首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   165篇
  免费   9篇
电工技术   4篇
综合类   1篇
化学工业   63篇
金属工艺   4篇
机械仪表   1篇
建筑科学   2篇
能源动力   3篇
轻工业   3篇
水利工程   2篇
石油天然气   2篇
无线电   16篇
一般工业技术   51篇
冶金工业   5篇
自动化技术   17篇
  2023年   2篇
  2022年   19篇
  2021年   13篇
  2020年   12篇
  2019年   7篇
  2018年   1篇
  2017年   7篇
  2016年   7篇
  2015年   4篇
  2014年   7篇
  2013年   8篇
  2012年   13篇
  2011年   23篇
  2010年   5篇
  2009年   5篇
  2008年   4篇
  2007年   8篇
  2006年   2篇
  2005年   2篇
  2004年   5篇
  2003年   2篇
  2002年   3篇
  2001年   2篇
  2000年   2篇
  1999年   1篇
  1998年   1篇
  1997年   1篇
  1996年   2篇
  1995年   2篇
  1994年   2篇
  1992年   1篇
  1987年   1篇
排序方式: 共有174条查询结果,搜索用时 15 毫秒
41.
Hijacked journals are cloned websites that resemble the homepages of legitimate journals, whose aim is to collect processing and publication fees from unwary authors. There is a growing recognition that the recent proliferation of these scam sites poses a threat to the integrity of the scientific process. This study presents an approach intended to prevent the indexing of papers published by hijacked journals in scientific databases by using classification algorithms. We will provide an overview of the problem, define key features of hijacked journals, and present a decision tree that can be used to detect hijacked publications.  相似文献   
42.
Silicene, a Si analogue of graphene, is suggested to become a versatile material for nanoelectronics. Being coupled with magnetism, it is predicted to be particularly suitable for spintronic applications. However, experimental realization of free‐standing silicene and its magnetic derivatives is lacking. Fortunately, magnetism can be induced into silicene layers, in particular, by intercalation. Here, a successful synthesis of multilayer silicene intercalated by inherently magnetic Eu ions – a compound expected to exhibit both massless Dirac‐cone states, as its Ca analogue, and a nontrivial magnetic structure – is reported. This new polymorph with EuSi2 stoichiometry is epitaxially stabilized by continual replication of silicene layers employing Sr‐intercalated multilayer silicene as a template. The atomic structure of the new compound and its sharp interface with the template are confirmed using electron diffraction, X‐ray diffraction, and electron microscopy techniques. Below 80 K, the material demonstrates anisotropic antiferromagnetism coexisting with weak ferromagnetism. The magnetic state is accompanied by an anomalous behavior of magnetoresistivity.  相似文献   
43.
44.
New configuration of cylindrical reentrant cavity with modified shape of the metal post is considered. The eigen wavelengths of two lowest modes obtained numerically are compared with analogous parameters of conventional reentrant cavity. Approximate analytical expressions for calculation of resonant wavelengths are derived with the help of statistical package TableCurve3D. © 2012 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2013.  相似文献   
45.
Critical thicknesses of two-dimensional to three-dimensional growth in GexSi1−x layers were measured as a function of composition for different growth temperatures. In addition to the (2 × 1) superstructure for a Ge film grown on Si(100), the GexSi1−x layers are characterized by the formation of (2 × n) reconstruction. We measured n for all layers of Ge/GexSi1−x/Ge heterosystem using our software with respect to the video recording of reflection high-energy electron diffraction (RHEED) pattern during growth. The n reaches a minimum value of about 8 for clear Ge layer, whereas for GexSi1−x films, n is increased from 8 to 14. The presence of a thin strained film of the GexSi1−x caused not only the changes in critical thicknesses of the transitions, but also affected the properties of the germanium nanocluster array for the top Ge layer. Based on the RHEED data, the hut-like island form, which has not been previously observed by us between the hut and dome islands, has been detected. Data on the growth of Ge/GexSi1−x/Ge heterostructures with the uniform array of islands in the second layer of the Ge film have been received.  相似文献   
46.
47.
