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21.
Using one of the generic models (CO oxidation on Pt with surface-oxide formation) predicting kinetic oscillations in heterogeneous catalytic reactions, we show that the efficiency of two-variable periodic perturbations with respect to converting natural period-1 oscillations to period-l oscillations at the forcing frequency is remarkably sensitive to the kind of perturbations used. Counter-phase perturbations are much more effective compared to in-phase perturbations. The physics underlying these findings is suggestive of their applicability to many other models and/or real systems exhibiting kinetic oscillations. 相似文献
22.
The diffusion of 57 Co isotope on the MgO (100) surface was investigated by the edge-source method. The surface diffusion parameter, αDs δ, where α is the segregation factor, Ds the surface diffusion coefficient, and δ the thickness of the high-diffusivity layer, was determined over the temperature region 750° to 1250°C. An Arrhenius plot shows a break at ∼1100°C. Below this temperature ionic or localized transport predominates and above it nonlocalized transport seems to predominate. The divalent Co ion diffuses faster than the trivalent Cr ion in the surface layer. The apparent activation energies for the localized surface diffusion of 57 Co and 59 Cr are 59±12 and 110±12 kj/mol, respectively. 相似文献
23.
Comparative data on the molecular weight distribution of polymers obtained by polymerization of ethylene, propylene and 1-hexene, and copolymerization of ethylene with α-olefins over the titanium-magnesium catalysts (TMC) in the absence and presence of hydrogen are presented. In contrast to the ethylene polymerization, in the cases of propylene and 1-hexene polymerization and copolymerization of ethylene with α-olefins, the hydrogen addition is characterized by noticeable narrowing of the molecular weight distribution (MWD) due to lower contribution of the MWD component with high molecular weight. This result is an evidence of the increased reactivity of TMC active sites producing high molecular weight poly-α-olefins and copolymers of ethylene with α-olefins in the chain transfer reaction with hydrogen. It is suggested that the increased reactivity of these sites in the transfer reaction with hydrogen appears after the 2,1-addition of α-olefin to the growing polymer chain. 相似文献
24.
Vladimir Brailovski Patrick Terriault Sergei Prokoshkin 《Journal of Materials Engineering and Performance》2002,11(6):614-621
Shape memory alloys (SMA) suffer from the same impairing mechanisms experienced during cycling loading by classic alloys.
Moreover, SMA fatigue behavior is greatly influenced by thermomechanical cycling through the zone of thermoelastic phase transformation,
which is the basis of shape memory and superelasticity effects. Since the fatigue resistance of any material can be improved
by an appropriate thermomechanical treatment, in the present work combined differential scanning calorimetry and microhardness
testing were used to determine an optimum annealing temperature for the cold-worked Ni-50.1%Ti alloy. The optimization is
based on the assumption that latent heat of transformation is proportional to the mechanical work generated by SMA upon heating,
while material hardness is related to the yield stress of the material. It is supposed that an optimum trade-off in these
two properties guarantees the best dimensional and functional stability of SMA devices. The level and stability of the mechanical
work generated by the material during low-cycle fatigue testing are considered criteria for the material performance and thus
of the validity of the proposed optimization procedure. 相似文献
25.
Platforms with automatic memory management, such as the JVM, are usually considered free of memory leaks. However, memory leaks can happen in such environments, as the garbage collector cannot free objects, which are not used by the application anymore, but are still referenced. Such unused objects can eventually fill up the heap and crash the application. Although this problem has been studied extensively, nevertheless, there are still many rooms for improvement in this area. This paper describes the statistical approach for memory leak detection, as an alternative, along with a commercial tool, Plumbr, which is based on the method. The tool is later analyzed with three case studies of real applications and in the process also analyzes strengths and weaknesses of the statistical approach for memory leak detection. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
26.
Dongwoon Jeon Doo-Hyun Kim Young-Guk Ha Vladimir Tyan 《Soft Computing - A Fusion of Foundations, Methodologies and Applications》2016,20(5):1713-1720
In this paper, we present an algorithm for providing visually-guided unmanned aerial vehicle (UAV) control using visual information that is processed on a mobile graphic processing unit (GPU). Most real-time machine vision applications for UAVs exploit low-resolution images because the shortage of computational resources comes from size, weight and power issue. This leads to the limitation that the data are insufficient to provide the UAV with intelligent behavior. However, GPUs have emerged as inexpensive parallel processors that are capable of providing high computational power in mobile environments. We present an approach for detecting and tracking lines that use a mobile GPU. Hough transform and clustering techniques were used for robust and fast tracking. We achieved accurate line detection and faster tracking performance using the mobile GPU as compared with an x86 i5 CPU. Moreover, the average results showed that the GPU provided approximately five times speedup as compared to an ARM quad-core Cortex-A15. We conducted a detailed analysis of the performance of proposed tracking and detection algorithm and obtained meaningful results that could be utilized in real flight. 相似文献
27.
