High‐Performance Manganese Hexacyanoferrate with Cubic Structure as Superior Cathode Material for Sodium‐Ion Batteries

Sodium manganese hexacyanoferrate (Na_xMnFe(CN)₆) is one of the most promising cathode materials for sodium‐ion batteries (SIBs) due to the high voltage and low cost. However, its cycling performance is limited by the multiple phase transitions during Na⁺ insertion/extraction. In this work, a facile strategy is developed to synthesize cubic and monoclinic structured Na_xMnFe(CN)₆, and their structure evolutions are investigated through in situ X‐ray diffraction (XRD), ex situ Raman, and X‐ray photoelectron spectroscopy (XPS) characterizations. It is revealed that the monoclinic phase undergoes undesirable multiple two‐phase reactions (monoclinic ? cubic ? tetragonal) due to the large lattice distortions caused by the Jahn–Teller effects of Mn³⁺, resulting in poor cycling performances with 38% capacity retention. The cubic Na_xMnFe(CN)₆ with high structural symmetry maintains the structural stability during the repeated Na⁺ insertion/extraction process, demonstrating impressive electrochemical performances with specific capacity of ≈120 mAh g^?1 at 3.5 V (vs Na/Na⁺), capacity retention of ≈70% over 500 cycles at 200 mA g^?1. In addition, the TiO₂//C‐MnHCF full battery is fabricated with an energy density of 111 Wh kg^?1, suggesting the great potential of cubic Na_xMnFe(CN)₆ for practical energy storage applications.     

诊断权衡优化测试性分析技术

现今对于电子设备进行故障诊断以及后续PHM的需求越来越多,本文结合测试性分析的流程,提出了一种面向诊断的测试性分析方法,并使用开发的软件对某型号的发电机进行测试性建模与分析,按照给出的诊断策略进行测试可以取得比较好的效果。     

Distributed machine learning load balancing strategy in cloud computing services

Wireless Networks - Mobile service computing is a new cloud computing model that provides various cloud services for mobile intelligent terminal users through mobile internet access. The quality of...     

基于MNMP的ScanSAR并行成像系统设计

该文对星载ScanSAR成像并行处理进行了详细的研究。首先,针对ScanSAR成像机制的特殊性,给出了基于传统主-从模式的并行实现流程。根据主-从模式的不足,该文提出了一种基于多节点-多进程的异步并行模式的星载ScanSAR并行处理的技术。实验结果表明,相对于传统的并行处理方法,该文所采用方法的成像时间得到了较好的改善,具有一定的优越性。     

Tsallis Entropy Based q-Gaussian Density Model and Its Application in Measurement Accuracy Improvement

The central limit theorem guarantees the distribution of the measurand is Gaussian when the number of repeated measurement is infinity, but in many practical cases, the number of measurement times is limited to a given number. To overcome this contradiction, this paper firstly carries out the maximum likelihood estimation for parameter q in q-Gaussian density model developed under the maximum Tsallis entropy principle. Then the q-Gaussian probability density function is used in the particle filter to estimate and measure the nonlinear system. The estimated parameter q is related to the ratio between the measurement variance and the given variance, which indicates that the measurement accuracy cannot be improved if we only increase the repeated measurement times. Via using the proposed q-Gaussian density model, the measurement error (the average mean square error) of the estimation results can be reduced to a considerable level where the number of repeated measurement is limited. The experimental example is given to verify the proposed model and the measurement results prove the correctness and effectiveness of it.     

