A Light‐Blue Phosphorescent Dendrimer for Efficient Solution‐Processed Light‐Emitting Diodes

We describe the preparation of a dendrimer that is solution‐processible and contains 2‐ethylhexyloxy surface groups, biphenyl‐based dendrons, and a fac‐tris[2‐(2,4‐difluorophenyl)pyridyl]iridium(III ) core. The homoleptic complex is highly luminescent and the color of emission is similar to the heteroleptic iridium(III ) complex, bis[2‐(2,4‐difluorophenyl)pyridyl]picolinate iridium(III ) (FIrpic). To avoid the change in emission color that would arise from attaching a conjugated dendron to the ligand, the conjugation between the dendron and the ligand is decoupled by separating them with an ethane linkage. Bilayer devices containing a light‐emitting layer comprised of a 30 wt.‐% blend of the dendrimer in 1,3‐bis(N‐carbazolyl)benzene (mCP) and a 1,3,5‐tris(2‐N‐phenylbenzimidazolyl)benzene electron‐transport layer have external quantum and power efficiencies, respectively, of 10.4 % and 11 lm W^–1 at 100 cd m^–2 and 6.4 V. These efficiencies are higher than those reported for more complex device structures prepared via evaporation that contain FIrpic blended with mCP as the emitting layer, showing the advantage of using a dendritic structure to control processing and intermolecular interactions. The external quantum efficiency of 10.4 % corresponds to the maximum achievable efficiency based on the photoluminescence quantum yield of the emissive film and the standard out‐coupling of light from the device.     

Bruchanalyse an Hohlgläsern

Failure analysis of hollow glasses The failure analysis is very important to clarify damages of hollow glasses. Damages of glass bottle through over pressure are very often linked with damages to persons. This is the reason why the causal research is from particular importance. Different surface characteristics of glass fragments as well as the fracture pattern give hints to the direction of the crack, the stress just before breakage and the reason of stress. A reconstruction of the bottle is a further helpful instrument for cause studies. The difference of the various characteristics of the surface will be explained. Further on there will be discussed different reasons and mechanism of fracture.     

成都市火车南站斜拉桥斜拉索安装工艺

采用倒链葫芦、卷扬机或软牵引装置对斜拉索进行牵引安装 ,使牵引力达到 5 0 0余kN ,解决了斜拉索安装拉力大这一施工难题。     

电液比例控制技术在工程船舶中的应用

以长江及沿海航道铺排工程船(长雁1号)液压系统的工程项目为背景,采用电液比例控制技术设计了一种新型的电液比例控制系统,通过对移船马达速度的控制实现了移船的移位和准确定位,同时液压系统的能耗也大大降低.     

钛镍形状记忆合金的研究进展

从应用角度简要介绍了钛镍合金的研究和应用状况，简明地评述了它的物理冶金基础、热机械行为和力学模型的研究情况．     

射频激励扩散型冷却阵列波导CO2激光器技术

本文介绍了目前国内外研究者们提出的各种射频激励相干阵列波导ＣＯ２激光器技术，讨论了射频激励相干阵列波导ＣＯ２激光器技术的一个研究方向。     

准分子激光泵浦的皮秒染料激光器

利用准分子激光泵浦猝灭式染料激光器，获得了３０ｐｓ的可调谐染料激光脉冲输出。