双酚AF型聚碳酸酯的制备与性能

以三光气和双酚AF为原料,采用界面缩聚法合成双酚AF型聚碳酸酯,得到最佳的聚合条件为：三光气和双酚AF的物质的量之比为1.3∶3,催化剂三乙胺的用量为双酚AF质量的4%,反应温度为35℃,反应时间为60 min。通过傅里叶变换红外吸收光谱、乌氏黏度计、同步热分析仪、热变形/维卡软化温度测试仪及极限氧指数测定仪对制备样品进行了结构和性能表征,结果表明,制备样品为双酚AF型聚碳酸酯,样品的黏均分子量为32000。玻璃化转变温度为164.3℃,热失重5%的温度为440.8℃,热变形温度为149℃、维卡软化温度为157℃,具有较好的耐热性能;极限氧指数为29.5%,具有较好的阻燃性能。样品经碱溶液浸泡后质量损失率较小,耐碱腐蚀性能较好。样品在很多有机溶剂中都有很好的的溶解性。     

Rational design on photoelectrodes and devices to boost photoelectrochemical performance of solar-driven water splitting: a mini review

As an eco-friendly, efficient, and low-cost technique, photoelectrochemical water splitting has attracted growing interest in the production of clean and sustainable hydrogen by the conversion of abundant solar energy. In the photoelectrochemical system, the photoelectrode plays a vital role in absorbing the energy of sunlight to trigger the water splitting process and the overall efficiency depends largely on the integration and design of photoelectrochemical devices. In recent years, the optimization of photoelectrodes and photoelectrochemical devices to achieve highly efficient hydrogen production has been extensively investigated. In this paper, a concise review of recent advances in the modification of nanostructured photoelectrodes and the design of photoelectrochemical devices is presented. Meanwhile, the general principles of structural and morphological factors in altering the photoelectrochemical performance of photoelectrodes are discussed. Furthermore, the performance indicators and first principles to describe the behaviors of charge carriers are analyzed, which will be of profound guiding significance to increasing the overall efficiency of the photoelectrochemical water splitting system. Finally, current challenges and prospects for an in-depth understanding of reaction mechanisms using advanced characterization technologies and potential strategies for developing novel photoelectrodes and advanced photoelectrochemical water splitting devices are demonstrated.     

低温高磁感取向硅钢热轧板通电加热织构研究

通过对低温高磁感取向硅钢热轧板通电加热处理,发现将热轧板以55℃/s从室温加热到1 000℃后降温,在1 000～950℃降温过程中保持时间2～5 s,可以获得与常化工艺等效的热轧板织构组分,根据所得结果,讨论了在热轧轧机后段增加电加热装置,从而代替常化工艺生产高磁感取向硅钢的可能性.     

固体碱催化法合成壬基酚甲醛树脂的工艺研究

本文研究了以壬基酚和甲醛为原料,固体碱为催化剂,合成壬基酚醛树脂的新工艺。对酚醛比、催化剂用量、反应时间、反应温度四个影响因素进行了正交优化实验,确定了优化合成工艺,得到了黏度为20000 mPa·s左右的壬基酚醛树脂,该工艺稳定可靠。     

浅析智能阀门定位器在控制阀上的应用

介绍Fisher公司生产的DVC6000系列智能阀门定位器的功能特点、维护要点及应用智能阀门定位器在线处理调节阀故障.改善了调节阀的工作特性,提高了调节阀的调节性能.     

Lignin-based Hydrogels for Biological Application

Lignin is the most abundant aromatic compound found in nature.The rich functional groups of lignin are responsible for its antibacterial,antioxidant, anti-ultraviolet, and biocompatible properties. As modified lignin has a higher molecular weight, water solubility, and better surface activity, it is a good candidate for the construction of new biological materials. Ligninbased hydrogels are a type of functional materials with broad application prospects in the biomedical field. This review aimed...     

某含锌锡多金属硫化矿石锌浮选试验研究

某含锌锡多金属硫化矿石Zn、Sn、Fe、S含量分别为6.04%、1.05%、29.33%、19.08%,锌主要以铁闪锌矿、闪锌矿的形式存在,锡主要以锡石的形式存在,铁主要以黄铁矿、磁黄铁矿等形式存在,其中的金属矿物共生关系密切,相互包裹现象普遍。为确保不影响后续选锡,对锌浮选流程进行了试验研究。结果表明：矿石在磨矿细度为-0.074 mm占80%的情况下,采用预先脱硫—锌硫混浮再分离流程处理,在选择硫酸铜为锌矿物活化剂、丁基黄药为捕收剂、松醇油为起泡剂、石灰为黄铁矿抑制剂的情况下,经1段脱硫、2粗1扫锌硫混浮、1粗2精锌硫分离,锌硫分离精选尾矿与锌硫混浮扫选精矿2次精选后锌硫分离,最终获得锌精矿Zn品位47.06%、回收率90.76%,试验指标良好。     

Discovery and characterization of tyrosinases from sea anemone pedal disc

Abstract

The formation of underwater adhesion is a complicated physiological process and many different types of enzymes are found to be essential apart from structural proteins. Previous studies have shown that various tyrosinases were present in marine adhesives, but little information is available about the over-expression and enzymatic characterization of these enzymes. Specifically, this study first identified four significantly up-regulated tyrosinases in the pedal disc of Haliplanella luciae by means of multi-omics technology, and made preliminary bioinformatics predictions. Sequence alignment showed that the Tyr1_Hl contained six conserved His residues that bind to copper ions, of which a tyrosinase with diphenolase activity named as Tyr1_Hl^Δ, was expressed in Escherichia coli BL21 (DE3) cells and purified by affinity chromatography. Enzymatic characterization showed that the activity of Tyr1_Hl^Δ was Cu²⁺ dependent and maximum catalytic activities were in 20?mM Tris–HCl (pH 8.0) at 37?°C. In summary, we identified novel tyrosinases in the pedal disks of sea anemone for the first time and the Tyr1_Hl^Δ was successfully recombinant expressed. Our study will provide basis for future exploration of bio-adhesion mechanism and design of bio-adhesives derived from sea anemones.     

基于遗传算法与BP神经网络的支架跟机自动化研究

针对综采工作面液压支架跟机自动化过程中移架动作存在的丢架、推移不到位等问题,提出了基于遗传算法(GA)与BP神经网络组合模型的控制方法。通过建立BP神经网络控制器为主体的反馈控制,将支架的运动参数输入模型,神经网络控制器计算实际输出与理想输出之间误差,判别是否需要回调控制,并添加遗传算法来优化更新模型的各层阈值和权值,从而得到网络模型的最优解,最终由执行部分来完成输出动作。组合网络模型具有良好的非线性特性,可以更好的满足非线性环境,利用神经网络的预测值与实际输出的差值来得到拟合曲线。通过对BP神经网络模型、GA模型、GA-BP组合模型的均方误差(MSE)分析,判断出GA-BP组合模型具有更快的训练速度和更高的预测准确率。相比较于单一的BP神经网络模型和GA模型,GA-BP组合模型可以很大程度地提高液压支架跟机过程中的推移精度,从而更好地适应综采工作面的环境和设备变化。基于对模型稳定性的分析,绘制组合网络的适应度曲线,种群在第5次迭代后趋于收敛,在第5次到第15次迭代的适应度值就已基本达到稳定,在迭代第15次后种群已达到最优参数集且恒定不变。采用上述方案的液压支架电液控制系统能够自主感知设备各项运动参数的变化,实现支架自身的静态调整和动态演化,可为综采工作面无人化建设提供技术支撑。