Homomorphic vector quantisation

A new approach is proposed for vector quantisation in linear predictive speech coding. The problem is formulated as speech model recognition by minimising the Euclidean distance measure of real cepstra of models with unit power transmission. The procedure is robust with respect to quantisation of both the cepstral coefficients and operational results.     

Wear resistance of polymer-impregnated mortars and concrete

The wear resistance of mortar and concrete samples untreated and impregnated with solutions of epoxide resin was tested. The compressive strength has a decisive influence on the abrasion of untreated mortar and concrete samples. The idealized diameter area of the maximal grain of the gravel in the sample has less influence on it. The wear resistance of impregnated samples with low compressive strength markedly increases. The hardener used influences the polymerization rate of the activated resin in the structure of samples, with time, and their abrasion is influenced also in this way.     

Surface and morphological investigation of the electrode/electrolyte properties in an all-solid-state battery using a Li<Subscript>2</Subscript>S-P<Subscript>2</Subscript>S<Subscript>5</Subscript> solid electrolyte

All-solid-state lithium-ion batteries represent a promising battery technology thanks to the replacement of the volatile and flammable state-of-the-art liquid electrolyte by a solid electrolyte. Despite the recent progress in the synthesis of sulfide based solid electrolyte with high ionic conductivity, little is known about the interface reactivity of the solid electrolyte with electrode materials. In this study, we synthesized and characterized an amorphous solid electrolyte with the nominal composition (Li₂S)₃(P₂S₅). We assessed the feasibility of using this electrolyte at the laboratory scale, and we discuss the potential challenges that govern its electrochemical performance. Galvanostatic cycling and rate performance measurements were conducted using lithium titanium oxide (Li₄Ti₅O₁₂) as the negative electrode material. The electrochemical measurements were performed using two different counter electrodes, namely Li metal and an InLi_x alloy. The alloy counter electrode suppressed the formation of lithium dendrites, resulting in increased cycling stability and cell safety. Post mortem X-ray photoemission spectroscopy measurements reveal the reactivity of the solid electrolyte Li₃PS₄ with the Li₄Ti₅O₁₂, lithium metal, and InLi_x alloy.     

Boosting the electrochemical performance of Li-garnet based all-solid-state batteries with Li<Subscript>4</Subscript>Ti<Subscript>5</Subscript>O<Subscript>12</Subscript> electrode: Routes to cheap and large scale ceramic processing

All-solid-state batteries based on fast Li⁺ conducting solid electrolytes such as Li₇La₃Zr₂O₁₂ (LLZO) give perspective on safe, non-inflammable, and temperature tolerant energy storage. Despite the promise, ceramic processing of whole battery assemblies reaching close to theoretical capacities and finding optimal strategies to process large-scale and low cost battery cells remains a challenge. Here, we tackle these issues and report on a solid-state battery cell composed of Li₄Ti₅O₁₂ / c-Li_6.25Al_0.25La₃Zr₂O₁₂ / metallic Li delivering capacities around 70–75 Ah/kg with reversible cycling at a rate of 8 A/kg (for 2.5–1.0 V, 95 °C). A key aspect towards the increase in capacity and Li⁺ transfer at the solid electrolyte-electrode interface is found to be the intimate embedding of grains and their connectivity, which can be implemented by the isostatic pressing of cells during their preparation. We suggest that simple adaption of ceramic processing, such as the applied pressure during processing, strongly alters the electrochemical performance by assuring good grain contacts at the electrolyte-electrode interface. Among the garnet-type all-solid-state ceramic battery assemblies in the field, considerably improved capacities and cycling properties are demonstrated for Li₄Ti₅O₁₂ / c-Li_6.25Al_0.25La₃Zr₂O₁₂ / metallic Li pressed cells, giving new perspectives on cheap ceramic processing and up-scalable garnet-based all-solid-state batteries.     

Structural Basis for Antimicrobial Activity of Lasiocepsin

Lasiocepsin is a unique 27‐residue antimicrobial peptide, isolated from Lasioglossum laticeps (wild bee) venom, with substantial antibacterial and antifungal activity. It adopts a welldefined structure consisting of two α‐helices linked by a structured loop. Its basic residues form two distinct positively charged regions on the surface whereas aliphatic side chains contribute to solvent‐accessible hydrophobic areas, thus emphasising the amphipathic character of the molecule. Lasiocepsin structurally belongs to the ShK family and shows a strong preference for anionic phospholipids; this is further augmented by increasing concentrations of cardiolipin, such as those found at the poles of bacterial cells. The membrane‐permeabilising activity of the peptide is not limited to outer membranes of Gram‐negative bacteria. The peptide interacts with phospholipids initially through its N terminus, and its degree of penetration is strongly dependent on the presence of cardiolipin.     

