Spatial and temporal trends of petroleum hydrocarbons in wild mussels from the Galician coast (NW Spain) affected by the Prestige oil spill

Polycyclic aromatic hydrocarbons (PAHs) were determined in tissues of wild mussels (Mytilus galloprovincialis) from the Galicia coast (NW Spain) in order to assess the extent of the environmental impact caused by the Prestige oil spill (November 13, 2002). Three sampling campaigns were carried out in February, June and November 2003 at 24 stations along the Galicia coast, from La Guardia (Pontevedra) to Ribadeo (Lugo). The spatial distribution of PAHs found in the first sampling period, clearly revealed the central area (Costa da Morte) as the most affected by the oil spill. In these stations, concentrations up to 7780 microg/kg dw of the sum of 13 parent PAHs were found 2-3 months after the spill. Molecular parameters within the aliphatic and aromatic fractions confirmed the presence of the Prestige oil in these samples. The levels markedly decreased at most of the stations in the second sampling and recovered to levels found before the spill in November 2003, 1 year after the accident (29-279 microg/kg dw, av. 133+/-83 microg/kg dw). However, a certain increase was observed in some sites which could be related to the remobilization of oil residues from still unclean intertidal spots or sediments due to the winter marine weather conditions.     

Betons a hautes performances,a granulats artificiels actifs

High strength concretes, in particular at early ages (more than 40 MPa at 3 days and up to 80 MPa at 7 days), are obtained by replacement of certain granular size ranges of sand or gravel by cement-active artificial aggregates in a given concrete composition elaborated with a local supply of aggregates and cement. The strengthening of the paste-aggregate bond by chemical reactions between the artificial aggregates and the cement also involves an improvement of other concrete performances and not only of mechanical strengths. The cracking ability is decreased, the wear strength is higher, and water permeability is low or even nil for certain compositions. The laboratory results are confirmed by tests on the site and show the possibility of achieving high strength concretes without any particular selection of cement and natural aggregates.     

Concurrent denitrification and oxygen uptake in microbial films

Mixed microbial films were grown on the inner walls of a tubular reactor with recirculation of the reactor contents and continuous flow-through of nutrient solution. The loss of total oxidized nitrogen was correlated to the film population, the nitrite concentration and the dissolved oxygen concentration in the reactor. When film population was greater than 0.5 × 10⁹ cells cm⁻², reactor dissolved oxygen concentration greater than 1 mg l⁻¹ had little effect on the nitrate loss. Nitrate loss declined for film populations greater than 2 × 10⁹ cells cm⁻². Models based on Monod and zero-order microbial kinetics were calibrated using these data and a nonlinear least squares method. There was little difference in the residual errors with these methods.     

Tunnelling projects in Southern Africa

Until some thirty years ago tunnelling in southern Africa for civil engineering purposes had been on a relatively small scale and of a sporadic nature. The first major tunnel to be built in the region was the 82 km long Orange-Fish Tunnel. Since 1970 more than 175 tunnels with an aggregate length of just over 400 km have been built. Much of the first phase of the Lesotho Highlands Water Project, which will have more than 100 km of tunnels, is about to be completed. The last thirty years represent the busiest period of tunnelling by civil engineers that southern Africa has ever known. The paper starts by summarising the early history of tunnelling in the region, and goes onto describe recent and current tunnelling projects. It also gives an indication of the possible demand for tunnels in the future.     

Essais d'aerateurs: Enseignements tires de 500 essais en eau claire effectues dans 200 stations d'epuration differentes—II ResultatsTests on aerators: Conclusions drawn from 500 clean water tests conducted in 200 different sewage treatment plants—II Data interpretation

The large number of aerator tests conducted in the field by the CEMAGREF teams has allowed developing a critical review of tests results by means of statistical analysis. Measurement quality is estimated from the variation of the transfer coefficient values from one sampling point to another. Individual transfer coefficient values $\text{(}\text{K}{}_{\mathrm{L}}\text{a)i}$ are compared with the average value of the test $\text{(}\text{K}{}_{\mathrm{L}}\text{a). (K}{}_{\mathrm{L}}\text{a)i/}\text{K}{}_{\mathrm{L}}\text{a}$ ratios correlating with one year's data are gathered in histogramms (Fig. 1).A χ² test is used for evaluating the fit of a Normal distribution on each histogram (Tables 1 and 2 results for two kinds of surface aerators). When the Normality is not rejected, the variances between distributions are compared by means of a Fisher test.$\text{(K}{}_{\mathrm{L}}\text{a)i/}\text{K}{}_{\mathrm{L}}\text{a}$ variations in a same run are independent of transfer coefficient when the K_La ranges 1–10 h^?1 and applied specific power ranges 15–70 W m^?3. Those variations allow evaluating the technique of measuring, the reliability of oxygen probes and the operator's experience (Table 3).In a well mixed tank and when the recommended procedure is correctly implemented the relative error in measuring the specific oxygen input (kg O₂ kWh^?1) is 5%. In less favorable cases it reaches 10%.Tables 4 and 5 show the reproductibility of repetitive run results in the same plant and of tests performed with the same aerator in different plants.The histograms of the performances of the main types of mechanical surface aerators (high speed vertical shaft turbine, slow speed vertical shaft turbine, horizontal shaft aerator) are presented (Figs 2, 4, 5). Relations between oxygenation capacity and specific power consumption are plotted in Figs 3 and 6. As to other aeration systems, fewer data are available. Table 6 summarizes the usual range of performances.In 1974, after a series of measurements performed on 72 different plants, CEMAGREF stated that the oxygenation capacities claimed by manufacturers were, on the average, 40% higher than actual results. Now, the performances predicted by manufacturers in France are generally very close to the measured values. A difference higher than 10% between predicted values and measured ones now occurs as an exception.     