Vladimir Alexiev Antoine Isaac Jutta Lindenthal 《International Journal on Digital Libraries》2016,17(1):39-48
Knowledge organization systems (KOS) can use different types of hierarchical relations: broader generic (BTG), broader partitive (BTP), and broader instantial (BTI). The latest ISO standard on thesauri (ISO 25964) has formalized these relations in a corresponding OWL ontology (De Smedt et al., ISO 25964 part 1: thesauri for information retrieval: RDF/OWL vocabulary, extension of SKOS and SKOS-XL. http://purl.org/iso25964/skos-thes, 2013) and expressed them as properties: broaderGeneric, broaderPartitive, and broaderInstantial, respectively. These relations are used in actual thesaurus data. The compositionality of these types of hierarchical relations has not been investigated systematically yet. They all contribute to the general broader (BT) thesaurus relation and its transitive generalization broader transitive defined in the SKOS model for representing KOS. But specialized relationship types cannot be arbitrarily combined to produce new statements that have the same semantic precision, leading to cases where inference of broader transitive relationships may be misleading. We define Extended properties (BTGE, BTPE, BTIE) and analyze which compositions of the original “one-step” properties and the Extended properties are appropriate. This enables providing the new properties with valuable semantics usable, e.g., for fine-grained information retrieval purposes. In addition, we relax some of the constraints assigned to the ISO properties, namely the fact that hierarchical relationships apply to SKOS concepts only. This allows us to apply them to the Getty Art and Architecture Thesaurus (AAT), where they are also used for non-concepts (facets, hierarchy names, guide terms). In this paper, we present extensive examples derived from the recent publication of AAT as linked open data. 相似文献
28.
Natalya N. Barabanova Victor V. Belyaev Dmitriy L. Bogdanov Vladimir G. Chigrinov Artem K. Dadivanyan Artem P. Nazarov Olga V. Noah 《Journal of the Society for Information Display》2015,23(10):486-490
A method of controlling anchoring energy of surface interaction of liquid crystal photoaligning substances is considered to enhance the liquid crystal display performances. An important parameter of the dye's molecular structure that determines the ratio of polar and azimuthal anchoring energy is the ability to form dimers. The values of dimerization thermodynamic potentials have been found. The probability of the formation of dye molecules dimers is evaluated. The bonds conjugation transfer via intermolecular hydrogen bond is revealed, and anisotropy of polarizability of the hydrogen bond is evaluated. The effect of dimerization on polar and azimuthal anchoring energy of liquid crystal — azo dye system — is shown. 相似文献
29.
Dongyu Zhao Fan Fan Vladimir G. Chigrinov Hoi Sing Kwok Ben Zhong Tang 《Journal of the Society for Information Display》2015,23(5):218-222
Nowadays, liquid crystal displays (LCDs) with light‐emission are considered as energy‐efficient devices and are promising alternatives to conventional LCDs. To realize such possibility, strong fluorescent materials with a dichroic properties are required. Aggregate‐induced emission (AIE) is an unusual photophysical phenomenon shown by some luminogenic materials that will be highly emissive in their aggregate state. In this work, we studied the AIE effect of a luminescent liquid crystalline molecule TPE‐PPE in our LC system as a luminophore dopant. The result showed the excellent AIE effect that higher concentration of luminogen in the nematic LC host induced stronger luminescent intensity. Through exposure of a photoisomeriable alignment material sulfonic‐dye‐1, the photopatterning of a light‐emitting LC device was achieved with the use of the TPE‐PPE/nematic LC mixture. 相似文献
30.
Abhishek K. Srivastava Vladimir G. Chigrinov Hoi Sing Kwok 《Journal of the Society for Information Display》2015,23(6):253-272
The ferroelectric liquid crystals, because of their fast electro‐optical response, are one of the most important classes of liquid crystals. Here, in this review, we have summarized the different electro‐optical modes for ferroelectric liquid crystals. Clark–Lagerwall effect (surface stabilized ferroelectric liquid crystal), deformed helix ferroelectric (DHF) effect, electrically suppressed helix (ESH) mode, DHF orientational Kerr effect, and ESH diffraction modes have been discussed. All of the crucial features, that is, optics, electro‐optics, dynamics, and their dependence on material parameters, operational regime, and applications, have been reviewed. 相似文献