Study of rotational temperature of oxygen molecules in H and T forms of DC glow discharge sustained in pure oxygen

The active DC glow discharge sustained in pure oxygen has been studied in a Silica discharge tube by means of optical emission spectroscopy and double-probe diagnostics for pressures 600, 750 and 1000 Pa and for discharge currents up to 40 mA. Two different forms of positive column of the discharge (high-gradient H form and low-gradient T form) were observed. Our investigation was focused on the variations of the rotational temperature T_rot determined from emission spectra of molecular oxygen (atmospheric A-band at 760 nm) in the dependence on the discharge current and on the pressure with respect to the existence of the two forms of the discharge. An increase of the rotational temperature with increasing discharge current has been observed. Moreover, higher values of T_rot were found in the H form compared with the T form.     

Sensitivity analysis of steel plane frames with initial imperfections

The article presents the sensitivity and statistical analyses of the load-carrying capacity of a steel portal frame. It elaborates a typical stability problem of a system comprising two single-storey columns loaded in compression. The elements of this system mutually influence each other, and this fact, in conjunction with the random imperfections, influences the load-carrying capacity variance. This mutual interaction is analysed using the Sobol’ sensitivity analysis. The Sobol’ sensitivity analysis is applied to identify the dominant input random imperfections and their higher order interaction effects on the load-carrying capacity. Majority of imperfections were considered according to the results of experimental research. Realizations of initial imperfections were simulated applying the Latin Hypercube Sampling method. The geometrical nonlinear solution providing numerical result per run was employed. The frame was meshed using beam elements. The columns of the plane frame are considered with two variants of boundary conditions. The dependence between mean and design load-carrying capacities and column non-dimensional slenderness is analysed.     

Oxygen‐Free Highly Conductive Graphene Papers

Graphene papers have a potential to overcome the gap from nanoscale graphene to real macroscale applications of graphene. A unique process for preparation of highly conductive graphene thin paper by means of Ar⁺ ion irradiation of graphene oxide (GO) papers, with carbon/oxygen ratio reduced to 100:1, is presented. The composition of graphene paper in terms of carbon/oxygen ratio and in terms of types of individual oxygen‐containing groups is monitored throughout the process. Angle‐resolved high resolution X‐ray photoelectron spectroscopy helps to investigate the depth profile of carbon and oxygen within reduced GO paper. C/O ratios over 100 on the surface and 40 in bulk material are observed. In order to bring insight to the processes of oxygen removal from GO paper by low energy Ar⁺ ion bombardment, the gases released during the irradiation are analyzed by mass spectroscopy. It is proven that Ar⁺ ion beam can be applied as a technique for fabrication of highly reduced graphene papers with high conductivities. Such highly conductive graphene papers have great potential to be used in application for construction of microelectronic and sensor devices.     

Inline skating, an old sport, newly discovered: harmless or a potential danger with socioeconomic effects?]

Over a period of one year, all accidents associated with in-line skating (ILS) were surveyed. Sport-specific data was recorded with a standardized questionnaire. The study comprised 66 patients with 75 injuries (48 upper limb, 16 skull, eight lower limb, three trunk). We were looking after 42 male and 24 female patients with an average age of 20 years (5-53 years). Twenty-seven patients (40%) had to be treated as inpatients. Overall, the most frequent injury (one third of all injuries) was forearm fracture close to the wrist (21 radius fractures, four radioulnar fractures). It had to be reset in 20 cases. Additional internal fixation was required in 10 cases (Kirschner wire osteosynthesis, intramedullary nailing or plate osteosynthesis). Only five patients could be treated with plaster cast fixation alone. Most patients with injuries in the vicinity of the wrist were not wearing a wrist protector at the time of the accident. The most frequent reasons given for not wearing protectors was forgetfulness or the high price of protectors. However, there were also two distal radius fractures and a disc injury in the wrist in patients who had been wearing wrist protectors. In most cases, ILS accidents lead to appreciable damage requiring a healing period of several weeks to months (average period of loss of work 41 days). The bfu (advisory center for accident prevention) reckons with 60,000 ILS cases annually in Switzerland. These injuries are thus of great socioeconomic importance. In the future, better risk behavior must be achieved by informing the population (wearing protectors, especially for the wrist and head, attendance of training courses).