N,N''-取代邻苯二胺的合成

通过2-取代苯并咪唑盐的还原开环反应制备了8个N,N′-不同取代的邻苯二胺,并经1HNMR、IR、MS及元素分析表征,其中5个未见文献报道.这是一条由邻苯二胺和羧酸经2.取代苯并咪唑制取该类化合物的简洁合成路线.     

Flocculation morphology: effect of particulate shape and coagulant species on flocculation.

Flocculation morphology is a new concept that investigates the morphological characteristics of colloidal particles and coagulants in water during the flocculation process, and the influence that these characteristics have on flocculation process efficiency. This paper is a summary of advances in research on this topic over several years. Morphological characteristics of colloids in natural waters and different kinds of hydrolysed coagulants are investigated, and their effect on colloid stability, flocculation kinetics and efficiency is analysed. It is confirmed that the traditional theory has some deviations in coagulation of nonspherical particles, and these deviations are revised by the flocculation morphology model. Flocculation morphology can not only promote research about flocculation theory, but also instruct the production, application and flocculation control. It can be foreseen that more progress will be made in research and application of flocculation morphology in the near future.     

Asymmetric Regulation System Fit for Chinese Telecom Market

After the new round of restructuring of Chinese telecom sector,it's pressing to formulate and implement asymmetric regulation policies so as to shape an effectively competitive market structure in a relatively short term.This paper reviewed the asymmetric regulation policies and practices carried out in foreign telecom market,and then according to the specific situations of Chinese telecom market,proposed the principles and corresponding policies for establishing an asymmetric regulation system fit for Chin...     

箍筋末端135度弯钩二次就位法讨论

随着人们对建筑安全的日益重视 ,对建筑抗震要求的提高 ,国内外有关规范都对箍筋末端的设置作了明确规定 ,要求做成 135度弯钩。而在工程实践中 ,由于施工上的技术困难 ,很多工程都只设置成 90度弯钩。笔者提出的箍筋末端 135度弯钩二次就位法在基本不增加 90度弯钩施工难度与费用的基础上实现了 135度弯钩的施工 ,其法是可行的     

基于显微视觉的宏/微双重驱动微动台的自动标定

提出了基于压电技术的微操作系统的自动标定方法,采用混合式步进电机直接驱动的宏动平台,实现系统大行程宏动定位,安装在宏动平台上的压电陶瓷驱动的微动平台和精密光栅,实现亚微米级的分辨率和定位精度,通过以上两部分实现定位机构的全闭环反馈控制,采用显微视觉反馈获取微动台操作器在图像中的位置信息进行标定。实验结果表明:系统的动态和稳定性能良好,自动标定运算速度快,运行速度达到11 frame/s,实现了对系统的精确标定,标定精度达到0.1μm。     

Synthesis and Characterizations of Triphenylamine End-Functionalized Polymers via Reversible Addition-Fragmentation Chain Transfer Polymerization

A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA) group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers. The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE as the RAFT agent. Number-average molecular weight (M_n,GPC) increased linearly with monomer conversion, and molecular weight distributions were relatively narrow (PDI< 1.50). The results of chain-extension reaction, ¹H NMR spectra and UV/Vis spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine (TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated.