Syntheses and Structural Characterization of Triorganotin Derivatives of Bis(carboxymethyl)trithiocarbonate: X-ray Crystal Structures of 2D Network Polymers

Six triorganotin(IV) complexes of the type {(R₃Sn)₂[C₃S₃(COO)₂]}_n (R = C₆H₅ 1; n-Bu 2; PhCH₂ 4; p-F-PhCH₂ 5; o-F-PhCH₂ 6) and {(R₃Sn)₂[C₃S₃(COO)₂]}_n·[EtOH] (R = Me 3) have been synthesized by the reaction of bis(carboxymethyl)trithiocarbonate with triorganotin(IV) chloride in the presence of sodium ethoxide. All complexes were characterized by elemental analysis IR, ¹H, ¹³C and ¹¹⁹Sn NMR spectroscopy. Except for 4–6, all complexes were also characterized by X-ray crystallography. The X-ray date revealed that complexes 1–3 show two-dimensional network polymeric structure in which the geometries of tin atoms are trigonal bipyramid with the axial positions occupied by carboxylic oxygen atoms.     

c-BN color change with bonded water added into the h-BN–Mg system

Cubic boron nitride (c-BN) crystals were synthesized in conditions of high temperature and high pressure (HTHP) when different kinds of bonded water were respectively added into the system of h-BN–Mg. All bonded water used in this work could reduce the temperature of growing c-BN compared to that in the system of h-BN–Mg. The c-BN color could change from black to yellow when certain amounts of bonded water, such as NiSO₄·6H₂O and CuSO₄·5H₂O, Mg(OH)_2, were added. However, c-BN color remained black no matter how much bonded water, such as NiCl₂·6H₂O, CuCl₂·2H₂O, and SnCl₂·2H₂O, was added. The bonded water can be classified into Chlorine-containing bonded water (Cl-BW) and Chlorine-free bonded water (ClF-BW) according to their different characters and effects on the synthesized c-BN color.     

Synthesis of Hexagonal‐Phase NaYF4:Yb,Er and NaYF4:Yb,Tm Nanocrystals with Efficient Up‐Conversion Fluorescence

IR‐to‐visible up‐conversion fluorescent nanocrystals of hexagonal‐phase NaYF₄:20 %Yb,2 %Er and NaYF₄:20 %Yb,2 %Tm have been synthesized by decomposition of multiprecursors of CF₃COONa, (CF₃COO)₃Y, (CF₃COO)₃Yb, and (CF₃COO)₃Er/(CF₃COO)₃Tm in oleylamine at 330 °C. The average particle size is 10.5 ± 0.7 nm (from random measurements of 200 particles from five transmission electron microscopy images) and 11.1 ± 1.3 nm (from dynamic‐light‐scattering measurements). The up‐conversion fluorescence intensity of the hexagonal nanocrystals in this work is much higher than that of other cubic‐phase NaYF₄:Yb,Er nanocrystals, including the ones in this work (by a factor of 7.5). Mechanisms for nucleation and growth of the hexagonal‐phase nanoparticles are proposed. These nanocrystals are easily dispersed in organic solvents, producing a transparent colloidal solution. The hydrophobic surfaces of the particles are made hydrophilic using a bipolar surfactant. These nanoparticles and their dispersions in various media have potential applications in optical nanodevices and bioprobes.     

除沫器自动冲洗装置的设计及应用

本文针对Ⅰ效二次蒸汽折流板式除沫器需定时冲洗的实际情况，设计了一套冲洗间隔灵活可调的自动冲洗装置，该装置结构简单、工作可靠，易于实现，有一定的实用价值。     

制盐设备用不锈钢及复合板的选材

OOCr18Ni5Mo3Si2(以下简称18－5）属铁素体（α）－奥氏体（γ）双相不锈钢，具有良好的耐Cl^-点蚀和应力腐蚀性能，18－5不锈钢复合板因其兼备优良的使用性能和较低的制造成本，在制盐领域不锈钢材料中，是理想的选择。本就OOCr18Ni5Mo3Si2双相不锈钢及复合板的性能、特点以及在制盐领域的成功事例作一介绍。     

Composite group vector space method for estimating melting and boiling point of pure organic compound

Composition Group Vector Space (CGVS) method for estimating melting and boiling point T _m , T _b of organic compound has been proposed, and the principle of this method has been elucidated. The models for estimating T _m , T _b have been established and the numerical values of relative parameters have been presented. The average percentage deviations of T _m , T _b estimation are 7.53 and 1.58, respectively, which show that the present method demonstrates significant improvement in applicability to predict the above properties, compared to conventional group methods.     

普通热轧钢材的合理洁净度及生产工艺探讨

钢凝固前、后生成的非金属夹杂物形貌和在钢中的分布特点不同,凝固前生成的夹杂物尺寸较大,在钢中随机分布,主要影响钢材的疲劳强度和延性等性能。凝固后生成的夹杂物尺寸小,主要在晶界富集析出。硅锰脱氧钢脱氧后钢液仍含有20×10-6以上溶解氧,这部分溶解氧在钢凝固后绝大多数会转变为微细的氧化物或氧硫化物夹杂。钢凝固后生成的夹杂物主要影响钢材的冲击韧性、韧-脆转换温度等性能。 对热轧长型材用普碳钢和低合金钢不必采用铁水脱硫预处理,对热轧钢板用普碳钢可采用铁水轻度脱硫预处理,对热轧钢板用低合金高强度钢可采用铁水脱硫预处理、炼钢过程抑制回硫和出钢过程脱硫的工艺。对超低硫低合金钢,在钢水炉外精炼脱硫处理过程钢-渣间须维持非常低的氧势,炉渣成分应控制在CaO:SiO2:Al2O3=60％～65％:4％-8％:30％～35％范围。 普通热轧长型材用钢脱氧后溶解氧含量可放宽至(30-50)×10-6,对中、厚板钢溶解氧含量必须较严格控制,最好采用铝脱氧将溶解氧控制在较低的水平,并将T[O]含量控制在50×10-6以下。采用降低炼钢终点钢水氧含量、出钢挡渣、CAS和CAB等较简易炉外精炼方法和防止铸坯夹渣等措施,能够生产满足普通热轧钢洁净度要求的高品质钢材。     

A multi-criterion interaction-oriented model with proportional rule for designing supply chain networks

Supply chain management has offered a way to improve the industrial environment becomes more competitive. While, the commonly seen methodologies may be effective in solving the production–distribution problem only from supplier- or customer-oriented consideration, those cannot present the interactive relationship between upstream and downstream enterprises. In the competitive semiconductor industry environment, considering the viewpoints of the supplier and consumer simultaneously is particularly required, because multiple manufacturing and demanding steps are performed at separate situations, concurrently. In this paper, we propose an interaction-oriented approach, which bases on the analytic hierarchy process (AHP) methodology and proportional rule, to solve the semiconductor distribution problem with multiple quantitative and qualitative criteria. The developed approach gives an expected satisfaction for the all participators of the whole chain while the cooperative information is shared perfectly and effectively. Analysis results demonstrate the proposed methodology is efficient and effective through a real world case study.