Selective Oxidation of Propene with Air to Propylene Oxide,a Case Study of Autoxidation Versus Catalytic Oxidation with AMM-Catalysts

The formation of propylene oxide from propene by direct oxidation with air has been studied with a series of new microporous amorphous catalysts containing isolated active sites. Although the materials showed good activities as heterogeneous oxidation catalysts, the formation of acroleine dominated in the gas phase. Oxidation selectivities of the various catalysts are reported. Significant PO-formation was only observed under reaction conditions involving pressures larger 5 bar. Promoting effects of solvents or additives like acetaldehyde could be excluded. Best results were observed in continuous gas phase flow experiments. All catalysts studied proved detrimental to the PO-yield and control experiments pointed to catalyst free autoxidation conditions. A factorial design followed by an optimization of the reaction conditions provided PO-selectivities of 60 % at propene conversion of 11.4 % (T = 290 °C; pressure = 25 bar; propene content = 75 %; total feed = 39.5 ml/min) at continuous reaction conditions. By passivating the inner reactor surfaces with gold, a PO-selectivity of 62.8 % at a propene conversion of 15.1 % could be obtained, indicating, that autoxidation of propene may become a serious contender in the search for improved production processes. This work is a case study of attempted catalyzed selective oxidation with air illustrating potential pitfalls and misleading interpretations.     

Application of a Spectral Element Method to Two-Dimensional Forward-Facing Step Flow

In the present study, we investigate the two-dimensional laminar flow through a one-sided constriction of a plane channel with a ratio of h:H=1:4 (where h is the step height and H is the channel height). The computational approach employed is based on a mixed implicit/explicit time discretization scheme together with a highly accurate spatial discretization using a P _N –P _N–2 spectral-element method. It is well known that this so-called forward-facing step (FFS) flow exhibits a singularity in the pressure and the velocity derivatives at the corner point. We account for this singularity by a geometric mesh refinement strategy that was proposed in a hp-FEM context. A detailed numerical study of the FFS flow reveals that length and height of the recirculation zone in front of the step are almost constant for creeping flow. In the limit of high Reynolds numbers the length and height of the recirculation zone increase proportional to Re ^0.6 and Re ^0.2, respectively.     

Messung des Nachstroms an Hochleistungsschaltern

Ohne ZusammenfassungMit 47 AbbildungenDie vorliegende Arbeit ist ein Auszug aus der Dissertation des Verfassers (Technische Hochschule Aachen 1956/57).     

Urokinase induces proliferation of human ovarian cancer cells: characterization of structural elements required for growth factor function

It has been well established that the cytoskeleton is an essential modulator of cell morphology and motility, intracytoplasmic transport and mitosis, however cytoskeletal linkage to the organelles has not been unequivocally demonstrated. Indeed, cytoskeleton appears to be essential in determining and modulating gene phenotype as a function of cellular environment. According to recent studies, the organization of the cytoskeleton network together with associated protein(s) could be essential in regulating mitochondrial function and particularly the permeability of the mitochondrial outer membrane to ADP. The aim of this chapter is to summarize the main properties of the cytoskeletal environment of mitochondria and the possible role(s) of this network in mitochondrial function in myocytes.     

Callus distraction for lengthening of mid-hand and finger stumps in congenital hand abnormalities--personal results and review of the literature

Distraction-lengthening technique is quite useful in a variety of congenital hand deformities with hypoplastic, or primary normal but secondary shortened (constriction ring syndrome) finger rays. It appears that around the age of two years is the earliest practical time to start distraction; certainly distraction and secondary surgical procedures to improve function should be completed before school entry age whenever possible. Between June 1990 and March 1993, nine distraction lengthening procedures (5 thumbs, 1 index, 3 little fingers) in five patients presenting with congenital hand deformities, were carried out. Although restoring length to the finger, lengthening does not provide normal circumference or, of course, interphalangeal joint motion. Amelioration in function seems to be more important than the esthetic gain. Distraction lengthening tolerates only few errors of indication, operative technique, and/or postoperative management. A high compliance of the patient and her/his parents as well as a close follow-up by an experienced surgeon, are mandatory for a good result. A variety of possible complications have been described. Generally, complication risk increases in cases of simultaneous and multiple level lengthening. Provided adequate operative technique and postoperative care, superficial pin infection and fracture in the region of distraction are the major complications. Contrary to adults, sufficient bone formation by distraction is the rule in children. Therefore, the distraction-lengthening technique is preferred to the distraction-interposition technique in the treatment of congenital hand deformities. The latter should only be used as a salvage procedure in the rare cases of insufficient callus formation. Because of the missing growth potential and reduced joint mobility, distraction lengthening is the therapy of second choice when compared to microvascular second toe transplantation.     

Die Thermokraft von Aluminiumnitrid bei Temperaturen zwischen 1350 und 1650 °C in Argon- und Stickstoffatmosphäre

Beschreibung der Versuchsapparatur zur Messung der Thermospannung der Kette Rh |_{T + Δ} AIN |_T Rh für Temperatur-differenzen bis zu ± 60 °C zwischen 1350 und 1650 °C. Ermittlung der Thermokraft und ihres homogenen Anteils. Berechnung der Überführungswärme der wandernden Ionen aus der homogenen Thermokraft. Erörterung zum Leitungsmechanismus im Aluminiumnitrid AlN.     

Korrosionsforschung in der Bundesanstalt für Materialprüfung (BAM) Berlin Überblick zum hundertsten Jubiläum ihrer Gründung

Corrosion research by Bundesanstalt für Materialprüfung (BAM) in Berlin A memorial review on the occasion of its 100th anniversary The report deals with the develop-ment in the field of corrosion, from the turn of the century to the present day. About 1900 scarcely anybody spoke of corrosion and corrosion protection. Start-ing from this zero point the whole field with its tremendous economic impor-tance has gone through an ever faster evolution. The knowledge concerning the origins of corrosion has been steadily increasing and well-founded. The corro-sion theories could be supported by practical experience and increasing scien-tific knowledge. On the strength of the knowledge on corrosion and the me-chanism of corrosion processes it became possible to develop efficient corrosion protection procedures. lnstitutions such as Materialprüfungsamt, Berlin-Dahlem, Chemisch-Technische Reichsanstalt and Bundesanstalt für Materialprüfung have had an important part in these succes-ses. It can be considered to be a parti-cular recognition of the achievements and merits of the predecessors of the present BAM, that after the merger of the two branches -i. e. materials test-ing and corrosion research -the latter bas been receiving particular attention and efficient support.