The selective sorption and multiple concentration of copper in the form of an ultradisperse precipitate from a diluted Cu2+–Zn2+-solution has been investigated. The selective sorption is accomplished by means of weakly basic anion exchangers in their free base forms. Regeneration of the sorbent and conversion of Cu2+ to Cu0 is carried out by means of a chemical reduction in the resin phase. Thus the resins can be reused for sorption of further copper ions. The process has been investigated in both, batch and packed bed experiments. After multiple saturation–reduction cycles an accumulation of metallic copper on the surface and in the pores of the sorbent is observed. The presence of finely dispersed metallic copper leads to the additional sorption of the Cu2+ ions due to a synproportional reduction–oxidation reaction. The total uptake of copper after several cycles amounts to more than 300 % of the anion exchange capacity.  相似文献   
48.
The enzyme that catalyzes water oxidation in oxygenic photosynthesis contains an inorganic cluster (Mn4CaO5) that is universally conserved in all photosystem II (PSII) protein complexes. Its hypothesized precursor is an anoxygenic photobacterium containing a type 2 reaction center as photo‐oxidant (bRC2, iron–quinone type). Here we provide the first experimental evidence that a native bRC2 complex can catalyze the photo‐oxidation of Mn2+ to Mn3+, but only in the presence of bicarbonate concentrations that allows the formation of (bRC2)Mn2+(bicarbonate)1–2 complexes. Parallel‐mode EPR spectroscopy was used to characterize the photoproduct, (bRC2)Mn3+(CO32?), based on the g tensor and 55Mn hyperfine splitting. (Bi)carbonate coordination extends the lifetime of the Mn3+ photoproduct by slowing charge recombination. Prior electrochemical measurements show that carbonate complexation thermodynamically stabilizes the Mn3+ product by 0.9–1 V relative to water ligands. A model for the origin of the water oxidation catalyst is presented that proposes chemically feasible steps in the evolution of oxygenic PSIIs, and is supported by literature results on the photoassembly of contemporary PSIIs.  相似文献   
49.
We present several possible microstructure development scenarios in Ti3SiC2-Cu composites during mechanical milling and Spark Plasma Sintering (SPS). We have studied the effect of in situ consolidation during milling of Ti3SiC2 and Cu powders and melting of the Cu matrix during the SPS on the hardness and electrical conductivity of the sintered materials. Under low-energy milling, (3–5) vol.%Ti3SiC2-Cu composite particles of platelet morphology formed, which could be easily SPS-ed to 92–95% relative density. Under high-energy milling, millimeter-scale (3–5) vol.%Ti3SiC2-Cu granules formed as a result of in situ consolidation and presented a challenge to be sintered into a bulk fully dense sample; the corresponding SPS-ed compacts demonstrated a finer-grained Cu matrix and more significant levels of hardening compared to composites of the same composition processed by low-energy milling. The 3 vol.% Ti3SiC2-Cu in situ consolidated and Spark Plasma Sintered granules showed an extremely high hardness of 227 HV. High electrical conductivity of the Ti3SiC2-Cu composites sintered from the granules was an indication of efficient sintering of the granules to each other. Partial melting of the Cu matrix, if induced during the SPS, compromised the phase stability and uniformity of the microstructure of the Ti3SiC2-Cu composites and thus it is not to be suggested as a pathway to enhanced densification in this system.  相似文献   
50.
Despite a significant number of investigations in the field of phosphazene chemistry, the formation mechanism of this class of cyclic compounds is still poorly studied. At the same time, a thorough understanding of this process is necessary, both for the direct production of phosphazene rings of a given size and for the controlled cyclization reaction when it is secondary and undesirable. We synthesized a series of short linear phosphazene oligomers with the general formula Cl[PCl2=N]n–PCl3+PCl6 and studied their tendency to form cyclic structures under the influence of elevated temperatures or in the presence of nitrogen-containing agents, such as hexamethyldisilazane (HMDS) or ammonium chloride. It was established that linear oligophosphazenes are inert when heated in the absence of the mentioned cyclization agents, and the formation of cyclic products occurs only when these agents are involved in the process. The ability to obtain the desired size phosphazene cycle from corresponding linear chains is shown for the first time. Known obstacles, such as side interaction with the PCl6 counterion and a tendency of longer chains to undergo crosslinking elongation instead of cyclization are still relevant, and ways to overcome them are being discussed.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号