Chemische Methoden der Abwasser-Aufbereitung

Chemical methods of waste-water treatment. Chemical methods of waste management by oxidation can be considered for particular effluents whose constituents are degraded too slowly in conventional sewage treatment plants or which interfere with the biodegradation of other substances. Of these methods, those we have to choose from today are, in order of increasing operating temperature: oxidation with hydrogen peroxide – wet oxidation at high pressure – evaporation and combustion. None of these methods is fundamentally better than the others, i.e. none has a maximum ecological benefit coinciding with a minimum economic impact. Detailed experimental work is required to establish the limits and possibilities in each case and thus to form a basis for useful comparisons. Thermal processes are normally ruled out for low concentrations of degradable constituents in waste water because the specific energy costs per unit volume are too high; this is where hydrogen peroxide may offer advantages, especially when the proportion of these constituents fluctuates. With higher concentrations, wet oxidation can be employed; evaporation and combustion are suitable if there is also a high concentration of inorganic salts.     

Das spezifische Brechungsinkrement eines statistischen Methylmethacrylat/Benzylacrylat/Styrol-Terpolymeren

The specific refractive index increments of a random methylmethacrylate/ benzylacrylate/styrene-terpolymer and of the three corresponding homopolymers was measured in several solvents and at six different wavelengths. With the known terpolymer composition and the specific refractive index increments of the homopolymers the specific refractive index increment of the terpolymer is calculated by means of an equation formerly derived. Calculated and experimental values are compared.     

Combination of computational prescreening and experimental library construction can accelerate enzyme optimization by directed evolution

Chiral compounds can be produced efficiently by using biocatalysts. However, wild-type enzymes often do not meet the requirements of a production process, making optimization by rational design or directed evolution necessary. Here, we studied the lipase-catalyzed hydrolysis of the model substrate 1-(2-naphthyl)ethyl acetate both theoretically and experimentally. We found that a computational equivalent of alanine scanning mutagenesis based on QM/MM methodology can be applied to identify amino acid positions important for the activity of the enzyme. The theoretical results are consistent with concomitant experimental work using complete saturation mutagenesis and high-throughput screening of the target biocatalyst, a lipase from Bacillus subtilis. Both QM/MM-based calculations and molecular biology experiments identify histidine 76 as a residue that strongly affects the catalytic activity. The experiments demonstrate its important influence on enantioselectivity.     

Analytical Determination of the Distribution of Polishing Time over the Surface of Polished Tiles

Several kinds of glossiness pattern can be seen on the surface of porcelain stoneware tiles right after the polishing process, as a function of the kinematics performed by the polishing heads. For the newest generation of industrial polishing trains, where a transverse oscillation is included, there is still a great need for literature about the resulting patterns. This paper intends to find the spatial distribution of time under polishing analytically using the kinematics equations involved in the polishing process. The measured values of glossiness collected from three polished tiles are also presented. The importance of adopting a good kinematics for the polishing process has been highlighted, and the equations developed herein are useful tools for further attempts at optimizing the polishing process.     

Undecidability of accordance for open systems with unbounded message queues

We study asynchronously communicating open systems modeled as Petri nets with an interface. An accordance preorder describes when one open system can be safely replaced by another open system without affecting some behavioral property of the overall system. Although accordance is decidable for several behavioral properties if we assume a previously known bound on the maximal number of pending messages, we show that it is not decidable without this assumption.     

15 years of processing and dissemination of SPOT-VEGETATION products

Throughout the VEGETATION programme, the Flemish Institute for Technological Research (VITO) uninterruptedly hosted the prime user segment of both VEGETATION 1 and VEGETATION 2 multispectral instruments on board the Satellite Pour l’Observation de la Terre 4 (SPOT 4) and SPOT 5 satellites. Operational since the launch of SPOT 4 in March 1998, and foreseen to continue at least until the end of the SPOT 5 mission (anticipated in spring 2014), this user segment comprises a processing facility (PF), actively receiving, processing, correcting, archiving, and distributing the VEGETATION data and derived added-value products. First and foremost, the VEGETATION programme has been serving the needs of operational users – both institutional and commercial – requesting data in near-real time. However, scientific and educational users too benefited significantly, in particular from VEGETATION’s unique time series of the Earth’s land cover, and more specifically the vegetation cover. Over the years, the centralized archive houses processed data covering the equivalent of 11,000 times the Earth’s surface, and delivered more than 50 terapixels to around 10.000 users. As such, VEGETATION’s mission is a prime example of what Europe wants to achieve through the Global Monitoring for Environment and Security (GMES) initiative: truly operational services providing reliable and up-to-date information.

