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51.
52.
Elena Bozhevolnaya Anders Lyckegaard Ole. T. Thomsen Vitaly Skvortsov 《Composites Part B》2004,35(6-8):619-627
The paper considers local bending effects induced in the vicinity of inserts in sandwich panels. Such local bending effects are associated with an increase of bending stresses in the sandwich faces and normal and shear stresses in the sandwich core. An earlier developed analytic model [Proceedings of the Sixth International Conference on Sandwich Structures (ICSS-6) (2002) 551] is adapted for the case of a sandwich panel with circular insert, with elastic properties differing from those of the core. The locally induced stresses in the faces and core due to presence of the insert are expressed via simple analytic relations (and charts) enabling an estimation of these local stresses. Finite element analysis is employed to demonstrate the applicability of the analytic model, and a good correspondence between the numerical and the analytical data is found. A study case related to marine applications, namely a circular insert in a sandwich deck panel used for mounting of a rigging fixture, is considered, and optimization of an existing design is carried out. 相似文献
53.
Eugene A Smirnov Maria A Meledina Alexey V Garshev Vitaly I Chelpanov Sven Frost Jan U Wieneke Mathias Ulbricht 《Polymer International》2013,62(5):836-841
Titania microspheres with narrow size distribution and diameters of about 1 µm were prepared and subsequently functionalized using surface‐initiated atom transfer radical polymerization (ATRP) of N‐isopropylacrylamide. The ATRP initiator was immobilized on the particle surface via acylation of surface hydroxyl groups with α‐bromoisobutyryl bromide. Subsequently, an established ATRP reaction system was used for the preparation of titania surface‐grafted poly(N‐isopropylacrylamide) (PNiPAAm). Characterization was performed with electron microscopies, X‐ray diffraction, infrared spectroscopy and dynamic light scattering. It was found that the particle size in aqueous dispersions changed reversibly with temperature as expected for a shell of PNiPAAm, a polymer with a lower critical solution temperature at 32 °C. This confirmed the successful preparation of functional, stimuli‐responsive TiO2 microparticles via a straightforward controlled surface‐initiated polymerization method. 相似文献
54.
Fabrice Burel Hassan Oulyadi Claude Bunel Vladimir Grishchenko Natalya Busko Antonina Barantsova Vitaly Boiko 《Journal of Polymer Research》2011,18(6):2265-2273
Azo-bis(isobutyroamidoxime) was synthesized and used as functionalized initiator to prepare a liquid isoprene bearing amidoxime end groups via radical polymerization. The polymer was characterized by FT-IR, Gel Permeation Chromatography and NMR. In particular, the structure of the polymer was investigated using 1D and 2D NMR techniques. The distribution of the different isoprene units (1,4-trans, 1,4-cis, 1,2 and 3,4), as well as the structure of the amidoxime end-groups was determined. It was found that the structure of the end groups was governed by the steric hindrance of the initiator. Only 1,4 and 4,1 functionalized end units were evidenced, with a majority of 4,1 end units. 相似文献
55.
Svetlana Pavlova Tamara Kharlamova Vladislav Sadykov Tamara Krieger Vitaly Muzykantov Yulia Bespalko 《传热工程》2013,34(11-12):904-916
Mixed ionic?electronic conducting nanocomposites comprising complex oxides - perovskite (lanthanum-strontium nickelate-ferrite [LSFN]) and gadolinium-doped ceria (GDC) have been prepared via ultrasonic dispersion of nanocrystalline powders of LSFNx and GDC in organic solvent with addition of surfactant, followed by drying and sintering up to 1300°C. Their structural and surface properties have been studied by x-ray diffraction, ultraviolet–visible (UV-vis) electron spectroscopy, transmission electron microscopy with elemental analysis, and x-ray photoelectron spectroscopy. Results of impedance spectroscopy, oxygen isotope exchange, O2 temperature-programmed desorption, weight, and conductivity relaxation experiments have revealed a strong positive effect of perovskite?fluorite nanodomain interfaces in composite on the oxygen mobility and reactivity. Testing in wet H2/air feeds for a button-size cell with functionally graded LSFN0.4–GDC cathode layer supported on a thin YSZ layer covering Ni/YSZ cermet has demonstrated high and stable performance, promising for the practical application in the intermediate temperature range. 相似文献
56.
57.
ZnO is an important material which has been widely applied in photodetector, catalyst, gas sensor, field emitter, etc. Yet, its inability to absorb visible light, poor charge transport, and low conductivity limit the application of these devices. Recently, it was discovered that introduction of defects such as oxygen and zinc vacancies into ZnO can effectively improve the existing properties or lead to new and unexpected yet highly desirable characteristics. Herein, we present a systematic review on the available approaches to synthesize oxygen- and/or zinc-deficient ZnO with emphasis on their chemical, structural, and electrical particularities. Furthermore, applications of defective ZnO in various nanoscale devices are discussed in terms of their functionality, reliability, and performance. Finally, we summarize major challenges and offer perspectives for further research in this field. We hope that this review would make a valuable contribution to broaden the knowledge of defective ZnO. 相似文献
58.
Results of an investigation of acousto-optic (AO) cells using single crystals of magnesium fluoride (MgF2) are presented. Two acousto-optic tunable filter (AOTF) cells for imaging application have been designed and tested in the visible and ultraviolet (UV) regions of the spectrum from 190 to 490 nm. The two imaging filters were developed by using the wide-angle AO interaction geometry in the (010) and (11 0) planes of the crystal. These filters were used to obtain spectral images at the shortest wavelengths achieved so far. Advantages and drawbacks of this crystal are discussed and photoelastic, acoustic, and AO properties of MgF2 are examined. The investigation confirmed that MgF2-based AOTF cells can be used in the deep UV region up to 110 nm. 相似文献
59.
An adaptive joint transform correlator for real-time pattern recognition is presented. A reference image for the correlator is generated with a new iterative algorithm. The training algorithm is based on synthetic discriminant functions. The obtained reference image contains the information needed to reliably discriminate a target against known false objects and a cluttered background. Calibration lookup tables of all optoelectronics elements used are included in the design of the adaptive joint transform correlator. Two methods for the implementation of the proposed joint transform correlator in an optodigital setup are considered. Experimental results are provided and compared with those of computer simulations. 相似文献
60.
Pinho ST Gutkin R Pimenta S De Carvalho NV Robinson P 《Philosophical transactions. Series A, Mathematical, physical, and engineering sciences》2012,370(1965):1871-1895
Modelling the longitudinal compressive failure of carbon-fibre-reinforced composites has been attempted for decades. Despite many developments, no single model has surfaced to provide simultaneously a definitive explanation for the micromechanics of failure as well as validated predictions for a generic stress state. This paper explores the reasons for this, by presenting experimental data (including scanning electron microscopic observations of loaded kink bands during propagation, and brittle shear fracture at 45° to the fibres) and reviewing previously proposed micromechanical analytical and numerical models. The paper focuses mainly on virgin unidirectional (UD) composites, but studies for woven and recycled composites are also presented, highlighting similarities and differences between these cases. It is found that, while kink-band formation (also referred to in the literature as microbuckling) is predominant in UD composites under longitudinal compression, another failure mode related to the failure of the fibres can be observed experimentally. It is also shown that the micromechanics of the failure process observed in UD composites is similar to that in other fibre architectures, hence encouraging the adaptation and application of models developed for the former to the latter. 相似文献