Structural modifications induced by recycling of polypropylene

The effect of numerous reprocessing cycles on transport properties of isotactic polypropylene (iPP) films was studied and related to the change of molecular weight and molecular weight distribution occurring during the recycling. Sorption curves of dichloromethane vapor in different samples of iPP were analyzed at 25°C to investigate the effect of structure modifications on the sorption mode. Moreover, gas permeability measurements were performed to evaluate the influence of reprocessing on the gas transport properties. The results obtained were attributed to modifications in the molecular structure of the polymer, evidenced from gel permeation chromatography (GPC), and to a different morphology of the films, as results from X-ray diffractograms and dynamic-mechanical thermal analysis (DMTA).     

Transport properties of dichloromethane in glassy polymers. I. Atactic polystyrene films

Sorption and diffusion of dichloromethane vapor were measured in atactic polystyrene films, obtained with different cooling conditions and after controlled aging times at different temperatures. The diffusional behavior is characterized by three zones, depending on temperature and penetrant activity. In Zone I, at low activity, the diffusion coefficient is independent of vapor concentration; Zone II is characterized by concentration-dependent diffusion, whereas in Zone III structural transformations are possible. The study of diffusion at three temperatures allowed building of a temperature-penetrant concentration diagram, which is very useful to visualize the different zones of behavior. The aging at room temperature has no effect on the curve of sorption as a function of vapor activity, whereas it determines two effects on the diffusion: a decrease of the zero concentration diffusion coefficient and a more and more anomalous behavior with the aging time. The aging at 70°C produces the same effects on the diffusion behavior as the aging at room temperature; in addition, a decrease sorption is observed at low penetrant activity. The possible presence of ordered domains, impermeable to the vapor, in the samples stored at 70°C, was suggested on the basis of sorption results.     

Variational multiscale large-eddy simulations of the flow past a circular cylinder: Reynolds number effects

Variational multiscale large-eddy simulations (VMS–LES) of the flow around a circular cylinder are carried out at different Reynolds numbers in the subcritical regime, viz. Re = 3900, 10,000 and 20,000, based on the cylinder diameter. A mixed finite-element/finite-volume discretization on unstructured grids is used. The separation between the largest and the smallest resolved scales is obtained through a variational projection operator and finite-volume cell agglomeration. The WALE subgrid scale model is used to account for the effects of the unresolved scales; in the VMS approach, it is only added to the smallest resolved ones. The capability of this methodology to accurately predict the aerodynamic forces acting on the cylinder and in capturing the flow features are evaluated for the different Reynolds numbers considered. The sensitivity of the results to different simulation parameters, viz. agglomeration level and numerical viscosity, is also investigated at Re = 20,000.     

Toxicological Profile of Plasmonic Nanoparticles in Zebrafish Model

Plasmonic nanoparticles are increasingly employed in several fields, thanks to their unique, promising properties. In particular, these particles exhibit a surface plasmon resonance combined with outstanding absorption and scattering properties. They are also easy to synthesize and functionalize, making them ideal for nanotechnology applications. However, the physicochemical properties of these nanoparticles can make them potentially toxic, even if their bulk metallic forms are almost inert. In this review, we aim to provide a more comprehensive understanding of the potential adverse effects of plasmonic nanoparticles in zebrafish (Danio rerio) during both development and adulthood, focusing our attention on the most common materials used, i.e., gold and silver.     

Appraisal of energy recovering sub-grid scale models for large-eddy simulation of turbulent dispersed flows

Current capabilities of Large-Eddy Simulation (LES) in Eulerian–Lagrangian studies of dispersed flows are limited by the modeling of the Sub-Grid Scale (SGS) turbulence effects on particle dynamics. These effects should be taken into account in order to reproduce accurately the physics of particle dispersion since the LES cut-off filter removes both energy and flow structures from the turbulent flow field. In this paper, we examine the possibility of including explicitly SGS effects by incorporating ad hoc closure models in the Lagrangian equations of particle motion. Specifically, we consider candidate models based on fractal interpolation and approximate deconvolution techniques. Results show that, even when closure models are able to recover the fraction of SGS turbulent kinetic energy for the fluid velocity field (not resolved in LES), prediction of local segregation and, in turn, of near-wall accumulation may still be inaccurate. This failure indicates that reconstructing the correct amount of fluid and particle velocity fluctuations is not enough to reproduce the effect of SGS turbulence on particle near-wall accumulation.     

SCIDDICA-SS3: a new version of cellular automata model for simulating fast moving landslides

Cellular Automata (CA) are discrete and parallel computational models useful for simulating dynamic systems that evolve on the basis on local interactions. Some natural events, such as some types of landslides, fall into this type of phenomena and lend themselves well to be simulated with this approach. This paper describes the latest version of the SCIDDICA CA family models, specifically developed to simulate debris-flows type landslides. The latest model of the family, named SCIDDICA-SS₃, inherits all the features of its predecessor, SCIDDICA-SS₂, with the addition of a particular strategy to manage momentum. The introduction of the latter permits a better approximation of inertial effects that characterize some rapid debris flows. First simulations attempts of real landslides with SCIDDICA-SS₃ have produced quite satisfactory results, comparable with the previous model.     

Synthesis, characterization and antimicrobial activity of conjugates based on fluoroquinolon-type antibiotics and gelatin

Different fluoroquinolon-type antibiotics were conjugated to gelatin with the aim to synthesize biomacromolecules with antimicrobial properties. The covalent linkage of the antibiotic was performed by a radical process involving the residues in the side chains of gelatin able to undergo oxidative modifications. The conjugation of antibiotic moieties onto the protein structure was confirmed by FT-IR, UV–Vis, fluorescence, and calorimetric analyses. Biocompatibility tests were performed on human bone marrow mesenchymal stromal cells and the antibacterial properties of bioactive polymers were investigated by appropriate tests against Klebsiella pneumoniae and Escherichia coli. With regard to the tests conducted in the presence of E. coli, a minimum inhibitory concentration (MIC) ranging from 0.05 to 0.40 μg mL^?1 was recorded, while in the presence of K. pneumoniae this concentration varies from 0.10 to 1.60 μg mL^?1. In all the conjugates, the drug moieties retain their biological activity and the MIC values are lower than the resistance parameters of fluoroquinolon-type antibiotics versus Enterobacteriacae. The collected data suggest a broad range of applications, from biomedical to pharmaceutical and food science for all conjugates.     

Speed up of Video Enhancement based on Human Perception

This paper presents SUVEHP (speed up of video enhancement based on human perception), a human perception-based model oriented to reduce the computational time of digital video restoration. In particular, two specific hypothesis tests able to classify degraded frame regions are proposed. Classification is performed in agreement with regions visual significance in order to enable or inhibit motion compensated enhancement. The level of the proposed hypothesis tests is theoretically assessed. Moreover, extensive experimental results on video sequences affected by additive Gaussian noise show that SUVEHP speeds up some standard motion compensated denoisers up to 60%, preserving or even slightly increasing both the objective and subjective visual quality of the restored sequences.