Complex impedance analysis of (Y2O3 + CeO2)-YCr0.5Mn0.5O3 composite NTC ceramics

Ceramic compositions based on (aY₂O₃ + bCeO₂)-0.4YCr_0.5Mn_0.5O₃ (a + b = 0.6) were prepared by conventional solid state reaction at 1200 °C, and sintered under air atmosphere at 1600 °C. For 0 ≤ a < 0.6, XRD patterns have shown that the major phases presented in the calcined powders are Y₂O₃, CeO₂ and orthorhombic perovskite YCr_0.5Mn_0.5O₃ phase, respectively. SEM and EDAX observations confirm the YCr_0.5Mn_0.5O₃ phases mostly exist at the grain, whereas the Y₂O₃ and CeO₂ phases mainly exist at the grain boundaries. Complex impedance analysis shows that, for 0 < a ≤ 0.6, single semicircular arc whose shape does not show any change with temperature. Nevertheless, for a = 0, two overlapping semicircular arcs are observed at and above 300 °C. The grain boundary properties exhibit thermistor parameters with a negative temperature coefficient characteristic. The relaxation behavior and conduction for the grain boundary could be due to a space-charge relaxation mechanism and oxygen vacancies, respectively.     

深层QPQ工艺参数对3Cr13钢渗层组织的影响

选用3Cr13马氏体不锈钢作为实验材料,利用深层QPQ盐浴复合处理处理技术,研究氮化温度、氮化时间和氰酸根浓度对QPQ复合处理后的渗层组织的影响.运用显微硬度计检测渗层的厚度和显微硬度值的变化,运用金相显微镜观察氮化后试样渗层的显微组织,检测化合物层的厚度和质量.结果表明:随氮化温度的升高或氮化时间的延长渗层深度增加;经630℃×2h氮化可形成深度高达97 μm的渗层组织;随氮化温度的升高,试样的表面硬度值在600℃后呈下降趋势,有疏松层的形成;氰酸根浓度对渗层的厚度影响显著,特别体现在扩散层的厚度上.而对试样表面硬度影响很小.     

毛细滴管计滴法测定水中氯离子含量

以自制的液滴体积为0.01-0.02 mL的聚乙烯毛细滴管对水中氯离子含量进行数滴分析,其主要仪器外形小巧、便于携带,滴定快速、准确,试剂消耗量约为常量法的5%,滴定剂用量约为20～100滴,氯离子含量不确定度Urel(C)为3.03%,比常量法略小,相对标准偏差与常量法的相当.该法克服了常量法中滴定管、移液管、铁架台和蝴蝶夹等仪器携带不方便的不足.适用于水中氯离子含量的快速分析.     

3-氨基吡唑-4-甲酰胺半硫酸盐的合成

以原甲酸三乙酯、丙二腈为起始原料,合成乙氧亚甲基丙二腈,将其加入80％水合肼中,加热回流1h,生成3-氨基-4-甲酰胺吡唑,将其与浓硫酸混和,调节pH值,40℃下搅拌0．5h,经过滤,重结晶,得到目标化合物3-氨基吡唑-4-甲酰胺半硫酸盐,总收率63．7％（以丙二腈计）。目标化合物结构经红外光谱、核磁共振分析验证。     

腐植酸类物质对温室黄瓜根际植物线虫数量的影响

本研究旨在明确3种腐植酸类物质(NaFA、KFA、CFA)及与新药肥(SY)复配物对温室黄瓜根际植物线虫数量是否有抑制作用.研究结果表明:(1)矮化线虫属Tylenchorhynchus和根结线虫属Meloidogyne是2种主要的植物线虫,(2)随着生长季后期植物线虫数量的迅速增长,5种腐植酸类物质(CFA、NaFA、KFA、OFA SY、NaFA SY)及SY防治区矮化线虫和根结线虫数量低于对照区,(3)CFA与新药肥SY复配效果强于OFA和SY的单一作用效果.     

邻甲酚中试含酚废水处理研究

采用蒸馏和萃取法对邻甲酚合成中含酚废水进行处理。实验结果表明：废水中甲醇的去除率９８．８％,酚的去除率９９．４％。     

基于谐波小波包和BSA优化LS-SVM的铣刀磨损状态识别研究

针对铣削刀具磨损状态识别问题,提出谐波小波包和最小二乘支持向量机（LS-SVM）的状态识别方法。为克服传统小波包分解的频带交叠问题,采用谐波小波包提取不同磨损状态下铣削力信号的各频段信号能量,归一化处理后,输入LS-SVM多类分类器,实现铣削刀具磨损状态的识别。针对LS-SVM的惩罚因子和核参数对模型识别精度影响较大的问题,提出回溯搜索算法（BSA）进行自动参数寻优。实验结果表明,谐波小波包比小波包在刀具磨损状态特征提取时具有更好的识别效果。与粒子群算法进行比较,证明BSA优化LS-SVM具有更高的识别精度。     

2,6-二异丙基苯胺的制备

研究了以苯胺铝为催化剂,苯胺与丙烯为原料高压液相烷基化法合成２,６ 二异丙基苯胺的过程。实验选择的优惠条件为：反应温度２８０～２９０℃;原料配比（ｍｏｌ）,苯胺∶丙烯＝１∶２;反应时间１～５ｈ。在此条件下,苯胺转化率＞８０％,２,６ 二异丙基苯胺选择性＞５０％。     

Freeze-drying and mechanical redispersion of aqueous PEDOT:PSS

Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films are attracting famous applications in antistatic coating, energy storage and conversion, printed electronics, and biomedical fields due to their conductivity, optical transparency and flexibility. However, PEDOT:PSS has poor dispersion stability during long-term storage and transport. Moreover, the dried PEDOT:PSS films are insoluble in any solvent and cannot be redispersed again. In comparison to bake drying, here, a feasible strategy to achieve mechanically redispersed PEDOT:PSS with the help of freeze-drying process was reported. The redispersed PEDOT:PSS can recover not only the initial characters such as pH, chemical composition, viscosity, and particle size under similar solid contents, but also conductivity and surface morphology of treated films. In addition, the treated film exhibits self-healing properties similar to pristine film in terms of mechanical and electrical properties. This technology enables reuse and overcomes the technical problems of PEDOT:PSS dispersion, realizing real-time processing to meet variable applications.     

正弦变载荷工况下液压泵振动信号的形态学滤波方法

液压泵的振动信号在受到大幅度变载荷作用时将引起振动特征的变化,特别是在正弦载荷变化的作用下,将会产生幅值调制现象。采用传统的单一尺度结构元素的形态学方法对该类信号进行滤波的效果不一定理想。因此,针对正弦载荷液压泵振动信号的特点,在单尺度形态滤波分析方法的基础上,提出了兼顾形态学结构元素长度和高度尺度的多尺度形态学滤波方法。首先,以冲击特征比值和二阶原点矩作为评价指标,提出综合考虑结构元素长度和高度尺度的寻优方法,确定最优长度和高度尺度算子组合。然后,用最优尺度组合对正弦载荷模拟仿真信号和变载荷液压泵故障振动信号进行滤波处理,分析结果证实其滤波效果优于单尺度滤波方法滤波效果。