偏载下板柱结构中柱节点破坏试验研究

采用重剪比以及配筋率两个试验变量对4个板柱中节点的破坏过程进行了对比试验,并在试验过程中采用特制应变测杆对试件内部斜裂缝的形成和发展予以监测。试验结果表明：试件最终破坏形态受重剪比和配筋率两因素共同影响;重剪比相同的试件,配筋率的提高也可有效提高中柱节点对不平衡弯矩的承载力;板内斜裂缝在节点发生冲切破坏之前已产生,并从靠近柱头的受压区向板底受拉区开展。基于试验结果和历史试验数据,将中国规范 GB 50010—2010所采用的基于偏心剪应力模型的计算方法和欧洲规范 Eurocode2-04进行对比,分析了偏心剪应力模型不足的原因。     

Preparation and characterization of epoxy/kaolinite nanocomposites

Epoxy/kaolinite nanocomposites were prepared by adding the organically modified layered kaolinite to an epoxy resin [biphenyl phenol novolac epoxy resin (BPNE)] with 4,4′‐diamino biphenyl sulfone (DDS) as a curing agent. The dispersion state of the kaolinite within crosslinked epoxy‐resin matrix was examined by X‐ray diffraction (XRD) and transmission electron micrograph (TEM). The effects of kaolinite on thermal properties were investigated and discussed by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Experimental results show that BPNE/kaolinite nanocomposites exhibit improved thermal than pure BPNE. When the kaolinite content is 5 wt %, the BPNE/kaolinite nanocomposites show the best thermal properties. These results indicate that nanocomposition is an efficient and convenient method to improve the thermal properties of BPNE. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Preparation,characterization, and polymerization of novel maleimidobenzoxazine containing carboxylic moiety and its cocuring behaviors with epoxy resin

A novel benzoxazine containing maleimide and carboxylic moieties, 1‐[3‐(4‐carboxylphenyl)‐3,4‐dihydro‐2H‐benzo[e][1,3]‐oxazin‐6‐yl]maleimide (Mal‐Bz‐Co), was synthesized and the structure was identified by ¹H‐NMR and FTIR. Mal‐Bz‐Co exhibited good solubility in common organic solvents. The cure behavior of Mal‐Bz‐Co and cocure behavior of Mal‐Bz‐Co with o‐cresol formaldehyde epoxy resin were investigated by differential scanning calorimetry. Results indicated that Mal‐Bz‐Co showed a single curing exothermic peak at about 238.3°C. However, the maximum curing temperature (T_p) decreased to 146.1°C when Mal‐Bz‐Co cocured with o‐cresol formaldehyde epoxy resin in the molar ratio of 1 : 1. The T_p was about 92°C lower than that of Mal‐Bz‐Co. Thermogravimetric analysis showed that high‐decomposition temperature and char yield were observed for the cured resins of Mal‐Bz‐Co and Mal‐Bz‐Co/o‐CFER. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

建筑中水处理技术及应用分析

介绍了建筑中水的主要处理工艺及中水回用技术应用情况,讨论了建筑中水的经济影响因素、发展趋势和制约中水推广应用的原因。     

石油化工污水深度处理与回用的研究进展

石油化工企业污水经过物理预处理,生化二级处理后仍含有难降解的微溶有机污染物、悬浮物、油等杂质,必须经过深度处理才能达到回用水质标准,实现污水回用,解决石化厂用水量大、水资源短缺的问题。简要介绍国内外石化污水回用现状,重点介绍了国内外石化污水深度处理的常用方法,分析了这些方法在石化污水深度处理中的优缺点,以及需要改进的方面,并展望了一些新型处理技术在石化污水深度处理中的应用前景。     

深部软弱围岩叠加拱承载体强度理论及应用研究

 目前,长锚索与锚喷网支护相结合的支护方式在深部软弱围岩中已经得到了广泛应用,但是对于这种联合支护结构的承载特点缺乏深入了解,特别是对于初次支护和二次支护的承载能力没有量化解析式。因此,在岩石力学理论的基础上,针对深部软弱围岩的“锚喷网+锚索”联合支护特点,提出由主压缩拱(锚杆支护)和次压缩拱(密集型锚索支护)共同构成的叠加拱承载体力学模型;根据弹塑性理论、锚杆的中性点理论和锚索的力传递机制推导初次支护和适当让压后二次支护的承载体强度方程;并将“围岩–支护结构”组成的共同体看作一种等效耦合围岩,运用弹塑性力学方法得到这种等效耦合围岩的力学参数随释放位移(让压位移)变化的关系式。工程计算表明,金川III矿区破碎硐室经叠加拱支护后,极限承载能力 可达到513.34 kN,等效耦合岩体 值可达到47.54°, 最大值为1.37 MPa,提高围岩的峰后强度,有利于硐室围岩的长期稳定;现场监测也表明,进行叠加拱承载体支护后的硐室围岩变形趋于平稳,收敛速率小于0.1 mm/d。     

Synthesis of dodecylbenzene via the alkylation of benzene and 1-dodecene over mesopore Beta zeolites

The alkylation of benzene with long chain α-olefins is a crucial process in the production of fine chemicals, which requires the upgrading from traditional homogeneous catalysis to heterogeneous catalysis involving zeolites. However, the application of zeolite catalysts has been limited by their fast deactivation due to constrained diffusion resulting from the sole micropores. To address this challenge, a desilication and secondary-crystallization strategy has been employed to fabricate hierarchically structured mesoporous Beta zeolites. The resultant mesoporous Beta zeolites demonstrate excellent catalytic activity and stability in the alkylation of benzene with 1-dodecene, arising from the exposed acid sites and enhanced internal diffusion. Importantly, the internal diffusion limitations for these mesopore Beta zeolites are negligible, which significantly extends their lifetime and improves their regeneration performance. To achieve these benefits, the degree of mesopores must be deliberately controlled. Overall, this approach provides a promising solution for achieving efficient and environmentally friendly alkylation processes.     

Measurement and prediction of isothermal vapor–liquid equilibrium of a-pinene + camphene/longifolene + abietic acid + palustric acid + neoabietic acid systems

The vapor–liquid equilibrium(VLE) data of a-pinene + camphene + [abietic acid + palustric acid + neoabietic acid] and a-pinene + longifolene + [abietic acid + palustric acid + neoabietic acid] systems at 313.15 K,333.15 K and 358.15 K were measured by headspace gas chromatography(HSGC). These data was compared with the predictions value by conductor-like screening model for realistic solvation(COSMO-RS).Moreover, the calculated data of COSMO-RS and Non-Random Two-Liquids(NRTL) models showed good...     

造纸企业能量系统"三环节"模型的建立及应用探讨(Ⅱ)--造纸企业能量系统用能分析与评价

根据"三环节"能量结构模型,对某造纸企业的能量系统进行了热量平衡、(火用)平衡以及能量效率进行了计算和分析,并分别对能量利用环节、能量回收环节和能量转换环节的能量利用、能量回收和能量转换效率进行了评价,分析研究了该厂各环节能量效率低下的因素,指出该厂具有巨大的节能潜力.     

激光对人眼的危害和防护

叙述了激光对人眼的危害作用，阐明了激光防护的重要性。列出了激光防护镜的标准。介绍了如何选择激光防护镜。