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41.
J. Chen J. B. Xu K. Xue J. An N. Ke W. Cao H. B. Xia J. Shi D. C. Tian 《Microelectronics Reliability》2005,45(1):137-142
Transition-metal compound TiC60 thin films were grown by co-deposition from two separated sources of fullerene C60 powder and titanium. Study of structural properties of the films, by Raman spectroscopy, atomic force microscopy, and scanning tunneling spectroscopy reveals that the films have a deformed C60 structure with certain amount of sp3 bonds and a rough surface with a large number of nanoclusters. z–V tunnelling spectroscopic measurements suggest that several charge transport mechanisms are involved in as the tip penetrates into the thin film. Conventional field electron emission (FEE) measurements show a high emission current density of 10 mA/cm2 and a low turn-on field less than 8 V/μm, with the field enhancement factors being 659 and 1947 for low-field region and high-field region, respectively. By exploiting STM tunneling spectroscopy, local FEE on nanometer scale has also been characterized in comparison with the conventional FEE. The respective field enhancement factors are estimated to be 99–355 for a gap varying from 36 to 6 nm. The enhanced FEE of TiC60 thin films can be ascribed to structural variation of C60 in the films and the electrical conducting paths formed by titanium nanocrystallites embedded in C60 matrix. 相似文献
42.
Recently, in our laboratory a closed form expression for the correlation function of the hard-sphere dimer fluid obtained
from Wertheims multidensity Ornstein-Zernike integral equation theory with Percus-Yevick approximation was presented by Kim
et al. [2001]. However, it is difficult to apply its expression to perturbation theory and vapor-liquid equilibria calculations,
since it is of very complex form. In this work, we present a simplified expression for the first shell of the radial distribution
function (RDF) of the hard-sphere dimer fluid using a series expansion of the analytical expression. The expansion is carried
out in terms of both the packing fraction and the radial distance. Expressions are also obtained for the coordination number
and its first and second derivatives as functions of radial distance and packing fraction. These expressions, which are useful
in perturbation theory, are simpler to use than those obtained from the starting equation, while giving good agreement with
the original expression results. Then we present an simplified equation of state for the square-well dimer fluid of variable
well width (λ) based on Barker-Henderson perturbation theory using its expression for the radial distribution function of
the hard-sphere dimer fluid, and test its expression with NVT and Gibbs ensemble Monte Carlo simulation data [Kim et al.,
2001]. 相似文献
43.
BaMgAl10O17∶Eu2 (BAM) was prepared in the microemulsion system and its phase behavior was studied. There exists a small region in the reverse microemulsion system where the dispersed particles are of spherical form. In this way, BAM blue phosphor with good dispersion can be synthesized. The microemulsion phase diagrams of the pseudo-ternary system (Triton X-100/cosurfactant-oil-BAM brine) were first established intuitively by the dilution method. The microstructure of microemulsions was determined through eyeballing, conductance technique, and polar optical microscopy. Its phase behavior is affected by various factors, such as temperature (room temperature, 30, 40 ℃), oil, surfactants, and cosurfactants in microemulsions. According to the phase diagrams, the microemulsion system of Triton X-100/1-hexanol-hexane-BAM brine was chosen to prepare the precursor. The BAM phosphor can be obtained via sintering the precursor at a comparatively low temperature. The phosphors were characterized by XRD and vacuum ultraviolet (VUV) spectra. 相似文献
44.
Nguyen An Tien I. Ya. Mittova O. V. Almjasheva S. A. Kirillova V. V. Gusarov 《Glass Physics and Chemistry》2008,34(6):756-761
Nanocrystalline LaFeO3 is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO3 nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size. 相似文献
45.
The Jian kiln, located in present-day Jianyang county of Fujian province, mainly produced black-glazed tea bowls. Jian tea bowl was used as a utensil for tea tasting and was greatly appreciated by emperor Huizong of the Northern Song dynasty. The black glaze of Jian bowl was sometimes marked with streaks or spots, usually called “hare's fur” or “oil spot”, which are the crystalline markings of iron oxide precipitated during firing in the dragon kiln. In this study, black-glazed Jian bowl sherds excavated from the late Northern Song strata of Luhuaping and Daluhoumen Jian kiln sites were adopted as test samples. Based on the physico-chemical foundation for the formation of glaze microstructure, the correlation among composition, microstructure, and visual appearance has been investigated by means of energy-dispersive X-ray fluorescence, X-ray diffraction, and field emission electron microscopy. For the first time, the study provides realizing proofs for two kinds of microstructural forming mechanics. 相似文献
46.
We present a numerical study of the packing of uniform spheres under three-dimensional vibration using the discrete element method (DEM), focusing on the effects of vibration condition (amplitude and frequency) and inter-particle frictions (sliding and rolling frictions). The results are analysed in terms of packing density, coordination number (CN), radial distribution function (RDF) and pore structure. It is shown that increasing either the vibration amplitude or frequency causes packing density to increase initially to a maximum and then decrease. Both vibration frequency and amplitude should be considered to characterize the effect of vibration process on packing structure. The sliding and rolling frictions between particles can decrease packing density since they dissipate energy, although the effect of rolling friction is less significant. In line with the change of packing density, microstructural properties such as CN, RDF and pore distribution also change: a looser packing often corresponds to smaller CN, less peaked RDF and larger but more widely distributed pores. 相似文献
47.
48.
Sung-Hoon An U-Yeol Park Kyung-In Kang Moon-Young Cho Hun-Hee Cho 《Canadian Metallurgical Quarterly》2007,21(4):259-264
Total conceptual cost estimates and the assessment of the quality of these estimates are critical in the early stages of a building construction project. In this study, the support vector machine (SVM) model for assessing the quality of conceptual cost estimates is proposed, and the application of SVM in construction areas is investigated. The results show that the SVM model assessed the quality of conceptual cost estimates slightly more accurately than the discriminant analysis model. This shows that using the SVM has potential in construction areas. In addition, the SVM model can assist clients in their evaluation of the quality of the estimated cost and the probability of exceeding the target cost, and in their decision on whether or not it is necessary to seek a more accurate estimate in the early stages of a project. 相似文献
50.