基于LabVIEW的小波去噪算法的研究

近年来,小波理论得到了迅速的发展。小波分析是目前国际公认的信号信息获取与处理领域的高新技术,是多学科关注的热点,是信号处理的前沿课题。由于小波变换具有低熵性、多分辨性、去相关性、选基灵活性等特性,使它成为在信号去噪领域内的有力工具。本文应用小波变换算法,并将其结合LabVIEW虚拟仪器开发平台、MATLAB中小波去噪工具箱的小波去噪函数进行仿真,用模拟信号验证了其去噪算法的有效性。     

Nanostructured Metal Chalcogenides for Energy Storage and Electrocatalysis

Energy storage and conversion technologies are vital to the efficient utilization of sustainable renewable energy sources. Rechargeable lithium‐ion batteries (LIBs) and the emerging sodium‐ion batteries (SIBs) are considered as two of the most promising energy storage devices, and electrocatalysis processes play critical roles in energy conversion techniques that achieve mutual transformation between renewable electricity and chemical energies. It has been demonstrated that nanostructured metal chalcogenides including metal sulfides and metal selenides show great potential for efficient energy storage and conversion due to their unique physicochemical properties. In this feature article, the recent research progress on nanostructured metal sulfides and metal selenides for application in SIBs/LIBs and hydrogen/oxygen electrocatalysis (hydrogen evolution reaction, oxygen evolution reaction, and oxygen reduction reaction) is summarized and discussed. The corresponding electrochemical mechanisms, critical issues, and effective strategies towards performance improvement are presented. Finally, the remaining challenges and perspectives for the future development of metal chalcogenides in the energy research field are proposed.     

Solid-State Reaction Mechanism and Deliquescence Phenomenon of K<Subscript>0.5</Subscript>Na<Subscript>0.5</Subscript>Nb<Subscript>0.7</Subscript>Al<Subscript>0.3</Subscript>O<Subscript>3</Subscript> Ceramic

Development of (K,Na)NbO₃-based ceramics has attracted much attention in recent decades. In this work, K_0.5Na_0.5Nb_0.7Al_0.3O₃ ceramic was prepared using conventional solid-state processing. A deliquescence phenomenon was observed when the specimen was exposed to moist atmosphere. The reaction mechanism and cause of deliquescence were investigated using x-ray diffraction analysis, scanning electron microscopy, energy-dispersive spectrometry, electron microprobe analysis, inductively coupled plasma mass spectrometry, and thermogravimetric/differential scanning calorimetric analysis. The results revealed interactions mainly amongst the raw materials K₂CO₃, Na₂CO₃, and Nb₂O₅ as well as K₂CO₃, Na₂CO₃, and Al₂O₃, which can influence the sintering behavior of the mixture. (K,Na)NbO₃ and (K,Na)AlO₂ were present in the sintered K_0.5Na_0.5Nb_0.7Al_0.3O₃ ceramic, with the latter leading to deliquescence. During the sintering process, Al₂O₃ reacts with alkali oxides (Na₂O and K₂O), which are the decomposition products of carbonates, to form (K,Na)AlO₂. In addition, Al₂O₃ is more likely to react with K₂O compared with Na₂O.     

抑制广播风暴对EPA确定性调度的影响

以太网由于采用CSMA/CD（载波侦听多路访问/冲突检测）介质访问控制机制,因此具有通信＂不确定性＂的特点,网络设备间通信时会出现乱序、丢包、数据冲突等不确定性问题,本文对EPA以太网确定性调度实现方法进行研究,提出抑制广播风暴的方法,并采用白噪声法对网络系统确定性调度进行仿真,仿真结果表明采用改进方法后系统的确定性得到了提高。     

Surface morphology of [110] a-plane GaN growth by MOCVD on [1■02] r-plane sapphire

Nonpolar a-plane [110] GaN has been grown on r-plane [1■02] sapphire by MOCVD, and investigated by high resolution X-ray diffraction and atomic force microscopy. As opposed to the c-direction, this particular orientation is non-polar, and it avoids polarization charge, the associated screening charge and the consequent band bending. Both low-temperature GaN buffer and high-temperature AlN buffer are used for a-plane GaN growth on r-plane sapphire, and the triangular pits and pleat morphology come forth with different buffers, the possible reasons for which are discussed. The triangular and pleat direction are also investigated. A novel modulate buffer is used for a-plane GaN growth on r-plane sapphire, and with this technique, the crystal quality has been greatly improved.