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11.
Witold Brostow Ligia Gargallo Andrea Hormazabal Magdalena Jaklewicz Kevin P Menard Alejandra Opazo Deodato Radic 《Polymer International》2004,53(4):460-464
We have studied blends of a polymer liquid crystal (PLC) with poly(cyclohexylethyl methacrylate) (PCHEMA) or poly(cyclohexylpropyl methacrylate) (PCHPMA). The PLC is PET/0.6PHB where PET = poly(ethylene terephthalate), PHB = p-hydroxybenzoic acid and 0.6 is the mole fraction of the latter in the copolymer. The microstructure was studied by scanning electron microscopy (SEM). PCHEMA + PLC (20 wt% of the latter, blend E) has a fine texture with LC islands evenly distributed in the matrix and good adhesion between the phases resulting from their partial miscibility. The PCHPMA + PLC (20 wt% of the latter, blend P) shows only limited compatibility. The SEM results are confirmed by values of the glass transition temperatures Tg determined via thermal mechanical analysis. The Tg value of the blend E is shifted towards the Tg of PLC; Tg of blend P is practically equal to that of PCHPMA. The linear isobaric expansivity αL values for both blends are lower than the respective values for pure PCHPMA and PCHEMA. Thermal stabilities of the blends determined by thermogravimetry are also better than those of pure polymethacrylates. The temperature of 50% weight degradation for blend E is higher than that for pure PCHEMA by more than 60 K Copyright © 2004 Society of Chemical Industry 相似文献
12.
In this paper, a fuzzy c‐means clustering algorithm based on interval‐valued weights is proposed for improving clustering performance. In the proposed algorithm, the interval‐valued weights are first constructed by synergy of the ReliefF algorithm and the analytic hierarchy process (AHP) method, and then they are transformed into a constraint condition associating with each weight variable in the weighted clustering objective function. In the sequence, the weighted clustering objective function is solved by combining the Lagrange multiplier method with the gradient‐based iteration computation. In the whole process of algorithm iteration, a compulsion strategy with human–computer cooperation is adopted to ensure each weight variable satisfies interval constraint itself. Three well‐known data set are used to perform profound experiments. Experimental results clearly show that the proposed algorithm has better clustering performance than other the weighted fuzzy c‐means clustering algorithm. 相似文献
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We introduce a new architecture of feed-forward neural networks called hybrid fuzzy set-based polynomial neural networks (HFSPNNs) that are composed of heterogeneous feed-forward neural networks such as polynomial neural networks (PNNs) and fuzzy set-based polynomial neural networks (FSPNNs). We develop their comprehensive design methodology by embracing mechanisms of genetic optimization and information granulation. The construction of information granulation-driven HFSPNN exploits fundamental technologies of computational intelligence (CI), namely fuzzy sets, neural networks, and genetic algorithms (GAs). The architecture of the resulting information granulation-driven genetically optimized HFSPNN results from a synergistic usage of the hybrid system generated by combining original fuzzy set-based polynomial neurons (FSPNs)-based FSPNN with polynomial neurons (PNs)-based PNN. The design of the conventional genetically optimized HFPNN exploits the extended Group Method of Data Handling (GMDH) whose some essential parameters of the network being tuned with the use of genetic algorithms throughout the overall development process. Two general optimization mechanisms are explored. First, the structural optimization is realized via GAs while the ensuing detailed parametric optimization is carried out in the setting of a standard least square method-based learning. The performance of the gHFSPNN is quantified through extensive experimentation where we considered a number of modeling benchmarks (synthetic and experimental data already experimented with in fuzzy or neurofuzzy modeling). 相似文献
16.
In this paper, we introduce a new category of fuzzy models called a fuzzy ensemble of parallel polynomial neural network (FEP2N2), which consist of a series of polynomial neural networks weighted by activation levels of information granules formed with the use of fuzzy clustering. The two underlying design mechanisms of the proposed networks rely on information granules resulting from the use of fuzzy C-means clustering (FCM) and take advantage of polynomial neural networks (PNNs).The resulting model comes in the form of parallel polynomial neural networks. In the design procedure, in order to estimate the optimal values of the coefficients of polynomial neural networks we use a weighted least square estimation algorithm. We incorporate various types of structures as the consequent part of the fuzzy model when using the learning algorithm. Among the diverse structures being available, we consider polynomial neural networks, which exhibit highly nonlinear characteristics when being viewed as local learning models.We use FCM to form information granules and to overcome the high dimensionality problem. We adopt PNNs to find the optimal local models, which can describe the relationship between the input variables and output variable within some local region of the input space.We show that the generalization capabilities as well as the approximation abilities of the proposed model are improved as a result of using polynomial neural networks. The performance of the network is quantified through experimentation in which we use a number of benchmarks already exploited within the realm of fuzzy or neurofuzzy modeling. 相似文献
17.
In this study, we are concerned with system modeling which involves limited data and reconciles the developed model with some previously acquired domain knowledge being captured in the format of already constructed models. Each of these previously available models was formed on a basis of extensive data sets which are not available for the current identification pursuits. To emphasize the nature of modeling being guided by the reconciliation mechanisms, we refer to this mode of identification as experience-consistent modeling. The paper presents the conceptual and algorithmic framework by focusing on regression models. By forming a certain extended form of the performance index, it is shown that the domain knowledge captured by regression models can play a similar role as a regularization component used quite commonly in system identification. Experimental results involve both synthetic low-dimensional data and selected data coming from Machine Learning repository. The data used in the experiments tackle regression models as well as classification problems (two-class classifiers). 相似文献
18.
Sung-Kwun Oh Seung-Hyun Jung Witold Pedrycz 《Expert systems with applications》2009,36(9):11641-11651
In this study, we present a design of an optimized fuzzy cascade controller based on Hierarchical Fair Competition-based Genetic Algorithms (HFCGA) for a rotary inverted pendulum system. In this system, one controls the movement of a pendulum through the adjustment of a rotating arm. The objective is to control the position of the rotating arm and to make the pendulum maintain the unstable equilibrium point at vertical position. To control the system, we design a fuzzy cascade controller scheme which consists of two fuzzy controllers arrange in a cascaded topology. The parameters of the controller are optimized by means of the HFCGA algorithm. The fuzzy cascade scheme comprises two controllers located in two loops. An inner loop controller governs the position of the rotating arm while an outer controller modifies a set point of the inner controller implied by the changes of the angle of pendulum. The HFCGA being a computationally effective scheme of the Parallel Genetic Algorithm (PGA) has been developed to eliminate an effect of premature convergence encountered in Serial Genetic Algorithms (SGA). It has emerged as an effective optimization vehicle to deal with very large search spaces. A comparative analysis involving computing simulations and practical experiment demonstrates that the proposed HFCGA based fuzzy cascade controller comes with superb performance in comparison with the conventional Linear Quadratic Regulator (LQR) controller as well as HFCGA-based PD cascade controller. 相似文献
19.
Development of heterogeneous acid catalysts produced from the carbonization of Miscanthus x giganteus for the esterification of butyric acid to butyl butyrate with n‐butanol
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20.
This paper is addressing problems related to the construction of classifiers based on the Similarity Discriminant Function (SDF), in which the traditional vector representation of a pattern is replaced with matrix data. We introduce potential modifications of the matrix data structure and propose new variants of the SDF. The algorithms that we present were tested on images of handwritten digits and on photographs of human faces, taken from the ORL and CMU‐PIE databases. The results of experiments show that our modifications significantly improved the performance of the original SDF classifier. 相似文献