This article describes the processing facility, the way the data and products are archived, the different dissemination channels as well as the data policy adopted and the users served. One of the recent evolutions, the development of an entirely new product distribution facility (PDF), implemented as part of the Project for On-Board Autonomy – Vegetation (PROBA-V) user segment is discussed.     

Scalable Realistic Rendering with Many‐Light Methods

Recent years have seen increasing attention and significant progress in many‐light rendering, a class of methods for efficient computation of global illumination. The many‐light formulation offers a unified mathematical framework for the problem reducing the full lighting transport simulation to the calculation of the direct illumination from many virtual light sources. These methods are unrivaled in their scalability: they are able to produce plausible images in a fraction of a second but also converge to the full solution over time. In this state‐of‐the‐art report, we give an easy‐to‐follow, introductory tutorial of the many‐light theory; provide a comprehensive, unified survey of the topic with a comparison of the main algorithms; discuss limitations regarding materials and light transport phenomena and present a vision to motivate and guide future research. We will cover both the fundamental concepts as well as improvements, extensions and applications of many‐light rendering.     

A 60‐GHz on‐chip slot‐array antenna in integrated‐passive‐device technology for antenna‐in‐package applications

A new millimeter‐wave antenna structure on a low‐cost, production platform integrated passive device technology is presented. The antenna consists of a 2‐by‐1 array of slot antennas at 60 GHz. An in‐house developed on‐chip antenna measurement setup was used to characterize the fabricated antenna. The measurement results show an antenna gain of more than 5 dBi with a return loss of 18 dB at 60 GHz. The better‐than‐10‐dB impedance bandwidth of the antenna covers the 60‐GHz unlicensed band from 57 to 64 GHz. The 3‐dB beamwidths of the antenna are 105° and 76° at E‐plane and H‐plane at 60 GHz, respectively. The size of the die of the antenna is 2 mm × 4.5 mm. © 2013 Wiley Periodicals, Inc. Int J RF and Microwave CAE 24:155–160, 2014.     

On the mechanism of transfer enhancement by eddy promoters

Mass transfer rates in a rectangular duct of low aspect ratio containing semicircular cylindrical inserts attached alternately on opposite walls and perpendicular to the flow direction were measured with the electrochemical diffusion-limited current technique. Local and average mass transfer coefficients determined with arrays of strip electrodes indicate the existence of at least two transfer regimes. In the laminar regime the exponent on the Reynolds number depends on the eddy promoter spacing. In the turbulent regime the data correlate well according to j_D = 0.57 Re^?0.35(d_h/p)^0.40.The local transfer distributions reveal the existence of separated flow regions downstream of, as well as opposite to, turbulence promoters. The flow in the reattachment region is very unstable and this results in earlier transition to turbulence.The local transfer distributions also suggest that boundary layer disruption at, and redevelopment downstream of, separated regions is the dominant mechanism of transfer enhancement in the turbulent regime. An idealized model based on this assumption, and making use, of results obtained for turbulent transfer to a flat plate in an infinite medium predicts a relationship in approximate agreement with the experimental correlation given above.The mass transfer results for fully developed turbulent flow also correlate well according to a mass transfer similarity law.     

Blends of i‐PP and SBS. I. Influence of the in situ compatibilization on the morphology

This article concerns the in situ compatibilization of immiscible isotactic polypropylene/butadiene‐styrene‐butadiene triblock copolymer blends (i‐PP/SBS) by means of a reactive mixture. For this purpose, maleated PP (PP‐MAH) and SBS (SBS‐MAH) were used as functionalized polymers and 4,4′‐diaminediphenylmethane was used as a coupling agent between maleated polymers, resulting in a graft copolymer. Binary blends i‐PP/SBS, nonreactive ternary blends i‐PP/PP‐MAH/SBS, and reactive ternary blends i‐PP/PP‐MAH/SBS‐MAH with varying diamine and anhydride molar ratios were prepared. Torque measurements suggest a graft copolymerization during the melt blending for ternary reactive blends, but the extension of the grafting does not vary with the diamine and anhydride molar ratio, but with the elastomer concentration. The morphology of the blends was investigated by scanning electron microscopy. The morphology of binary and ternary nonreactive blends is similar, exhibiting elastomer domains disperse in the i‐PP matrix, whose sizes increase with elastomer concentration. On the other hand, the elastomer domain size in the ternary reactive blends is practically independent of the blends composition and of the diamine and anhydride molar ratio. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 847–855, 2002