Reviews

DROUGHT AND FAMINE IN ETHIOPIA Editor: Abdul Mejid Hussein. African Environment Special Report No. 2, The International African Institute, London, 1976,121 pp. £1.50.

HEDGING (A Practical conservation handbook) Alan Brooks, The British Trust for Conservation Volunteers, The Zoological Gardens, Regents Park, London, 1975. 117 pp. £2.10 inc. postage.

THREE JOURNALS Habitat: Published by : The Council for Nature, The Zoological Gardens, Regents Park, NW1 4RY. At £2.50, or £5.00 per annum.

Recreation News: Published by: The Countryside Commission , John Dower House, Crescent Place, Cheltenham, Glos., GL50 3RA.

The International Journal of Environmental Studies: Published by : Gordon Breach Science Publishers Ltd., 42 William IV Street. London, W.C.2. £17.50 for individuals, £35.00 for Libraries. Habitat

A HISTORY OF LANCASHIRE J.J. Bagley, Phillimore & Co. Ltd., London & Chichester 1976. 128 pp. £4.95.     

Assessment of nitrification in groundwater filters for drinking water production by qPCR and activity measurement

In groundwater treatment for drinking water production, the causes of nitrification problems and the effectiveness of process optimization in rapid sand filters are often not clear. To assess both issues, the performance of a full-scale groundwater filter with nitrification problems and another filter with complete nitrification and pretreatment by subsurface aeration was monitored over nine months. Quantitative real-time polymerase chain reaction (qPCR) targeting the amoA gene of bacteria and archaea and activity measurements of ammonia oxidation were used to regularly evaluate water and filter sand samples. Results demonstrated that subsurface aeration stimulated the growth of ammonia-oxidizing prokaryotes (AOP) in the aquifer. Cell balances, using qPCR counts of AOP for each filter, showed that the inoculated AOP numbers from the aquifer were marginal compared with AOP numbers detected in the filter. Excessive washout of AOP was not observed and did not cause the nitrification problems. Ammonia-oxidizing archaea grew in both filters, but only in low numbers compared to bacteria. The cell-specific nitrification rate in the sand and backwash water samples was high for the subsurface aerated filter, but systematically much lower for the filter with nitrification problems. From this, we conclude that incomplete nitrification was caused by nutrient limitation.     

Analysis and jointing of polygonal road slabs

Conclusions 1. For anlaysis of circular (polygona) slabs which can be included in the category of absolutely rigid slabs, a practical approximate method of analysis has been developed and experimentally verified which permits determining the bending moments under centrally and eccentrically applied loads acting over a small circular area, as well as at any other points in the slab beyond the limits of the loaded area.2. Monolithic bonding of hexagonal road slabs up to 3–4 m² in area designed for the N-30 load results in increased design bending moments and, consequently, in thicker pavements. For these slabs it is expedient to use nonrigid joints, which do not transmit bending or torsional moments; however, these slabs must be placed on stabilized beds and their joints must be filled with waterproofing mastic.Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 5, pp. 19–22, September–October, 1974.     

Toxicity, accumulation and elimination studies of α-hexachlorocyclohexane (α-HCH) with freshwater organisms of different trophic levels

A short- and long-term toxicity study with α-hexachlorocyclohexane (α-HCH) was carried out with freshwater organisms of different trophic levels (algae, crustaceae and fishes). In this study mortality, immobilization, growth, reproduction, histopathologic changes and enzyme activities were chosen as criteria.Furthermore accumulation and elimination processes were investigated in separate organisms as well as the uptake of α-HCH by one organism and through a food-chain.Finally a tentative method for deriving an “ecological limit” for χ-HCH in surface water is described.