Aktuelle Aktivitäten zu den europäischen Rohstoff-Initiativen

The European Initiatives manifested in the Communications of the European Commission on Raw Materials, in the Strategic Implementation Plan of the European Innovation Partnership on Raw Materials and in the 2014 Call of the European Institute for Innovation & Technology (EIT) for a Knowledge and Innovation Community (KIC) on Raw Materials lead to manifold Austrian activities on Government level and on level of the Montanuniversitaet Leoben. The ESEE Region, thus East- and Southeast Europe has a special role.     

Precueing spatial S-R correspondence: Is there regulation of expected response conflict?

Four experiments investigated the ability to prepare for the level of forthcoming stimulus-response correspondence in choice-response tasks. In a Simon task, participants responded to the color of spatially variable stimuli with spatially variable responses. Participants were given advance information about whether a forthcoming stimulus-response event would be spatially corresponding, neutral, or spatially noncorresponding. Reliable cues decreased reaction times (RTs) in the corresponding conditions of 2- and 3-choice tasks, decreased RTs in noncorresponding conditions of a 2-choice task but not in a 3-choice task, and left RTs in neutral conditions unaffected. The pattern of results suggests that participants used reliable cues for responding to the nominally irrelevant stimulus location if the correct response could be inferred from location (attention switching). By contrast, the lack of cueing effects on performance in noncorresponding conditions of 3-choice tasks suggests that participants cannot use cues for changing the attentional weights of processing channels for different stimulus dimensions (gating). In summary, gating may be involved in the regulation of experienced response conflict, but the present results suggest that it is not involved in the regulation of expected (i.e., predicted) response conflict. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

High-temperature liquid chromatography coupled on-line to a continuous-flow biochemical screening assay with electrospray ionization mass spectrometric detection

The potential of high-temperature liquid chromatography (HTLC) was investigated in an on-line combination with a screening system for bioactive compounds against the enzyme cathepsin B. Samples were separated by HTLC and subsequently analyzed by an on-line continuous-flow enzymatic assay. Detection was performed by electrospray ionization mass spectrometry, revealing both the bioactivity and the molecular mass of the bioactive compounds. Compared to conventional reversed-phase liquid chromatography, the amount of methanol necessary for separation could be decreased to only 10%, which improved the compatibility of LC with a biochemical assay. Sufficient preheating of the mobile phase prior to the separation and postcolumn cooling to prevent deactivation of the enzyme, even at column temperatures as high as 208 degrees C, was achieved as indicated by the reliable peak shapes obtained. The sensitivity was comparable with previously described systems operating at ambient temperatures as similar IC50 values were obtained. Exposing the inhibitors to high temperatures did not lead to thermal decomposition. The separation of inhibitors and the subsequent biochemical assay was performed either isothermally at various temperatures or by applying various temperature gradients as well as at various flow rates. The results obtained clearly show the compatibility of HTLC with an enzymatic screening assay.     

Continued fraction for formal laurent series and the lattice structure of sequences

Besides equidistribution properties and statistical independence the lattice profile, a generalized version of Marsaglia's lattice test, provides another quality measure for pseudorandom sequences over a (finite) field. It turned out that the lattice profile is closely related with the linear complexity profile. In this article we give a survey of several features of the linear complexity profile and the lattice profile, and we utilize relationships to completely describe the lattice profile of a sequence over a finite field in terms of the continued fraction expansion of its generating function. Finally we describe and construct sequences with a certain lattice profile, and introduce a further complexity measure.     

Electrochemical lithiation synthesis of nanoporous materials with superior catalytic and capacitive activity

Nanoporous materials have attracted great technological interest during the past two decades, essentially due to their wide range of applications: they are used as catalysts, molecular sieves, separators and gas sensors as well as for electronic and electrochemical devices. Most syntheses of nanoporous materials reported so far have focused on template-assisted bottom-up processes, including soft templating (chelating agents, surfactants, block copolymers and so on) and hard templating (porous alumina, carbon nanotubes and nanoporous materials) methods. Here, we exploit a mechanism implicitly occurring in lithium batteries at deep discharge to develop it into a room-temperature template-free method of wide applicability in the synthesis of not only transition metals but also metal oxides with large surface area and pronounced nanoporosity associated with unprecedented properties. The power of this top-down method is demonstrated by the synthesis of nanoporous Pt and RuO2, both exhibiting superior performance: the Pt prepared shows outstanding properties when used as an electrocatalyst for methanol oxidation, and the RuO2, when used as a supercapacitor electrode material, exhibits a distinctly better performance than that previously reported for non-hydrated RuO2 (refs 19,20).     

