基本形及其在概念交通工具创意草图设计中的运用

概念交通工具造型创新是形态创新的过程,创意草图是形态推演的常用手段。在了解基本形概念、形体组合方式的基础上,结合造型形态的设计原则,对基本形的绘制原则和方法进行分析。通过案例的设计应用,阐述了基本形的抽象性、发散性与概念交通工具造型设计具有适应性和可应用性,为概念交通工具创意草图设计提供了较为可行的方法。     

离子液体改性花生壳对铬离子的吸附行为与机制

研究了用离子液体改性花生壳,并考察了改性花生壳对Cr(Ⅵ)的吸附行为与机制.结果表明:在改性花生壳用量10 g/L、温度50℃、初始Cr(Ⅵ)质量浓度10 mg/L条件下,改性花生壳对Cr(Ⅵ)的吸附率达99.82％;吸附过程符合Langmuir等温吸附模型,为单分子层吸附,吸附发生在均匀的吸附点位上,理论最大吸附量qm=9.70 mg/g;RL=0.221<1,表明吸附过程为优惠吸附;吸附过程符合准二级动力学模型,动力学常数k2=0.0452 g/(mg·min),理论平衡吸附量qe=1.14 mg/L,表明吸附过程主要为化学吸附.     

焦家金矿无废矿山建设工程实践

焦家金矿存在尾矿库库容不足,井下采空区难以保证细粒级尾砂全部利用等问题。为缓解排尾压力,实行细粒级尾砂充填、粗粒级尾砂加工销售模式;为增加新的采空区,在井下浅部区域回采低品位矿石,同时增加了金属回收量。实践结果表明,采用废石利用+低品位资源综合利用+尾砂再造及综合利用协同技术生产工艺,实现了焦家金矿无废矿山建设,也为同类矿山实现无废矿山提供了宝贵经验,具有借鉴意义。     

基于FLAC~(3D)的井下采场结构参数优化研究

针对金源矿业公司大直径深孔阶段空场嗣后充填采矿法在实际生产过程中,由于采场跨度过大,回采过程中普遍出现的冒顶、片帮等安全问题,提出了分矿房矿柱的中深孔凿岩阶段空场嗣后充填采矿法;采用岩土工程专用分析软件FLAC3D,经数值模拟分析回采过程,确定合理的采场跨度参数;模拟结果为金源矿业公司J5矿体后续回采整体规划及采场结构参数调整发挥了重要的指导作用,确保了井下生产安全。     

Synthesis and luminescence properties of a novel phosphor Ca2–x/2Si1–xPxO4:Eu2+for near UV-excited white-light-emitting diodes

A novel green-emitting phosphor,Eu2+-doped Ca2-x/2 Si1-x Px O4(0.25≤x≤0.30),was prepared through a conventional solidstate reaction.X-ray diffraction(XRD),photoluminescence(PL) and decay studies were employed to characterize the sample,which was assigned to P63mc space group in the hexagonal system.The effect of P-doping on the α-Ca2 SiO4 was studied and P2 O5 broken down by the raw material of(NH4)2 HPO4 played an important role in stabilizing α-Ca2 SiO4 which can only be stable at high temperature.The XRD patterns of the Ca2-x/2 Si1-x Px O4 host were found pure and optimized when the mole fraction of P2 O5 was 14.5%.The diffuse reflectance spectra of the Ca1.855 Si0.71 P0.29 O4 and Ca1.845 Si0.71 P0.29 O4 :0.01Eu2+covered the spectral region of 230-400 nm,implying that the phosphor was suitable for UV or near-UV LED excitation.The phosphor could be effectively excited in the near UV region with the maximum at 372 nm.The emission spectrum of the Ca1.845 Si0.71 P0.29 O4 :0.01Eu2+phosphor showed an asymmetrical single intensive band centered at 513 nm,which corresponded to the 4f65d1→4f7transition of Eu2+.Eu2+ions might occupy two types of Ca2+sites in the Ca1.855 Si0.71 P0.29 O4 lattice and form two corresponding emission centers,which led to the asymmetrical emission of Eu2+in Ca1.855 Si0.71 P0.29 O4.The effects of Eu2+-doped concentration in Ca1.855-x Si0.71 P0.29 O4 :xEu2+on the PL were also discussed,the optimum doping concentration of Eu2+was 1 mol.% and the critical distance of the energy transfer was also calculated by the concentration-quenching method.The non-radiative energy transfer between Eu2+seemed to be caused by the multipole-multipole interaction.The fluorescence lifetime of Eu2+was found to be 0.55711 μs.The results suggested that these phosphors might be promising candidates used for near UV light excited white LEDs.     

结构面岩体爆破破坏机理探究

岩体多属于各向异性的复杂不连续体。岩体中主要结构面在爆破时,会对岩石的破坏和最终的爆破效果产生影响。总结了结构面岩体爆破破坏机理的研究现状,并从应力波传播、岩体破坏方式等方面研究了结构面岩体爆破的影响。在研究结构面岩体爆破破坏作用机理的基础上,提出改善爆破效果的技术措施,供同类型矿山参考。     

基于未确知测度理论的采空区稳定性分级

针对采空区复杂性和不确定性的特点,以未确知测度理论为依据,对采空区稳定性进行分级。确定了14项影响因子作为采空区稳定性的评判标准,并建立采空区稳定性评价体系。根据矿山真实数据建立不同因素的未确知测度函数,通过熵计算各影响因素的指标权重,结合置信度识别准确对采空区进行稳定性划分,为采空区治理提供理论依据。将该方法应用于玲珑金矿西山矿区25个采空区的稳定性分析,划分出1个Ι级空区,12个Ⅱ级空区,11个Ⅲ级空区以及1个Ⅳ级空区。研究结果表明,未确知测度理论科学可靠,能够较准确地分析采空区的稳定性,可以在矿山实际生产中推广应用。     

基于Excel VBA编程的SolidWorks零件参数化设计

结合Excel表格的处理能力和Solid Works实体造型功能,实现对非标零件的参数化设计。以涂装行业喷漆室某侧板为例,重点介绍了用VBA编程进行参数化设计的优势、过程和基本代码。研究结果表明,此方法实现了零件的自动生成,提高了生产和工作效率,减少了出错率。     

钠过量对铌酸钾钠基陶瓷结构及性能的影响

用常规氧化物固溶法制备了(Na0.520+xK0.480)0.915Li0.085NbO3(x=0～0.025)无铅压电陶瓷,研究了过量Na的掺杂量对其烧结温度、微观结构及压电性能的影响。结果表明,过量Na掺杂在烧结过程中促进液相的产生,导致样品烧结温度显著降低。室温下样品均为四方结构。随x的增加,样品的斜方-四方相变温度tO-T趋向低温。当x从0.010增大到0.025时,Qm从131提高到238,tanδ和d33分别从0.034和125pC/N下降至0.012和105pC/N,表明过量Na实际上起到了"硬性掺杂"的作用。