Monitoring the Ratio of Two Normal Variables Using EWMA Type Control Charts

In many fields, there is the need to monitor quality characteristics defined as the ratio of two random variables. The design and implementation of control charts directly monitoring the ratio stability is required for the continuous surveillance of these quality characteristics. In this paper, we propose two one‐sided exponentially weighted moving average (EWMA) charts with subgroups having sample size n > 1 to monitor the ratio of two normal random variables. The optimal EWMA smoothing constants, control limits, and ARLs have been computed for different values of the in‐control ratio and correlation between the variables and are shown in several figures and tables to discuss the statistical performance of the proposed one‐sided EWMA charts. Both deterministic and random shift sizes have been considered to test the two one‐sided EWMA charts' sensitivity. The obtained results show that the proposed one‐sided EWMA control charts are more sensitive to process shifts than other charts already proposed in the literature. The practical application of the proposed control schemes is discussed with an illustrative example. Copyright © 2015 John Wiley & Sons, Ltd.     

Mechanical property enhancement of aligned multi-walled carbon nanotube sheets and composites through press-drawing process

A solid-state drawing and winding process was done to create thin aligned carbon nanotube (CNT) sheets from CNT arrays. However, waviness and poor packing of CNTs in the sheets are two main weaknesses restricting their reinforcing efficiency in composites. This report proposes a simple press-drawing technique to reduce wavy CNTs and to enhance dense packing of CNTs in the sheets. Non-pressed and pressed CNT/epoxy composites were developed using prepreg processing with a vacuum-assisted system. Effects of pressing on the mechanical properties of the aligned CNT sheets and CNT/epoxy composites were examined. Pressing with distributed loads of 147, 221, and 294 N/m showed a substantial increase in the tensile strength and the elastic modulus of the aligned CNT sheets and their composites. The CNT sheets under a press load of 221 N/m exhibited the best mechanical properties found in this study. With a press load of 221 N/m, the pressed CNT sheet and its composite, respectively, enhanced the tensile strength by 139.1 and 141.9%, and the elastic modulus by 489 and 77.6% when compared with non-pressed ones. The pressed CNT/epoxy composites achieved high tensile strength (526.2 MPa) and elastic modulus (100.2 GPa). Results show that press-drawing is an important step to produce superior CNT sheets for development of high-performance CNT composites.     

Reproducible Enhancement of Fluorescence by Bimetal Mediated Surface Plasmon Coupled Emission for Highly Sensitive Quantitative Diagnosis of Double‐Stranded DNA

Plasmonic enhancement of fluorescence from SYBR Green I conjugated with a double‐stranded DNA (dsDNA) amplicon is demonstrated on polymerase chain reaction (PCR) products. Theoretical computation leads to use of the bimetallic (Au 2 nm–Ag 50 nm) surface plasmons due to larger local fields (higher quality factors) than monometallic (Ag or Au) ones at both dye excitation and emission wavelengths simultaneously, optimizing fluorescence enhancement with surface plasmon coupled emission (SPCE). Two kinds of reverse Kretschmann configurations are used, which favor, in signal‐to‐noise ratio, a fluorescence assay that uses optically dense buffer such as blood plasma. The fluorescence enhancement (12.9 fold at maximum) with remarkably high reproducibility (coefficient of variation (CV) < 1%) is experimentally demonstrated. This facilitates credible quantitation of enhanced fluorescence, however unlikely to obtain by localized surface plasmons. The plasmon‐induced optical gain of 46 dB due to SPCE‐active dye molecules is also estimated. The fluorescence enhancement technologies with PCR enables LOD of the dsDNA template concentration of ≈400 fg µL^?1 (CV < 1%), the lowest ever reported in DNA fluorescence assay to date. SPCE also reduces photobleaching significantly. These technologies can be extended for a highly reproducible and sufficiently sensitive fluorescence assay with small volumes of analytes in multiplexed diagnostics.     

Phonon Scattering in Thin Silica Films Below 1 K

A method is described for studying thermal phonon scattering in thin films on dielectric substrates below a few Kelvin. It is used to study silica films on silicon substrates. Using Monte Carlo simulations with no free parameters, we find that thermally grown silica films 0.1 to 1.0 m thick scatter the phonons as strongly as bulk silica, and hence, have the same thermal conductivity as bulk silica, while a 0.1 m thick e-beam evaporated silica film has a thermal conductivity five times smaller than bulk silica, indicative of additional defects.