Statisches und dynamisches Werkzeugverhalten beim Innenrundschleifen mit axial vorgespannten Werkzeugen

Zusammenfassung Die in diesem Beitrag vorgestellten theoretischen Betrachtungen zum statischen und dynamischen Werkzeugverhalten beim Innenrundschleifen langer Bohrungen nach dem ILB-Verfahren haben wichtige Hinweise für das Proze?verhalten ergeben. Durch geeignete Modellbildung kann hiermit der Einflu? unterschiedlicher Werkzeugspezifikationen sowohl auf die statische Nachgiebigkeit der Werkzeuge und damit letztendlich auf den L?ngsformfehler am Bauteil als auch auf das dynamische Verhalten, insbesondere das Auftreten kritischer Resonanzfrequenzen, vorherbestimmt werden. Die analytischen Berechnungen konnten durch praktische Untersuchungen verfiziert werden. Durchgeführte Schleifversuche haben die Eignung des ILB-Verfahrens als Alternative zur konventionellen Innenrundbearbeitung langer Bohrungen in keramischen Bauteilen best?tigt. Zukünftige Untersuchungen am IFW werden sich auch mit dem Innenrundschleifen langer Bohrungen in Bauteilen aus Hartmetall und geh?rtetem Stahl befassen. Dipl.-Ing.W. Buchholz und Dipl.-Ing.U. Wasmann, wissenschafliche Mitarbeiter des IFW.     

Analysis of debonding fracture in a sandwich plate with hexagonal core

In lightweight applications (as, e.g., aerospace structures) sandwich constructions are very useful and common due to their superior specific bending stiffness and bending strength. In many cases the sandwich consists of an upper and lower laminate facesheet and an intermediate hexagonal cellular aluminum core. Along their interfaces the facesheets and the core are glued together. In order to ensure structural integrity, the facesheet/core bonding is of particular interest. Finite element method has been used to study the cause and the effects of debonding phenomena in between the facesheet and the core of a sandwich plate under in-plane loading. A “unit cell” approach has been followed throughout the study. It has been observed that under an applied in-plane loading, there is a significant stress concentration at the junction of three cell walls and facesheet which easily leads to the generation of cracks and their growth. In order to judge about the tendency of crack initiation and growth, hypothetical interface cracks have been considered and analyzed by fracture mechanics technique. In doing so for various crack length, the energy release rate has been calculated and assessed by means of Irwin’s crack closure integral for a number of different situations. It has been observed that there is a significant amount of energy release rate even in the case of a very small or virtually no crack. This phenomenon indicates that the glue used to attach the facesheet and the cell must withstand a non-zero energy release rate even in the intact situation without any debonding.     

On-line coupling of high-performance liquid chromatography to a continuous-flow enzyme assay based on electrospray ionization mass spectrometry

Liquid chromatography (LC) was coupled on-line to a continuous-flow enzymatic assay using electrospray ionization mass spectrometry (ESI-MS) as readout for the screening of enzyme inhibitors in complex samples. Inhibitors were detected by changes in the concentration of the enzymatic reaction products, indicating the inhibition of enzymatic activity. The molecular masses of the inhibitors were determined with high certainty by using retention time matching and peak shape comparison. Due to the high matching accuracy, baseline separation of coeluting analytes was not necessary in order to identify the correct masses of the bioactive compounds. The continuous-flow system was successfully applied for the screening of complex samples, such as natural extracts. For a red clover extract, detection limits of 0.3-0.8 micromol/L were obtained. System validation was performed by determining the IC(50) values of four inhibitors in the flow-injection mode. The IC(50) values were in the 0.11-5.6 micromol/L range and correspond closely to data obtained by microtiter plate assays. Detection limits were in the range of 0.018-0.35 micromol/L in the flow-injection mode, and 0.075-0.75 micromol/L in the LC mode. These values are well below the typical compound concentrations (1-10 micromol/L) used in high-throughput screening. Together with an interday precision of 12.6%, these results demonstrate the applicability of the system for bioactivity screening of complex mixtures, generating both chemical and biological information on bioactive compounds in a single run.     

Effective stiffness and microscopic deformation of an orthotropic plate containing arbitrary holes

Many engineering materials and structures, such as cellular structures, sandwich core structures and laminated plates with holes, can be modeled by an inclusion problem with anisotropic matrix. The paper studies the effective properties and the microscopic deformation of anisotropic plates with periodic holes by using direct and mathematical homogenization. The effective stiffnesses are calculated by different homogenization methods and the microscopic deformation of a RVE is modeled by the finite element method for the plate with arbitrarily shaped holes. All of the effective stiffness coefficients, especially stretching-shear coupling coefficients are evaluated.     

Zur Verantwortung des Informatikers-Militärische Anwendungen der Informatik

Ohne Zusammenfassung