Experimental and theoretical aspects of the stabilization of zirconia.

Using the Rietveld method, phases of ceria-doped zirconia, calcined at temperatures of 600 and 900 °C, were quantitatively analysed for different concentrations of ceria. The results show that the stabilization of zirconia depends on the dopant concentration and calcination temperature. Moreover, the theoretical calculation using the ab initio Hartree–Fock–Roothaan method indicates that the most stable phases for ceria-stabilized zirconia are cubic or tetragonal, in accordance with experimental results.     

Short-term effects of thyroid hormones on the Na/H antiport in L-6 myoblasts: high molecular specificity for 3,3',5-triiodo-L-thyronine

The thyroid hormones L-T3 and L-T4 were shown to activate the Na/H antiport in L-6 cells from rat skeletal muscle by a rapid, nongenomic mechanism. Under pH equilibrium conditions, a significant rise in the intracellular pH, measured by the fluorescent pH indicator 2',7'-bis-(carboxyethyl)-5(6)-carboxyfluorescein was observed after the addition of physiological concentrations (10(-10) M) of either L-T3 or L-T4, but with different time courses. L-T3 at all concentrations increased the pH after a delay of 2 min, whereas L-T4 showed a concentration-dependent lag time, going from 11 min at 10(-11) M down to 5 min for a hormone concentration of 10(-6) M. The effect of L-T4 was blocked in the presence of the 5'-deiodinase inhibitor 6-n-propyl-2-thiouracil, suggesting that the difference in lag time between L-T3 and L-T4 was due to the 5'-deiodination process that transforms L-T4 into the bioactive L-T3. In short term studies (<5 min), a high molecular specificity for L-T3 was found, as L-T4, rT3, the D-isomer of T3, and the deaminated analogues were ineffective at physiological concentrations. In analogy with the results found at equilibrium, intracellular pH recovery from an acid load and set-point were increased after 2 min for L-T3 (10(-9) M) and after 10 min for L-T4 (10(-9) M). The effect of the hormones on the intracellular pH was completely blocked by the specific antiport inhibitor 5-(ethyl-N-isopropyl)amiloride. These findings suggest that thyroid hormones may play an active role in the recovery from muscular acidosis through direct stimulation of the Na/H antiport.     

Visible PL Phenomenon at Room Temperature in Disordered Structure of SrWO4 Powder

The SrWO₄ (SWO) powders were synthesized by the polymeric precursor method and annealed at different temperatures. The SWO structure was obtained by X-ray diffraction and the corresponding photoluminescence (PL) spectra was measured. The PL results reveal that the structural order–disorder degree in the SWO lattice influences in the PL emission intensity. Only the structurally order–disordered samples present broad and intense PL band in the visible range. To understand the origin of this phenomenon, we performed quantum-mechanical calculations with crystalline and order–disordered SWO periodic models. Their electronic structures were analyzed in terms of band structure. The appearance of localized levels in the band gap of the order–disordered structure was evidenced and is a favorable condition for the intense PL to occur.     

Alcuni aspetti della struttura formale dei codici lineari

In this work some results are presented regarding the formal structure of codes whose words are built up by means of a system ofn linear forms ink variables (k<n), with coefficients from a finite field. In n. 1, after a review of several properties of these codes, a different proof is given of a theorem, already proved by I. I. Gruscko, on the linear dependence of the aforementioned forms. In n. 2 group codes are considered in greater detail, and a distance is introduced and geometrically characterized. By means of this distance a generalization is given of a theorem (known in the binary case), concerning the choice of the coset leaders in the decomposition of the space of alln-tuples in cosets of a code. In n. 3, finally, a theorem on lattice properties of groups is applied to group codes, and a possible utilization for the construction of codes is pointed out.      

Promotion of CO2 mass transfer in carbonate solutions

A general, physico-chemical analysis of mass transfer rate promotion in the system CO₂-potassium carbonate-water-promoter is presented. Different possible mechanisms of promoter action including homogeneous catalysis, “shuttle” mechanism and surface reactions are discussed and classified. A unified picture of promoter chemistry is presented, showing that differences between inorganic and organic promoters are predominently quantitative, not qualitative.The “shuttle” mechanism is analyzed for absorption. The analysis leads to the prediction that the CO₂ mass transfer rate may be influenced by the liquid hold up. This is related to the fact that, although the reaction in the interface region may be fast enough to enhance the mass transfer rate, the different reaction in the bulk may not be fast enough to maintain chemical equlibrium. This complex type of chemical absorption process has not been considered previously in the literature.     

Simultaneous Flow over and under a Gate

This paper reports the results of an investigation carried out to establish the stage-discharge relationship for a flow simultaneously discharging over and under a sluice or a broad-crested gate. The stage-discharge relationship is deduced by a theoretical analysis, based on the application of the Π-theorem of the dimensional analysis and the incomplete self-similarity theory, coupled with an experimental investigation carried out by using a laboratory flume.