Catalytic partial oxidation of methane to synthesis gas in a ceramic membrane reactor

Methane has been selectively converted to synthesis gas using a two-zone fixed bed of a Ni/Al₂O₃ catalyst inside a modified ceramic membrane. The first zone of the reactor was surrounded by an impervious wall, and therefore behaved as a conventional fixed bed reactor. In the second zone, some of the reaction products could preferentially diffuse out of the reactor, which yielded higher than equilibrium methane conversions. The influence of the different operating conditions has been studied, and the performance of the membrane reactor has been compared to that of a fixed bed reactor. The membrane reactor has also been used at pressures above atmospheric (2 bar), with good conversions and selectivities.     

大孔树脂分离纯化商陆红色素的研究

研究了几种大孔吸附树脂和离子交换树脂对商陆红色素的静态吸附特性,筛选出一种吸附性能较好的树脂,并应用柱层析进行商陆红色素的分离纯化研究。实验结果表明:D301离子交换树脂对商陆红色素的静态吸附率达到96.0%,柱层析吸附饱和后用0.15 mol/L HCl洗脱时,洗脱率达到92.8%,洗脱液经低温干燥得到的商陆红色素色价达到45.9。     

P2O5含量对Al2O3-SiO2-P2O5系统玻璃结构和析晶性能的影响

采用高温熔融冷淬法制备Al2O3-SiO2-P2O(5ASP)系统玻璃,用原位晶化法获得了磷酸盐微晶玻璃;用IR、DSC、XRD、SEM等测试方法表征了玻璃结构及析晶性能,讨论了P2O5含量对ASP玻璃结构和析晶性能的影响。结果表明:P2O5含量在35～50%能形成稳定的ASP玻璃。在磷含量较低时,玻璃结构中的P5 主要以不含P=O双键的[PO4]四面体形式存在,P2O5含量较高时,结构中的P-O-键削弱,P=O双键加强,P5 部分以含P=O双键的[PO4]四面体形式存在。随着P2O5含量的增加,玻璃稳定性变差,析晶趋势增强;晶化后的玻璃以AlPO4为主晶相,同时含有少量的Al(PO)3晶相,当晶化温度由650℃升高到800℃时,晶相含量增加并出现YPO4晶相。     

Mn2+、Nb5+共掺BaTiO3陶瓷的制备及压电性能的研究

本文采用改进的固相反应法,制备了施主杂质Nb5 和受主杂质Mn2 共掺的BaTiO3陶瓷。按不同Nb5 、Mn2 的掺杂量,分别在1180℃、1210℃、1250℃、1280℃温度下煅烧。实验结果表明:当烧结温度为1250℃、掺杂量为0.05mol%时,制得的试样性能较好。     

POE-g-MAH及其在增韧尼龙6中的应用

利用熔融接枝法制备了马来酸酐接枝乙烯-辛烯共聚物（POE-g—MAH），探讨了各个因素对POE-g—MAH接枝率和熔体流动速率（MFR）的影响，并得出了最佳配方、最佳工艺条件。将POE与接枝产物POE-g—MAH同时作为弹性体改性PA6时，体系的缺口冲击强度较纯尼龙提高近9倍，而其他力学性能改变不大。     

AIN陶瓷烧结技术研究进展

氮化铝（AIN）因其具有高热导率，作为基片材料在电子元器件中得到日益重视。本文主要论述了氮化铝陶瓷制备过程中各种烧结参数，包括烧结助剂、烧结气氛、保温时间、常压烧结、热压烧结、微波烧结和等离子烧结等对氮化铝陶瓷性能的影响。并指出可通过合适的AIN粉体制备技术，结合快速烧结方法可得到具有晶粒细小、结构均匀、高致密度和高导热率的AIN陶瓷。     

端氨基聚脲聚氨酯环氧树脂体系的固化反应及粘接性能

本文采用DTA和FT-IR研究了端氨基聚脲聚氨酯固化环氧树脂的反应特性,考察了被粘表面状态、偶联剂和促进剂、填料等对剪切强度性能的影响。并对该粘合剂耐化学腐蚀性进行了试验,说明具有好的耐腐蚀性。     

大直径浅圆仓缩尺模型试验研究

大直径浅圆仓在生产过程中,由于仓底的偏心卸料使筒仓仓壁产生不均受力,会给筒仓结构的使用带来安全隐患。通过对浅圆仓缩尺模型试验,模拟筒仓生产过程的卸料状况,并对筒仓仓壁及仓底廊道顶部进行压力测试,将测试结果与理论计算进行对比,从而得出偏心卸料与静载状态的超压系数,为大直径浅圆仓设计提供依据。     

基于高密度电阻率法的露天铁矿采空区探测的研究

露天铁矿开采区地下浅部大量采空区的存在,给矿山的人员及生产安全带来极大的威胁。为保证生产活动的顺利进行,必须对采空区进行精确探测。由于高密度电阻率法较常规电法具有信息丰富、精度高的特点,运用该法对露天铁矿采空区进行探测,结合数据反演断面图,在地下50m的范围内,共划定采空区四处,并精确划定采空区顶底板深度、水平范围和展布方向,为矿山的治理工作提供了可靠依据。并且在分析采集数据的基础上,总结出视电阻率识别模型及其主要特点,为地下采空区的划定提供了理论基础。     

Approximate K-Median of Location Streams with Redundancy and Inconsistency

Data streams produced by positioning systems such as Global Positioning System (GPS) or RFID readers can be considered as location streams[12]. Location streams are usually generated in a distributed fashion by a large scale distributed system covering a wide range of areas. Computing on distributed location streams is both practically useful and theoretically challenging. The results of computation could be used to schedule the traffic in a metropolis to avoid traffic jam, dispatch taxis to serve the passengers more quickly and display the current position of goods in supply chain management, etc. Since location streams are usually generated with very high rate in uncertain ways over hostile environments, the collected updates of location are probably redundant and inconsistent in a wide positioning system. To process distributed location streams with redundancy and inconsistency, this paper proposes a novel method based on min-wise hash. With this method, redundant updates of distributed location streams can be effiectively filtered out, while the true location could be derived from inconsistent ones. Consequently, globally uniform samples can be obtained. Based on the uniform samples, an algorithm for computing the approximate k-median of huge number of moving objects is presented in this paper. Furthermore, it is demonstrated that sketch-based methods are not necessarily effiective in processing location streams with redundancy and inconsistency. In addition to theoretical analysis, some extensive experiments are conducted to validate the efficiency and effiectiveness of the proposed approach.