Synthesis of Single-Crystalline Silicon Nitride Nanobelts Via Catalyst-Assisted Pyrolysis of a Polysilazane

Recently, one-dimensional nanostructures have attracted extensive attention since they are potentially important for both applications and fundamental research. In this paper, we report the synthesis of ultra-long single crystal Si₃N₄ nanobelts via catalyst-assisted pyrolysis of polymeric precursors. The obtained products contain both α- and β-Si₃N₄ nanobelts, which are 50–100 nm in thickness, 400–1000 nm in width, and a few hundreds of micrometers to several millimeters in length. Different from previous techniques for synthesizing one-dimensional structures, the current nanobelts are synthesized through confined crystallization of an amorphous phase. A solid–liquid–gas–solid reaction/crystallization growth mechanism is proposed. The formation of nanobelts instead of nanowires is attributed to the anisotropy growth at an earlier stage.     

库什塔依水电站工程建设质量管理

库什塔依水电站工程面临着工期紧、任务重、沥青混凝土冬季施工等问题,给现场的施工管理带来了挑战。在建设过程中严格执行中电投新疆公司管理制度,通过建立健全质量保证体系,完善质量保证措施,强化参建各方的质量责任意识,加强过程监控,实现了工程建设的质量目标。     

Inadequacy of Land Use and Impervious Area Fraction for Determining Urban Stormwater Quality

Urban stormwater quality is multifaceted and the use of a limited number of factors to represent catchment characteristics may not be adequate to explain the complexity of water quality response to a rainfall event or site-to-site differences in stormwater quality modelling. This paper presents the outcomes of a research study which investigated the adequacy of using land use and impervious area fraction only, to represent catchment characteristics in urban stormwater quality modelling. The research outcomes confirmed the inadequacy of the use of these two parameters alone to represent urban catchment characteristics in stormwater quality prediction. Urban form also needs to be taken into consideration as it was found have an important impact on stormwater quality by influencing pollutant generation, build-up and wash-off. Urban form refers to characteristics related to an urban development such as road layout, spatial distribution of urban areas and urban design features.     

乡村居民疫水接触时空规律研究

基于农村居民疫水接触的空间行为及作息时间的地理调查,了解乡村居民的血吸虫病疫水接触时空规律,对43个行政村的疫水接触人数、方式、天数、接触季节和时间段进行调查。农村居民疫水接触方式有种田、捕鱼、游泳、抗洪、挖沙、打藜蒿、放牛、养鸭和洗衣服洗菜一共9种方式,接触方式多、时间长,感染血吸虫病危险性较大。     

Effect of polycarboxylate-type superplasticizer on the paste fluidity based on the water film thickness of flocs

The excess water film theory and the properties of flocs are integrated to examine the effect of the polycarboxylate-type superplasticizer on the paste fluidity.The theory states that excess water can surround the flocs rather than the particles and that the cell consists of a floc and a superficial water film.Experiments on limestone powder pastes were conducted to verify the theory.The superplasticizer dosage(sp%)and the water–powder ratio by volume(Vw/Vp)were systematically varied.A sedimentation balance method was used to measure the size distribution of the flocs in the limestone powder pastes.The water film thickness(WFT)of flocs was then calculated and shown to determine the paste fluidity.Based on this WFT of flocs,the effect of the sp on the paste fluidity was determined and then compared with the effect of water.     

工程总承包公司的合同管理研究

山东鲁能工程有限责任公司开展电力工程总承包始于上世纪九十年代中期,近五年来总承包事业发展迅速,公司陆续签订了嘉峪关宏晟2×300M W电厂、重庆永川2×125M W电厂、费县2×600M W电厂脱硫、章丘2×300M W电厂脱硫、潍坊2×25M W电厂、单县1×25M W生物发电厂等一批总承包合同,均采用了国际上通行的FID IC合同条款。为规范公司的经营管理,防范合同风险,维护公司合法权益,我们研究摸索了一套适应矩阵管理的总承包公司合同管理体系,在此做简要介绍,与同行交流。一、合同管理中常见问题合同是市场经济下确定不同主体之间经济关系的重…     

Consecutively spin-assembled layered nanoarchitectures of poly(sodium 4-styrene sulfonate) and poly(allylamine hydrochloride)

The recently established spin-coating electrostatic self-assembly (SCESA) technique has been shown to facilitate not only the rapid fabrication of polyelectrolyte multilayer assemblies, but also allow each layer to be easily controlled on a monomolecular scale by minimizing the film thickness across a substrate surface. In this paper, the influence of polyelectrolyte concentration on the amount and thickness of spin-deposited polymer films has been examined for a multilayer system of poly(allyamine hydrochloride) (PAH) and poly(sodium 4-styrenesulfonate) (PSS), when the washing steps employed for removing weakly bound polyelectrolytes on a resultant film on a substrate are excluded from the standard fabrication procedure of the SCESA method. The thickness of the spin-deposited PAH/PSS bilayer increased linearly for the PSS concentrations in the range from 1 to 10 mM with PAH constant at 1 mM, which demonstrates the uniform deposition of each layer material onto the thin film. The thickness of PAH/PSS bilayers increased from 1.43 ± 0.06 to 3.37 ± 0.08 nm as the PSS concentration increased from 1 to 10 mM, while the PAH concentration was kept constant at 1 mM. The multilayer films were found to be stable in a good solvent (H₂O) for at least 30 h, without any noticeable loss of the adsorbed layer component of the polyelectrolyte. This improvement to the SCESA method (exclusion of washing steps) provides a convenient way to create multilayer heterostructures with the thickness of each layer being easily adjusted.     

单质铝水解机理研究(Ⅲ)——单质铝水解结晶过程研究

为了了解单质铝在水解过程中产物物相的变化规律,对单质铝水解过程进行了全过程监测,在反应的不同时段取样并对其进行XRD、SEM分析。以XRD分析结果为依据,对单质铝水解结晶过程中产物物相的变化进行了深入研究,彻底弄清了水解产物的生成顺序。以SEM分析为依据,对影响水解产物形貌、粒度及粒度分布的因素进行了研究。分析认为,团聚、二次成核、搅拌等因素对结晶过程中水解产物的形貌、粒度有显著影响。     

两种标准信号之间的函数变换

用函数变换的方法解决两种标准信号之间的转换，进而阐述了数学在解决实际问题中的应用。