A solar air heater with variable flow passage width

Different designs of solar air heaters with variable width of the flow channels are investigated.

Four possible geometries for the flow passage are considered with the aim to improve the efficienc of the system by maintaining a constant temperature of the absorber plate.

Efficiencies and plate temperatures are calculated for various designs, among them the most efficient is the one with decreasing duct width.     

Heat transfer from a spinning disk during semi-confined axial impingement from a rotating nozzle

Conjugate heat transfer from a uniformly heated spinning solid disk of finite thickness and radius during a semi-confined liquid jet impingement from a rotating nozzle is studied. The model covers the entire fluid region including the impinging jet on a flat circular disk and flow spreading out downstream under the spinning confinement plate and free surface flow after exposure to the ambient gaseous medium. The model examines how the heat transfer is affected by adding a secondary rotational flow under semi-confined jet impingement. The solution is made under steady state and laminar conditions. The study considered various plate materials such as aluminum, copper, silver, constantan and silicon. Ammonia, water, flouroinert FC-77 and MIL-7808 oil were used as working fluids. The range of parameters covered included Reynolds number (220–900), Ekman number (7.08 × 10^?5–∞), nozzle-to-target spacing (β = 0.25–1.0), disk thicknesses to nozzle diameter ratio (b/d_n = 0.25–1.67), Prandtl number (1.29–124.44) and solid to fluid thermal conductivity ratio (36.91–2222). It was found that a higher Reynolds number increased local heat transfer coefficient reducing the interface temperature difference over the entire disk surface. The rotational rate also increased local heat transfer coefficient under most conditions. An engineering correlation relating the Nusselt number with other dimensionless parameters was developed for the prediction of the system performance.     

Hydrogen production by reforming of liquid hydrocarbons in a membrane reactor for portable power generation—Model simulations

One of the most promising technologies for lightweight, compact, portable power generation is proton exchange membrane (PEM) fuel cells. PEM fuel cells, however, require a source of pure hydrogen. Steam reforming of hydrocarbons in an integrated membrane reactor has potential to provide pure hydrogen in a compact system. In a membrane reactor process, the thermal energy needed for the endothermic hydrocarbon reforming may be provided by combustion of the membrane reject gas. The energy efficiency of the overall hydrogen generation is maximized by controlling the hydrogen product yield such that the heat value of the membrane reject gas is sufficient to provide all of the heat necessary for the integrated process. Optimization of the system temperature, pressure and operating parameters such as net hydrogen recovery is necessary to realize an efficient integrated membrane reformer suitable for compact portable hydrogen generation. This paper presents results of theoretical model simulations of the integrated membrane reformer concept elucidating the effect of operating parameters on the extent of fuel conversion to hydrogen and hydrogen product yield. Model simulations indicate that the net possible hydrogen product yield is strongly influenced by the efficiency of heat recovery from the combustion of membrane reject gas and from the hot exhaust gases. When butane is used as a fuel, a net hydrogen recovery of 68% of that stoichiometrically possible may be achieved with membrane reformer operation at 600 °C (873 K) temperature and 100 psig (0.791 MPa) pressure provided 90% of available combustion and exhaust gas heat is recovered. Operation at a greater pressure or temperature provides a marginal improvement in the performance whereas operation at a significantly lower temperature or pressure will not be able to achieve the optimal hydrogen yield. Slightly higher, up to 76%, net hydrogen recovery is possible when methanol is used as a fuel due to the lower heat requirement for methanol reforming reaction, with membrane reformer operation at 600 °C (873 K) temperature and 150 psig (1.136 MPa) pressure provided 90% of available combustion and exhaust gas heat is recovered.     

An IND-CCA2 Secure Certificateless Hybrid Signcryption

This article proposes a hybrid certificateless signcryption scheme that is secure against adaptive chosen ciphertext adversary in the random oracle model. The scheme combines an asymmetric encryption which is one way against chosen plaintext attack and any One-Time secure symmetric encryption scheme, combined using Fujisaki–Okamoto transformation. Uncommon to many Fujisaki–Okamoto based constructions which ensure message integrity alone, this scheme provides entity authentication in addition. By the choice of a hash function that utilizes the advantage of sponge based construction, the scheme enables the user to incorporate any One-Time secure symmetric encryption by re-configuring the input/output parameters. Fujisaki–Okamoto transformation, which is currently a standard in hybrid constructions, guarantees the indistinguishability against adaptive chosen ciphertext attack. The provision for choosing symmetric encryption in the scheme enables it to be implemented in all sort of cryptographic requirements including those in wireless communication.

     

Analog Circuit Fault Detection Using Location of Poles

A method for detection of parametric faults occurring in linear analog circuits based on location of poles of the Circuit Under Test (CUT) is proposed. In the proposed method, the value of each component of the CUT is varied within its tolerance limit using monte carlo simulation. The upper and lower bounds of magnitude, phase angle, real part and imaginary part of all poles of the CUT are obtained. While testing, the locations of poles are obtained. If any one or more of the poles lies outside the tolerance limit then the CUT is declared faulty. The effectiveness of the proposed method is validated through two benchmark circuits like second order sallenkey band pass filter and fourth order leapfrog low pass filter.     

Organometallic L-Alanine Cadmium Iodide Crystals for Optical Device Fabrication

Single crystals of L-alanine cadmium iodide (LACI) were grown by the slow evaporation technique at room temperature. A single-crystal X-ray diffraction (SXRD) model was used to evaluate the crystal structure of the as-grown LACI crystal. The energy dispersive X-ray (EDX) analysis and ultraviolet-visible-near infrared (UV-vis-NIR) transmittance studies were carried out, and the results reveal the presence of elements in the title compound. From the transmittance data, the optical bandgap as a function of photon energy was estimated, and the different optical constants were calculated. A fluorescence study was performed for the LACI crystal. Thermogravimetric and differential thermal analyses have also been studied to investigate the thermal property of the LACI crystal. The efficiency of the second harmonic generation (SHG) of the title crystal was investigated. The magnetic and electrical properties were estimated by the vibrating sample magnetometer (VSM) analysis and impedance study, respectively.     

Stochastic behaviour of man-machine systems operating under different weather conditions

This paper presents two mathematical models to predict the performance of the man—machine systems under different weather conditions. The operator may be in good or poor physical condition which also affects the performance of the system. Failure rate of the system, rate of change of weather conditions as well as rate of change of physical conditions of the operator are assumed to be constant while the repair time distributions are general. Regenerative technique in MRP is applied to obtain several reliability characteristics of interest.     

Changes in Pigments and Volatiles of Saffron ( Crocus sativusL) During Processing and Storage

Significant variations were observed in the concentration of pigments (10·0–17·0%, moisture-free basis) and flavour components during different post-harvest processing conditions of saffron (stigmas ex Crocus sativus L). The crocin pigments concentration was highest (15–17%) in the saffron samples dried between 35°C and 50°C either in a solar dryer or in an oven dryer and this also resulted in considerable reduction of normal drying time. Under these conditions the main flavouring component, safranal, was at its peak value of 60% in the oil in almost all the samples except the vacuum oven dried samples which interestingly contained 4-β-hydroxysafranal in major amounts. Studies indicated that 4-β-hydroxysafranal may be an intermediate in the formation of safranal. It was observed that prolonged storage affected the pigments and flavour concentration to a great extent, but proper packaging and storage with 5% moisture in the saffron reduced the deterioration, thereby increasing the shelflife of the product.     

Chemotherapeutic agents. XII [1]. Synthesis of Pyrimidines and Fused Pyrimidines as leishmanicides and herbicides

Various bicyclic ( 2 , 3 ) and tricyclic ( 4 , 5 ) heterocycles were prepared by the reaction of 1a , c with dihaloalkanes and polynitrohalobenzene separately. Electrophilic substitution on 1a–c with different alkyl halides yielded mono and dialkyl pyrimidiens ( 6–20 ). Nucleophilic substitution reactions on 18 and 21 with amine and hydrazine separately yielded 22–31 , 21a , b and 41c . Reaction of 25a with ethyl ethoxymethylenecyanoacetate and chloroacetyl chloride separately provided bicyclic compounds 32 and 33 . Condensation-cyclization of 25a with formic, acetic and nitrous acid separately yielded 34a , b and 35 . Reaction of 26a with ethylthiocylycolate and thiourea separately provided 36a and 39 . The latter was alkylated with methyl iodide to 40 . An attempt to cyclize 29a and 30a with thionyl chloride provided bicyclic compounds 37a , b and an uncyclic product 38 . Some of the compounds were screened for leishmanicidal and herbicidal activities and a few of them exhibited significant activity. Leishmaniasis is considered to be one of the most devastating diseases and is ominous to tropical countries. The high toxicity of leishmanicidal drugs in current use, aroused considerable interest to develop new safer and effective chemotherapeutic agents. The only drug pyrimethamine [2] is the representative of pyrimidine derivatives, known as leishmanicides but low order of activity at high dose failed to retain in the clinic. Based on our past experiences in rational designing of leishmanicidal pyrimidine analogs, incorporation of levamisole pharmacophore either in flexible or rigid forms is indispensable for potential activity [1,3] against visceral leishmaniasis. These observations induced an impetus to synthesize pyrimidine analogs as potential leishmanicides.     

Studies on slag deposit formation in pulverized coal combustors. 1. Results on the wetting and adherence of synthetic coal ash drops on steel

As part of a study of slag deposit formation in pulverized-coal-fired boilers, apparent contact angles and adhesion strengths of molten mineral drops contacted with cooler oxidized steel substrates have been investigated. High-speed photography indicated that freezing of the interface between the molten drop and metal surface occurred in milliseconds. Adherence occurred between an oxide film on the metal and the drop, adherence was weak on stainless steels, and particles of oxide film were broken away from the substrate when the drops were sheared off. Higher substrate temperatures gave increased adhesion, with a larger area of strong interaction between the oxide and the drop interface and less area of weak interaction. Addition of compounds to lower the liquidus temperature of the drop gave increased adherence. Pyrite drops were converted to mainly pyrrhotite on melting and showed a high degree of wetting and adherence to the oxidized steel even at low temperatures.