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排序方式: 共有701条查询结果,搜索用时 281 毫秒
611.
Jian Quan Qi Hu Yong Tian Long Tu Li Helen Lai Wah Chan 《Nanoscale research letters》2007,2(2):107-111
Here we report a very simple method to convert conventional CuO powders to nanoparticle interlinked microsphere cages by solution
method. CuO is dissolved into aqueous ammonia, and the solution is diluted by alcohol and dip coating onto a glass substrate.
Drying at 80 °C, the nanostructures with bunchy nanoparticles of Cu(OH)2 can be formed. After the substrate immerges into the solution and we vaporize the solution, hollow microspheres can be formed
onto the substrate. There are three phases in the as-prepared samples, monoclinic tenorite CuO, orthorhombic Cu(OH)2, and monoclinic carbonatodiamminecopper(II) (Cu(NH3)2CO3). After annealing at 150 °C, the products convert to CuO completely. At annealing temperature above 350 °C, the hollow microspheres
became nanoparticle interlinked cages. 相似文献
612.
Copolymers of acrylonitrile with furan, 2-methylfuran and with 2,5-dimethyl furan have been prepared by free radical copolymerizations, and their 13C spectra examined for evidence of the three types of structure that formed, according to previous studies. We have characterized the Diels-Alder adducts of acrylonitrile with furan and with 2-methylfuran, and have found that they may also copolymerize with acrylonitrile by addition at their double bonds. The enchained adducts were most readily recognized in the 1H spectrum by shifts at 4.8 and 4.6 ppm respectively from protons at the oxygen bridgehead. The 13C spectra of these various polymers have been assigned with the aid of model compounds. Below δ=60 ppm the nitrile shift was dispersed over a larger range of shifts than is found in PAN itself, and was joined by the shifts of unsaturated carbon atoms and of carbon atoms linked to the oxygen atoms within these structures. Above 60 ppm the shifts of carbons in acrylonitrile units were found to be perturbed systematically from their normal places by the presence of neighbouring structures formed from the different furan-containing molecules. In both the 1H and 13C spectra shifts characteristic of the end groups from the AIBN initiator were noted. Fine structure in the spectra was attributed to monomer sequence effects and to the tactic structure of the polymer. Chiral centres appeared to be created from the furan rings at random, at least when protonated carbons were the site of initial attachment, but the mode of addition to the ring—whether cis, trans or both, was not certain. Assignments were made of bands in the i.r. spectra to modes of vibration of the units formed from the furan monomers. 相似文献
613.
614.
VW Keng KE Fujimori Z Myint N Tamamaki Y Nojyo T Noguchi 《Canadian Metallurgical Quarterly》1998,426(2):183-186
Photographs frequently are used to document change in the management of hypertrophic scars. The purpose of this study was to design a scale for the analysis of photographs of hypertrophic scars and to test its reliability. The subjects were four occupational and physical therapists, (two novices and two experts), in scar management. Existing scales were modified to produce a new scale. The subjects twice rated four slides from each of ten patients' scars, in random order. They used a Latin Square design. Interrater and test-retest reliabilities were calculated using a weighted kappa statistic. The newly developed scale demonstrated interrater reliability, which ranged between 0.66 and 0.90 for all items. The test-retest reliability ranged between 0.73 and 0.89 for all items. The new scale had substantial reliability (using a single rater) and was at least as reliable when used by novice therapists. This indicated that training had no effect. 相似文献
615.
We propose a novel global minimization method, called NOVEL (Nonlinear Optimization via External Lead), and demonstrate its superior performance on neural network learning problems. The goal is improved learning of application problems that achieves either smaller networks or less error prone networks of the same size. This training method combines global and local searches to find a good local minimum. In benchmark comparisons against the best global optimization algorithms, it demonstrates superior performance improvement 相似文献
616.
Ab initio calculations at the QCISD(T)/6–311G** level have been carried out to study the addition of the methyl radical to a series of substituted alkenes, and the results analyzed with the aid of the curve-crossing model. It is found that (a) reaction exothermicity is the main factor that dominates reactivity, (b) polar contributions to the transition states are generally small and of minor energetic consequences, and (c) the general observation that π-electron-accepting substituents in the alkene enhance reactivity is a secondary correlation that is a consequence of the effect of these substituents on reaction exothermicity. There is no evidence for the prevalent view that the methyl radical is generally nucleophilic towards alkenes. 相似文献
617.
An efficient and practical source encoding algorithm for compressing binary facsimile data is presented. The vertical correlation is taken into account by forming vectors and the horizontal correlation is considered by the run-length coding of these vectors. New proposals for an end-of-line codeword and error correction are described. 相似文献
618.
Thein Wah 《International Journal of Mechanical Sciences》1982,24(2):89-93
A general procedure for the analysis of elastic plates under partial loading is described. The method applies to any elastic plate with rectilinear boundaries. Loads distributed over a circular region and a rectangular region are investigated. 相似文献
619.
Sentiment classification is a useful tool to classify reviews about sentiments and attitudes towards a product or service. Existing studies heavily rely on sentiment classification methods that require fully annotated inputs. However, there is limited labelled text available, making the acquirement process of the fully annotated input costly and labour-intensive. Lately, semi-supervised methods emerge as they require only partially labelled input but perform comparably to supervised methods. Nevertheless, some works reported that the performance of the semi-supervised model degraded after adding unlabelled instances into training. Literature also shows that not all unlabelled instances are equally useful; thus identifying the informative unlabelled instances is beneficial in training a semi-supervised model. To achieve this, an informative score is proposed and incorporated into semi-supervised sentiment classification. The evaluation is performed on a semi-supervised method without an informative score and with an informative score. By using the informative score in the instance selection strategy to identify informative unlabelled instances, semi-supervised models perform better compared to models that do not incorporate informative scores into their training. Although the performance of semi-supervised models incorporated with an informative score is not able to surpass the supervised models, the results are still found promising as the differences in performance are subtle with a small difference of 2% to 5%, but the number of labelled instances used is greatly reduced from 100% to 40%. The best finding of the proposed instance selection strategy is achieved when incorporating an informative score with a baseline confidence score at a 0.5:0.5 ratio using only 40% labelled data. 相似文献
620.
A 2nd order sliding mode algorithm is applied to control the speed of a diesel power generator set. Tuning guidelines are given. The robustness of the controller is investigated and the performance of the 2nd order sliding mode controller is compared with that obtained by a commercial diesel engine controller and a classical proportional‐integral (PI) controller. Robustness to unmodelled dynamics is discussed and implementation results presented. 相似文献