were constructed, for BTS2.5 and BTS15 graded layers in FGMs, using shrinkage data obtained by a heating microscope during sintering at four constant heating rates, 2, 5, 10 and 20 °/min. The effective activation energies were determined using the concept of MSC; values of 359.5 and 340.5 kJ/mol were obtained for graded layers BTS2.5 and BTS15, respectively. A small difference of the effective activation energies of chosen powders made it possible for us to prepare high-quality FGMs, without delamination, distortion or other forms of defects.     

A class of non-canonic,driving-point immittance realizations of passive,common-ground,transformerless, two-element-kind RLC networks

A new class of non-canonic, driving-point immittance realizations of passive, common-ground, transformerless, two-element-kind RLC networks with minimum number of nodes is presented. Six new algorithms of realization are developed by application of canonic, orthogonal matrix transformations with reduced number of degrees of freedom. the number of applied RLC elements of one kind can be minimized and of the other kind reduced, while their parameter values are calculated directly in a linear way.     

Modeling Robot “Psycho-Physical” State and Reactions – A New Option in Human–Robot Communication Part 2: Modeling and Simulation

This part of the paper examines numerically the possibility of modeling robot fatigue being representative of a human psychophysical state that can be applied to robots. Temperatures of driving motors are suggested as analogs to fatigue in muscles. Simulation of robot behavior is performed on a typical human task, namely handwriting. Three phases of task execution, characteristic for humans, are observed, i.e. regular motion, reconfiguration after symptoms of fatigue, and degeneration caused by the too long, hard work.     

A Genetic Programming Approach to Rainfall-Runoff Modelling

Planning for sustainable development of water resources relies crucially on the data available. Continuous hydrologic simulation based on conceptual models has proved to be the appropriate tool for studying rainfall-runoff processes and for providing necessary data. In recent years, artificial neural networks have emerged as a novel identification technique for the modelling of hydrological processes. However, they represent their knowledge in terms of a weight matrix that is not accessible to human understanding at present. This paper introduces genetic programming, which is an evolutionary computing method that provides a transparent and structured system identification, to rainfall-runoff modelling. The genetic-programming approach is applied to flow prediction for the Kirkton catchment in Scotland (U.K.). The results obtained are compared to those attained using two optimally calibrated conceptual models and an artificial neural network. Correlations identified using data-driven approaches (genetic programming and neural network) are surprising in their consistency considering the relative size of the models and the number of variables included. These results also compare favourably with the conceptual models.