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71.
72.
Daniel Grosjean Eric Grosjean II Edwin L. Williams 《Israel journal of chemistry》1994,34(3-4):365-373
The atmospheric oxidation of the unsaturated aldehyde 2-ethyl acrolein, CH2=C(C2H5)CHO, has been studied in laboratory experiments involving the reaction of ozone with 2-ethyl acrolein in the dark (with cyclohexane added to scavenge the hydroxyl radical), and the sunlight irradiation of 2-ethyl acrolein with NO in air. The major carbonyl products of the 2-ethyl acrolein reaction with ozone are formaldehyde, acetaldehyde, and the dicarbonyl ethylglyoxal, CH3CH2COCHO. Sunlight irradiation of 2-ethyl acrolein and NO led to the formation of three carbonyls (formaldehyde, acetaldehyde, and ethylglyoxal) and three peroxyacyl nitrates, (RC(O)OONO2), including PAN (R = CH3), PPN (R = C2H5), and the unsaturated compound EPAN (R = CH2=C(C2H5)). Mechanisms are outlined for the reactions of ozone and of the hydroxyl radical with 2-ethyl acrolein. These mechanisms are consistent with the observed carbonyl and peroxyacyl nitrate products. Thermal decomposition, a major atmospheric removal process for peroxyacyl nitrates, has been studied for EPAN. The decomposition rate of EPAN relative to that of PAN is 0.59–0.73 at 292–294 K and 1 atm of air. Atmospheric implications of these results are discussed. 相似文献
73.
Bernard Williams 《Metal Powder Report》2003,58(10):27-28
With commercially available PIM feedstock reportedly unable to fulfill the requirements for the microPIM components under investigation, researchers at the Institute for Materials Research III (IMR) in Karlsruhe, Germany, have developed new binder systems for feedstock based on both nanoceramic and ultrafine metallic powders. In the case of ceramics (zirconia) the powders can be as fine as 300 nm, and for metals in the 3μm-5μm particle size range. The powders are used to develop PIM gearwheels (Figure 1) and other components for a demonstrator micro annular gear pump design (Figure 2); however, the technology is also said to be applicable to micro gears used in watches. 相似文献
74.
Control laws are often designed for linear time-varying processes by solving the algebraic Riccati equation for the optimum control law at each instant of time. Such designs may be called "adiabatic approximations." Although they are not optimum, they can result in closed loop systems which perform well. The stability of systems designed using the adiabatic approximation can be assessed by the "second method of Lyapunov." Stability is assured if a readily computed test matrixF , which depends on the rate of change of the parameters of the system, is negative-definite. 相似文献
75.
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Many of the targeted applications for powder-metallurgy materials, particularly in the automotive industry, undergo cyclic
loading. It is, therefore, essential to examine the fatigue mechanisms in these materials. The mechanisms of fatigue-crack
initiation and propagation in ferrous powder-metallurgy components have been investigated. The fatigue mechanisms are controlled
primarily by the inherent porosity present in these materials. Since most, if not all, fatigue cracks initiate and propagate
at the specimen surface, surface replication was used to determine the role of surface porosity in relation to fatigue behavior.
Surface replication provides detailed information on both initiation sites and on the propagation path of fatigue cracks.
The effect of microstructural features such as pore size and pore shape, as well as the heterogeneous microstructure on crack
deflection, was examined and is discussed. Fracture surfaces were examined to elucidate a mechanistic understanding of fatigue
processes in these materials. 相似文献
77.
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79.
PA Smanik KY Ryu KS Theil EL Mazzaferri SM Jhiang 《Canadian Metallurgical Quarterly》1997,138(8):3555-3558
The active iodide uptake of the thyroid gland in humans is mediated by the human sodium iodide symporter (hNIS). In this report, we show that hNIS expression was detected primarily in thyroid tissue, but also in breast, colon, and ovary tissues. Expression of hNIS is greatly reduced in thyroid tumors compared to normal thyroid tissue. Among tumor tissues, hNIS expression appears to be variable, consistent with the variable response to radioiodide treatment observed for thyroid carcinomas. The coding region of hNIS is interrupted by 14 introns, and the nucleotide sequence of each exon-intron junction is reported. Using this information, an alternatively spliced form of hNIS was identified. Finally, the chromosome location of the hNIS gene was mapped to chromosome 19p. 相似文献
80.